Fe-Ni alloy pipe stock and method for manufacturing the same
View Patent ↗An Fe—Ni alloy pipe stock containing, by mass %, C≦0.04%, Si≦0.50%, Mn: 0.01 to 6.0%, P≦0.03%, S≦0.01%, Cr: 20 to 30%, Ni: 30 to 45%, Mo: 0 to 10%, W: 0 to 20%, with Mo(%)+0.5W(%): more than 1.5% to not more than 10%, Cu: 0.01 to 1.5%, Al≦0.01% and N: 0.0005 to 0.20%, and the balance being Fe, with 1440−6000P−100S−2000C≧1300, Ni+10(Mo+0.5W)+100N≦120, (Ni−35)+10(N−0.1)−2(Cr−25)−5(Mo+0.5W−3)+8≧0, can be manufactured into a seamless pipe by use of a Mannesmann piercing and rolling mill because of its excellent inner surface properties. The resulting seamless pipe has excellent mechanical properties and moreover has excellent corrosion resistance in a sour gas environment.
1. A method for manufacturing an Fe—Ni alloy pipe stock, comprising piercing and rolling a billet by use of a Mannesmann piercing and rolling mill, wherein the billet comprises, by mass %, C: not more than 0.04%, Si: not more than 0.50%, Mn: 0.01 to 6.0%, P: not more than 0.03%, S: not more than 0.01%, Cr: 20 to 30%, Ni: 30 to 45%, Mo: 0 to 10%, W: 0 to 20%, with Mo(%)+0.5W(%): more than 1.5% to not more than 10%, Cu: 0.01 to 1.5%, Al: not more than 0.10% and N: 0.0005 to 0.20%, and the balance being substantially Fe, with values of T GBm , P sr and P σ represented by the following equations (1) to (3) being not less than 1300, not more than 120 and not less than 0, respectively, wherein:
T GBm =1440−6000P−100S−2000C (1),
P sr =Ni+10(Mo+0.5W)+100N (2),
P σ =(Ni−35)+10(N−0.1)−2(Cr−25)−5(Mo+0.5W−3)+8 (3),
and further wherein each element symbol in the equations (1) to (3) represents the content by mass % of the element concerned,
wherein the piercing and rolling by the Mannesmann piercing and rolling mill is performed in a condition where the value of fn represented by the following equation (4) is not more than 1:
fn ={P/(0.025H−0.01)} 2 +{S/(0.015H−0.01)} 2 (4),
wherein P and S represent contents, by mass %, of P and S in the pipe stock, respectively, and H represents the pipe expansion ratio represented by the ratio of the outer diameter of the pipe stock to the diameter of the steel stock billet.
2. The method according to claim 1 , wherein the content of Mn is 0.01 to 1.0% by mass %.
3. The method according to claim 1 , wherein the billet further contains an element or elements of one or more groups selected from the groups (a) to (d) listed below in lieu of part of Fe:
(a): one or more selected from among V: 0.001 to 0.3%, Nb: 0.001 to 0.3%, Ta: 0.001 to 1.0%, Ti: 0.001 to 1.0%, Zr: 0.001 to 1.0% and Hf: 0.001 to 1.0% by mass %;
(b): B: 0.0001 to 0.015% by mass %;
(c): Co: 0.3 to 5.0% by mass %;
(d): one or more selected from among Mg: 0.0001 to 0.010%, Ca: 0.0001 to 0.010%, La: 0.0001 to 0.20%, Ce: 0.0001 to 0.20%, Y: 0.0001 to 0.40%, Sm: 0.0001 to 0.40%, Pr: 0.0001 to 0.40% and Nd: 0.0001 to 0.50% by mass %.
4. The method according to claim 3 , wherein the content of Mn is 0.01 to 1.0% by mass %.