Composition comprising polyvinyl chloride and ethylene copolymer
View Patent ↗Disclosed is a composition comprising, consisting essentially of, consisting of, or produced from polyvinyl chloride, filler, and an impact strength-retaining amount of a modifier wherein the modifier includes is or an ethylene copolymer, an acid anhydride- or acid monoester-modified polyolefin, or combinations thereof. Also disclosed is a process comprising combining an impact strength-retaining amount of a modifier to a blend that comprises or is produced by combining a rigid PVC and one or more fillers. The combining is carried out under a condition sufficient to prevent or minimize the reduction of impact strength of the blend, to reduce the molten viscosity of the blend, or to minimize the loss in stiffness (flexural modulus) of the blend, in comparison to the unmodified blend.
1. A composition comprising, or produced from, polyvinyl chloride, filler, and an impact strength-retaining amount of a modifier wherein the modifier is an ethylene copolymer, an acid anhydride- or acid monoester-modified polyolefin, or combinations thereof;
the filler includes glass fiber, hollow glass microsphere, CaCO 3 , silica, calcium silicate, calcium metasilicate, clay, mica, talc, alumina trihydrate, magnesium hydroxide, metal oxides, or combinations of two or more thereof;
the ethylene copolymer is ethylene alkyl (meth)acrylate copolymer, ethylene butyl acrylate glycidyl methyl acrylate copolymer, ethylene (meth)acrylic acid copolymer or its corresponding ionomer, ethylene butyl acrylate (meth)acrylic acid copolymer or its corresponding ionomer, or combinations of two or more thereof; and
the acid anhydride or acid monoester includes maleic anhydride, itaconic anhydride, fumaric anhydride, maleic acid monoesters, itaconic monoesters, fumaric acid monoester, a salt of thereof, combinations of two or more thereof.
2. The composition of claim 1 wherein the modifier is the ethylene butyl acrylate glycidyl methyl acrylate copolymer.
3. The composition of claim 1 wherein the modifier is ethylene methyl acrylate copolymer.
4. The composition of claim 1 wherein the modifier is the ethylene alkyl (meth)acrylic acid copolymer or its corresponding ionomer.
5. The composition of claim 1 wherein the filler is the glass fiber.
6. The composition of claim 1 wherein the ethylene copolymer is the ethylene butyl acrylate copolymer.
7. The composition of claim 4 wherein the modifier is an ionomer of an ethylene butyl acrylate methacrylic acid copolymer.
8. The composition of claim 1 wherein the modifier is the acid anhydride- or acid monoester-modified polyolefin.
9. The composition of claim 7 wherein the modifier is the acid anhydride-modified polyolefin, the acid anhydride is maleic anhydride, and the polyolefin is polyethylene, polypropylene, or combinations thereof.
10. The composition of claim 7 wherein the modifier is the maleic anhydride-modified polyethylene, polypropylene, or combinations thereof.
11. The composition of claim 10 wherein the filler is the glass fiber.
12. A process comprising combining an impact strength-retaining amount of a modifier and a filler with PVC to produce a blend wherein
the modifier is an ethylene copolymer, an acid anhydride- or acid monoester-modified polyolefin, or combinations thereof;
the filler includes glass fiber, hollow glass microsphere, CaCO 3 , silica, calcium silicate, calcium metasilicate, clay, mica, talc, alumina trihydrate, magnesium hydroxide, metal oxides, or combinations of two or more thereof;
the ethylene copolymer is ethylene alkyl (meth)acrylate copolymer, ethylene butyl acrylate glycidyl methyl acrylate copolymer, ethylene (meth)acrylic acid copolymer or its corresponding ionomer, ethylene butyl acrylate (meth)acrylic acid copolymer or its corresponding ionomer, or combinations of two or more thereof;
the acid anhydride or acid monoester includes maleic anhydride, itaconic anhydride, fumaric anhydride, maleic acid monoesters, itaconic monoesters, fumaric acid monoester, a salt thereof, combinations of two or more thereof; and
the combining is carried out under a condition sufficient to prevent or minimize the reduction of impact strength of the blend, to reduce the molten viscosity of the blend, or to minimize the loss in stiffness (flexural modulus) of the blend, in comparison to a blend without the modifier.
13. The process of claim 12 wherein process comprises combining the modifier and the filler to produce a sub-blend and combining the sub-blend with the PVC to produce the composition.
14. The process of claim 13 wherein the modifier is the ethylene butyl acrylate glycidyl methyl acrylate copolymer.
15. The process of claim 13 wherein the ethylene copolymer is the ethylene alkyl (meth)acrylate copolymer.
16. The process of claim 13 wherein the filler is the glass fiber and the ethylene copolymer is the ethylene butylacrylate copolymer, the ethylene butyl acrylate (meth)acrylic acid copolymer or its corresponding ionomer.
17. The process of claim 12 wherein the modifier is the acid anhydride- or acid monoester-modified polyolefin and the polyolefin includes polyethylene, polypropylene, or combinations thereof.
18. The process of claim 17 wherein the modifier is the maleic anhydride-modified polyethylene, polypropylene, or combinations thereof.
19. The process of claim 17 wherein the filler is the glass fiber.
20. A article comprising or produced from a composition wherein the article includes decorative moldings inside or outside of a house, railroad ties, picture frames, furniture, porch decks, railings, window moldings, window components, door components, roofing systems, sidings, pellets, slugs, rods, ropes, sheets, or molded articles and the composition is as recited in claim 1 .