Low alloy steel for oil well pipes having excellent sulfide stress cracking resistance
View Patent ↗Disclosed is a low alloy steel for oil well pipes which has excellent sulfide stress cracking resistance and is suitable for casing and tubing for oil wells or gas wells. Specifically disclosed is a low alloy steel for oil well pipes containing, in mass %, 0.2-0.35% of C, 0.05-0.5% of Si, 0.05-1.0% of Mn, not more than 0.025% of P, not more than 0.01% of S, 0.005-0.10% of Al, 0.1-1.0% of Cr, 0.5-1.0% of Mo, 0.002-0.05% of Ti, 0.05-0.3% of V, 0.0001-0.005% of B, not more than 0.01% of N, not more than 0.01% of O (oxygen), 0-0.1% of Nb, 0-0.01% of Ca, 0-0.01% of Mg and 0-0.1% of Zr, and having a half-value breadth (H) and a hydrogen diffusion coefficient (D) (10 −6 cm 2 /s) satisfying the following formula (1): 30 H+D ≦19.5 (1).
1. A low alloy steel for oil well pipes consisting of, by mass %, C: 0.25 to 0.35%, Si: 0.05 to 0.3%, Mn: 0.05 to 1.0%, P: 0.025% or less, S: 0.01% or less, Al: 0.005 to 0.10%, Cr: 0.1 to 1.0%, Mo: 0.6 to 1.0%, Ti: 0.002 to 0.05%, V: 0.05 to 0.3%, B: 0.0001 to 0.005%, N: 0.01% or less. O (oxygen): 0.01% or less, Ca: 0 to 0.01%, Mg: 0 to 0.01% and Zr: 0 to 0.1%, and the balance Fe and impurities, which has a stress intensity factor K ISSC value of 25 or more measured in accordance with the NACE TM 0177D method, and has a half-value width H for the peak of the [211] crystal face and a hydrogen diffusion coefficient D (10 −6 cm 2 /s) that satisfy the following equation (1):
30 H+D≦ 19.5 equation (1).
2. The low alloy steel for oil well pipes according to claim 1 , wherein a yield stress is 861 MPa or more.