Polymer compositions comprising peptizers, sports equipment comprising such compositions, and method for their manufacture
View Patent ↗Embodiments of the disclosed polymer composition comprise a first unsaturated polymer or polymer precursor, and an effective amount of a peptizer. The peptizer typically comprises a heteroaryl or a heterocyclic compound, other than morpholine as disclosed in assignee's prior applications. Disclosed polymer compositions are useful for making sports equipment, such as at least one layer of a golf ball, often a core. Because the compositions are useful for making golf balls, materials commonly known for making such golf balls can be used in combination with the polymer composition. A method for forming a golf ball also is disclosed. The method comprises providing disclosed compositions and then forming at least one component of a golf using the composition.
1. A golf ball, comprising a core and at least one layer surrounding the core, the layer surrounding the core comprising a polymer composition comprising a polyalkenamer, a cross-linking agent, and an effective amount of at least one peptizer having a formula
where at least one of R 2 -R 6 is —SH, at least one of R 2 -R 6 is halogen, with any remaining R 2 -R 6 being independently selected from hydrogen, halogen, oxygen-bearing moieties, sulfur-bearing moieties, or aliphatic groups.
2. The golf ball according to claim 1 where the core comprises an unsaturated polymer, a synthetic rubber, a natural rubber, a polyalkenamer, an olefinic thermoplastic elastomer, or combinations thereof.
3. The golf ball according to claim 2 where the unsaturated polymer is 1,2-polybutadiene, cis-1,4-polybutadiene, trans-1,4-polybutadiene, cis-polyisoprene, trans-polyisoprene, polychloroprene, polybutylene, styrene-butadiene rubber, styrene-butadiene-styrene block copolymer, styrene-isoprene-styrene block copolymer, nitrile rubber, silicone rubber, polyurethane, polyoctenamer, or mixtures thereof.
4. The golf ball according to claim 1 where the core or layer surrounding the core comprises at least a second polymer selected from synthetic and natural rubbers, thermoset polyurethanes and thermoset polyureas, unimodal ethylene/carboxylic acid copolymers, unimodal ethylene/carboxylic acid/carboxylate terpolymers, bimodal ethylene/carboxylic acid copolymers, bimodal ethylene/carboxylic acid/carboxylate terpolymers, unimodal ionomers, bimodal ionomers, modified unimodal ionomers, modified bimodal ionomers, polyurethane ionomer, thermoplastic polyurethanes, thermoplastic polyureas, polyamides, copolyamides, polyesters, copolyesters, polycarbonates, polyolefins, halogenated polyolefins, halogenated polyethylenes, polyphenylene oxide, polyphenylene sulfide, diallyl phthalate polymer, polyimides, polyvinyl chloride, polyamide-ionomer, polyvinyl alcohol, polyarylate, polyacrylate, polyphenylene ether, impact-modified polyphenylene ether, polystyrene, high impact polystyrene, acrylonitrile-butadiene-styrene copolymer styrene-acrylonitrile (SAN), acrylonitrile-styrene-acrylonitrile, styrene-maleic anhydride (S/MA) polymer, styrenic copolymer, functionalized styrenic copolymer, functionalized styrenic terpolymer, styrenic terpolymer, cellulose polymer, liquid crystal polymer (LCP), ethylene-propylene-diene terpolymer (EPDM), ethylene-vinyl acetate copolymers (EVA), ethylene-propylene copolymer, ethylene vinyl acetate, polyurea, polysiloxane, a compound having a general formula (R 2 N) m —R′—(X(O) n OR y ) m , wherein R is selected from the group consisting of hydrogen, one or more C 1 -C 17 aliphatic systems, one or more cycloaliphatic systems, one or more aromatic systems, R′ is a bridging group comprising one or more unsubstituted C 1 -C 17 straight chain or branched aliphatic or alicyclic groups, one or more substituted straight chain or branched aliphatic or alicyclic groups, one or more aromatic groups, one or more oligomers each containing up to 12 repeating units, and when X is C or S or P, m is 1-3, when X═C, n=1 and y=1, when X═S, n=2 and y=1, and any and all combinations of such materials.
5. The golf ball according to claim 1 where the peptizer has a formula
where at least one of R 2 -R 3 and R 5 -R 6 is halogen, with any remaining R 2 -R 3 and R 5 -R 6 being independently hydrogen or halogen.
6. The golf ball according to claim 1 where the cross-linking agent is a primary, secondary, or tertiary aliphatic, alicyclic or aromatic peroxide.
7. The golf ball according to claim 1 where the core comprises polybutadiene and the peptizer.
8. The golf ball according to claim 1 where the core or the at least one layer comprises a fiber, a filler, or both.
9. The golf ball according to claim 8 where the filler is selected from precipitated hydrated silica, limestone, clay, talc, asbestos, barytes, glass fibers, aramid fibers, mica, calcium metasilicate, barium sulfate, zinc sulfide, lithopone, silicates, silicon carbide, diatomaceous earth, calcium carbonate, magnesium carbonate, barium carbonate, calcium sulfate, magnesium sulfate, barium sulfate, tungsten, steel, copper, cobalt, iron, metal alloys, tungsten carbide, zinc oxide, calcium oxide, barium oxide, titanium dioxide, metal stearates, particulate carbonaceous materials, nanofillers and any and all combinations thereof.
10. The golf ball according to claim 1 where the polymer composition comprises a cross-linking agent selected from sulfur compounds, peroxides, azides, maleimides, a co-cross-linking agent comprising zinc or magnesium salts of an unsaturated fatty acid having from about 3 to about 8 carbon atoms, a base resin, a peptizer, an accelerator, a UV stabilizer, a photostabilizer, a photoinitiator, a co-initiator, an antioxidant, a colorant, a dispersant, a mold release agent, a processing aid, a fiber, a density adjusting filler, a nanofiller, an inorganic filler, an organic filler, or combinations thereof.
11. The golf ball according to claim 1 having a core, one or more intermediate layers, and a cover, the core having a PGA compression of from about 30 to about 190, the one or more intermediate layers or cover layer having a thickness of from about 0.01 to about 0.17 inch and a Shore D hardness of greater than about 25.
12. The golf ball according to claim 1 comprising the core, the at least one layer comprising the polymer composition, at least one intermediate layer and a cover.
13. The golf ball according to claim 1 comprising a four-piece golf ball, comprising:
a rubber-based core having a center;
the at least one layer comprising the polymer composition;
an inner intermediate layer or an outer intermediate layer; and
a cover.
14. The golf ball of claim 1 , wherein the peptizer is 2,3,5,6-tetrachloro-4-pyridinethiol.
15. The golf ball of claim 14 , wherein the polymer composition further comprises a zinc or magnesium salt of an unsaturated fatty acid having from about 3 to about 8 carbon atoms.
16. The golf ball of claim 14 , wherein the polymer composition further comprises zinc diacrylate.
17. The golf ball of claim 1 , wherein the polymer composition further comprises a zinc or magnesium salt of an unsaturated fatty acid having from about 3 to about 8 carbon atoms.
18. A method for making a golf ball, comprising:
providing a polymer composition comprising a polyalkenamer and an effective amount of at least one peptizer having a formula
where at least one of R 2 -R 6 is —SH, at least one of R 2 -R 6 is halogen, with any remaining R 2 -R 6 being independently selected from hydrogen, halogen, oxygen-bearing moieties, sulfur-bearing moieties, or aliphatic group; and
forming at least one layer of a golf ball around the core, wherein the at least one layer comprises the polymer composition.
19. The method of claim 18 where the golf ball has a core comprising polybutadiene and the peptizer.