IP Library Granted Patent US 7,897,260
Granted Patent B2
US 7,897,260 · App. 11/641,827 · Granted Mar 1, 2011

Coated article with low-E coating including tin oxide interlayer

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Quick Facts
Patent No.
US 7,897,260
App. No.
11/641,827
Granted
Mar 1, 2011
Kind
B2
Abstract

A coated article is provided which may be heat treated (e.g., thermally tempered) in certain instances. In certain example embodiments, an interlayer of or including a metal oxide such as tin oxide is provided under an infrared (IR) reflecting layer so as to be located between respective layers comprising silicon nitride and zinc oxide. It has been found that the use of such a tin oxide inclusive interlayer results in significantly improved mechanical durability, thermal stability and/or haze characteristics.

Claims (35)

1. A coated article including a coating supported by a glass substrate, the coating comprising from the glass substrate outwardly:

a first IR reflecting layer comprising silver;

a first dielectric stack located between the first IR reflecting layer comprising silver and the glass substrate;

a second IR reflecting layer comprising silver;

a second dielectric stack located between the first and second IR reflecting layers;

a third dielectric stack located above the first and second IR reflecting layers;

wherein the second dielectric stack comprises first and second tin oxide-based layers, spaced apart by at least a layer comprising silicon nitride;

wherein the first dielectric stack has no tin oxide-based layers, and the third dielectric stack has only one tin oxide-based layer; and

wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a visible transmission decrease of more than 1% from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

2. The coated article of claim 1 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing any visible transmission decrease from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

3. The coated article of claim 1 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a visible b* color value shift of more than 1.0 from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

4. The coated article of claim 1 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a visible b* color value shift of more than 0.5 from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

5. The coated article of claim 1 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a visible b* color value shift of more than 0.3 from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

6. The coated article of claim 1 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a sheet resistance increase of more than 0.1 ohms/square from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

7. The coated article of claim 1 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a sheet resistance increase from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

8. The coated article of claim 1 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a transmitted haze value of more than 0.5 following such heat treatment.

9. A coated article including:

a coating supported by a glass substrate, wherein the coating comprises first and second IR reflecting layers comprising silver which are spaced apart from one another by at least first and second tin oxide-based layers;

a first dielectric stack located between the first IR reflecting layer comprising silver and the glass substrate;

a second dielectric stack located between the first and second IR reflecting layers;

a third dielectric stack located above the first and second IR reflecting layers;

wherein the second dielectric stack comprises the first and second tin oxide-based layers, spaced apart by at least a layer comprising silicon nitride; and

wherein the first dielectric stack has no tin oxide-based layers, and the third dielectric stack has only one tin oxide-based layer and at least one other dielectric layer.

10. The coated article of claim 9 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a sheet resistance increase from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically.

11. The coated article of claim 9 , wherein the coated article is capable of being heat treated for 18 minutes at a furnace temperature of about 650 degrees C. without realizing a visible transmission decrease of more than 1% from the 8 minute mark to the 18 minute mark of such heat treatment, measured monolithically, due to such heat treatment.

12. The coated article of claim 9 , wherein said first and second tin oxide-based layers each contact the layer comprising silicon nitride.

13. The coated article of claim 12 , wherein one of said IR reflecting layers is located on and contacting a layer comprising zinc oxide.

14. A coated article including:

a coating supported by a glass substrate, wherein the coating comprises first and second IR reflecting layers comprising silver which are spaced apart from one another by at least first and second tin oxide-based layers;

a first dielectric stack located between the first IR reflecting layer comprising silver and the glass substrate;

a second dielectric stack located between the first and second IR reflecting layers;

a third dielectric stack located above the first and second IR reflecting layers;

wherein the second dielectric stack comprises the first and second tin oxide-based layers, spaced apart by at least a layer comprising silicon nitride;

wherein the first dielectric stack has no tin oxide-based layers, and the third dielectric stack has only one tin oxide-based layer; and

wherein the coated article is capable of being heat treated at a furnace temperature of about 650 degrees C. for 12 minutes, and realizing at least one of the following due to such heat treatment: (a) a visible transmission that does not decrease between the 8 and 12 minute marks of such heat treatment; (b) a transmissive b* value which does not change by more than 0.5 from the 8 minute mark to the 12 minute mark of such heat treatment; and (c) a sheet resistance in units of ohms/square which does not increase from the 8 minute mark to the 12 minute mark of such heat treatment.

Assignments (4)
MERGER Recorded May 30, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
To: GUARDIAN EUROPE S.À R.L.
Reel/Frame 046834/0495 →
CORRECTIVE ASSIGNMENT TO CORRECT THE NAME AND ADDRESS OF THE ASSIGNEE PREVIOUSLY RECORDED ON REEL 044900 FRAME 0321. ASSIGNOR(S) HEREBY CONFIRMS THE CHANGE OF NAME. Recorded Feb 28, 2018
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À R.L.
Reel/Frame 045870/0001 →
CHANGE OF NAME Recorded Dec 18, 2017
From: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.A.
To: CENTRE LUXEMBOURGEOIS DE RECHERCHES POUR LE VERRE ET LA CERAMIQUE S.À.R.L.
Reel/Frame 044900/0321 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 29, 2017
From: GUARDIAN INDUSTRIES CORP.
To: GUARDIAN GLASS, LLC.
Reel/Frame 044053/0318 →