Water-sensitive biodegradable film
View Patent ↗A film that is biodegradable and water-sensitive (e.g., water-soluble, water-dispersible, etc.) in that it loses its integrity over time in the presence of water is provided. More specifically, the film contains a combination of a biodegradable polyester and a water-sensitive thermoplastic starch. The desired water-sensitive attributes of film may be achieved in the present invention by selectively controlling a variety of aspects of the film construction, such as the nature of the components employed, the relative amount of each component, the manner in which the film is formed, and so forth.
1. An absorbent article comprising a water-sensitive biodegradable film, wherein the absorbent article comprises a body portion that includes a liquid permeable topsheet, a generally liquid impermeable backsheet, and an absorbent core positioned between the backsheet and the topsheet, further comprising a release liner that defines a first surface and an opposing second surface, the first surface being disposed adjacent to an adhesive located on the absorbent article, wherein the backsheet, the release liner, or both includes the water-sensitive biodegradable film, the film comprising:
from 1 wt. % to 20 wt. % of a biodegradable polyester component, wherein the biodegradable polyester component includes at least one biodegradable aliphatic-aromatic copolyester that has a melting point of from about 50° C. to about 180° C. and a glass transition temperature of about 0° C. or less; and
from 80 wt. % to 99 wt. % of a thermoplastic starch component, comprising from about 60 wt. % to about 80 wt. % of at least one water-soluble, chemically modified starch, from about 0.5 wt. % to about 4 wt. % of at least one surfactant, and from about 20 wt. % to about 40 wt. % of at least one plasticizer, wherein the water-soluble, chemically modified starch comprises a starch ester, a hydoxyalkyl starch, or a combination thereof;
wherein the film has a thickness of about 50 micrometers or less and exhibits visible disintegration when sloshed in tap water for 30 seconds at a frequency of 3.5 sloshes per second, the film further exhibiting a dry ultimate tensile strength of from about 20 to about 50 Megapascals in the machine direction and a dry modulus of elasticity of from about 400 to about 1000 Megapascals in the machine direction.
2. The absorbent article of claim 1 , wherein the biodegradable aliphatic-aromatic copolyester has a number average molecular weight of from about 40,000 to about 120,000 grams per mole.
3. The absorbent article of claim 1 , wherein the biodegradable aliphatic-aromatic copolyester has a glass transition temperature of about −10° C. or less.
4. The absorbent article of claim 1 , wherein the biodegradable aliphatic-aromatic copolyester has a melting point of about 80° C. to about 160° C.
5. The absorbent article of claim 1 , wherein the plasticizer is a polyhydric alcohol.
6. The absorbent article of claim 5 , wherein the plasticizer is a sugar alcohol.
7. The absorbent article of claim 1 , wherein the surfactant is a nonionic surfactant having an HLB value of from about 1 to about 10.
8. The absorbent article of claim 7 , wherein the nonionic surfactant includes monoglyceride and/or diglyceride of a fatty acid.
9. The absorbent article of claim 1 , wherein the film has a thickness of from about 5 to about 30 micrometers.
10. The absorbent article of claim 1 , wherein the film exhibits a dry ultimate tensile strength of from about 5 to about 30 Megapascals in the cross-machine direction and a dry modulus of elasticity of from about 150 to about 500 Megapascals in the cross-machine direction.