IP Library Granted Patent US 9,379,393
Granted Patent B2
US 9,379,393 · App. 11/644,122 · Granted Jun 28, 2016

Carbon cladded composite flow field plate, bipolar plate and fuel cell

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Quick Facts
Patent No.
US 9,379,393
App. No.
11/644,122
Granted
Jun 28, 2016
Kind
B2
Abstract

The present invention provides a carbon-cladded composite composition for use as a fuel cell flow field plate or bipolar plate. In one preferred embodiment, the composition comprises a core composite layer sandwiched between two clad layers, wherein (a) the clad layer comprises a conductive carbon or graphite material (e.g., carbon nano-tubes, nano-scaled graphene plates, graphitic nano-fibers, and fine graphite particles); (b) the core composite layer comprises a matrix resin and a conductive filler present in a sufficient quantity to render the composite layer electrically conductive with an electrical conductivity no less than 1 S/cm (preferably no less than 100 S/cm); and (c) the composition has a planar outer surface on each clad side having formed therein a fluid flow channel.

Claims (15)

1. A carbon-cladded composite fuel cell flow field plate or bipolar plate, said plate consisting of a first clad coated on or bonded to a first surface of a conductive composite layer, and a second clad coated on or bonded to a second surface of said conductive composite layer, wherein said first clad, composite layer, and second clad together form a three-layer sandwich structure and wherein

(a) said first clad or said second clad consists of conductive particles of nano-scaled graphene platelets that are substantially non-parallel to said first surface or said second surface of said composite layer such that the basal plane of said platelets are substantially non-parallel to said first surface or said second surface of said composite layer, wherein said first clad or said second clad has an exterior skin that contains 100% of the nano-scaled graphene platelet particles free from any resin;

(b) said conductive composite layer comprises a matrix resin and a conductive filler present in a sufficient quantity to render said composite layer electrically conductive with an electrical conductivity no less than 1 S/cm, wherein said matrix resin is selected from a thermoset resin, a semi-interpenetrating network, an interpenetrating network, a rubber, or a combination thereof and said first clad is bonded to said composite layer to eliminate a resin-rich layer from said first surface and said second clad is bonded to said composite layer to eliminate a resin-rich layer from said second surface; and

(c) said carbon-cladded composite has a planar outer surface, on said first clad or said second clad side, having formed therein a fluid flow channel.

2. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said matrix resin comprises a thermoset resin selected from the group consisting of unsaturated polyester resin, vinyl ester, epoxy, phenolic resin, polyimide resin, bismaleimide resin, polyurethane resin, and combinations thereof.

3. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said conductive filler comprises a conductive material selected from carbon fiber, metal fiber, carbon nano-tube, graphitic nano-fiber, carbon black, metal particle, graphite powder, or a combination thereof.

4. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said first clad or second clad has a thickness smaller than 100 μm.

5. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said first clad or second clad has a thickness smaller than 10 μm.

6. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said first clad or second clad has a thickness smaller than 1 μm.

7. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said composite layer has a thickness smaller than 100 μm.

8. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said three-layer sandwich structure has an electrical conductivity no less than 100 S/cm.

9. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , wherein said three-layer sandwich structure has an areal conductivity no less than 200 S/cm 2 .

10. The carbon-cladded composite flow field plate or bipolar plate as defined in claim 1 , further comprising a coolant channel.

11. A fuel cell comprising a flow field plate as defined in claim 1 .

12. A fuel cell stack comprising a plurality of fuel cell units separated by at least a bipolar plate as defined in claim 1 .

Assignments (9)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 18, 2019
From: NANOTEK INSTRUMENTS, INC.
To: NANOTEK INSTRUMENTS GROUP, LLC
Reel/Frame 049787/0643 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 21, 2016
From: NANOTEK INSTRUMENTS, INC.
To: EVERPOWER SHENG TIE (XIAMEN) GRAPHENE TECHNOLOGY CO., LTD.
Reel/Frame 039818/0217 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 30, 2016
From: NANOTEK INSTRUMENTS, INC.
To: EVERPOWER SHENG TIE (XIAMEN) GRAPHEME TECHNOLOGY CO., LTD.
Reel/Frame 039583/0889 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 25, 2016
From: GUO, JIUSHENG
To: NANOTEK INSTRUMENTS, INC
Reel/Frame 038371/0276 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 25, 2016
From: ZHAMU, ARUNA, DR
To: NANOTEK INSTRUMENTS, INC
Reel/Frame 038370/0576 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 25, 2016
From: JANG, BOR Z, DR
To: NANOTEK INSTRUMENTS, INC
Reel/Frame 038370/0192 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 19, 2016
From: JANG, BOR Z.
To: NANOTEK INSTRUMENTS, INC.
Reel/Frame 038464/0403 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 13, 2016
From: GUO, JIUSHENG
To: NANOTEK INSTRUMENTS, INC.
Reel/Frame 038427/0531 →
CONFIRMATORY LICENSE Recorded Apr 24, 2014
From: NANOTEK INSTRUMENTS, INC.
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 032797/0246 →