Back side contact solar cell structures and fabrication processes
View Patent ↗In one embodiment, active diffusion junctions of a solar cell are formed by diffusing dopants from dopant sources selectively deposited on the back side of a wafer. The dopant sources may be selectively deposited using a printing method, for example. Multiple dopant sources may be employed to form active diffusion regions of varying doping levels. For example, three or four active diffusion regions may be fabricated to optimize the silicon/dielectric, silicon/metal, or both interfaces of a solar cell. The front side of the wafer may be textured prior to forming the dopant sources using a texturing process that minimizes removal of wafer material. Openings to allow metal gridlines to be connected to the active diffusion junctions may be formed using a self-aligned contact opening etch process to minimize the effects of misalignments.
1. A method of forming active diffusion regions in a back side contact solar cell, the method comprising:
forming a first set of dopant sources on a back side of a wafer to be processed into a solar cell, the wafer having a front side configured to face the sun during normal operation of the solar cell, the back side being opposite the front side;
selectively depositing a second set and a third set of dopant sources over the first set of dopant sources, the second and third set of dopant sources having different polarity, the second set of dopant sources being selectively deposited in a first set of openings through the first set of dopant sources, the third set of dopant sources being selectively deposited in a second set of openings through the first set of dopant sources, the first set of dopant sources being formed thicker than the second set of dopant sources and the third set of dopant sources;
performing a diffusion step to diffuse dopants from the first set of dopant sources to form a first set of active diffusion regions of the solar cell, dopants from the second set of dopant sources to form a second set of active diffusion regions of the solar cell, and dopants from the third set of dopant sources to form a third set of active diffusion regions of the solar cell; and
exposing what are left of the first, second and third sets of dopant sources after the diffusion step to an etchant to remove portions of what are left of the third and second sets of dopant sources in a self-aligned etch process to form contact openings to the second and third sets of active diffusion regions without completely removing what are left of the first set of dopant sources.
2. The method of claim 1 wherein exposing what are left of the first, second, and third sets of dopant sources to an etchant are performed using a timed etch step.
3. The method of claim 1 wherein forming the first set of dopant sources on the back side of the wafer comprises:
performing a blanket deposition to form the first set of dopant sources; and
patterning the first set of dopant sources to form the first and second set of openings through the first set of dopant sources.
4. The method of claim 3 wherein the blanket deposition is by spin coating.
5. The method of claim 1 wherein the front side of the wafer is textured using a texturing process prior to selectively forming the first set of dopant sources and prior to selectively depositing the second and third sets of dopant sources, the texturing process comprising:
thinning the front side and the back side of the wafer to partially remove damaged portions of the wafer on the front side and the back side;
texturing the front side and the back side of the wafer to remove remaining damaged portions on the front side and the back side of the wafer; and
polishing the back side of the wafer to remove the texturing o the back side of the wafer.