IP Library Granted Patent US 7,794,918
Granted Patent B2
US 7,794,918 · App. 11/646,368 · Granted Sep 14, 2010

Ink composition, inkjet recording method, printed material, method for producing planographic printing plate, and planographic printing plate

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Quick Facts
Patent No.
US 7,794,918
App. No.
11/646,368
Granted
Sep 14, 2010
Kind
B2
Abstract

The invention provides an ink composition having at least (A) a polymerization initiator, (B) an ester or amide of (meth)acrylic acid having a 1,3-dioxolane ring skeleton or a 1,3-dioxane ring skeleton or (B′) an ester or amide of (meth)acrylic acid having a 1,3-diketone structure, and (C) a colorant. The invention further provides an inkjet recording method and a method for producing a planographic printing plate, each of which includes at least (I) ejecting the ink composition onto a hydrophilic support and (II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support. The invention furthermore provides a planographic printing plate formed by the method for producing a planographic printing plate.

Claims (66)

1. An inkjet recording composition comprising an ink composition,

wherein the ink composition comprises:

(A) a polymerization initiator;

(B) an ester of (meth)acrylic acid having 1,3-dioxane ring skeleton represented by the following Formula (I) or an amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton;

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group; one of R 1 to R 8 has a structure of an ester of (meth)acrylic acid represented by the following Formula (III) as a substituent at a terminal thereof:

wherein R 9 represents a hydrogen atom or a methyl group; and

(C) a colorant.

2. The inkjet recording composition according to claim 1 , wherein the ink composition further comprises a vinyl ether compound.

3. An inkjet recording method, comprising:

(i) ejecting an ink composition onto a recording medium; and

(ii) irradiating the ejected ink composition with active radiation to cure the ink composition,

wherein the ink composition comprises:

(A) a polymerization initiator;

(B) an ester of (meth)acrylic acid having 1,3-dioxane ring skeleton represented by the following Formula (I) or an amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton;

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group; one of R 1 to R 8 has a structure of an ester of (meth)acrylic acid represented by the following Formula (III) as a substituent at a terminal thereof:

wherein R 9 represents a hydrogen atom or a methyl group; and

(C) a colorant.

4. The inkjet recording method according to claim 3 , wherein the amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is represented by the following Formula (I):

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, and at least one of R 1 to R 8 has a structure of an amide of (meth)acrylic acid as a substituent at a terminal thereof.

5. The inkjet recording method according to claim 3 , wherein the ink composition further comprises a vinyl ether compound.

6. A method for producing a planographic printing plate, comprising:

(I) ejecting an ink composition onto a hydrophilic support; and

(II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support,

wherein the ink composition comprises:

(A) a polymerization initiator;

(B) an ester of (meth)acrylic acid having 1,3-dioxane ring skeleton represented by the following Formula (I) or an amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton;

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group; one of R 1 to R 8 has a structure of an ester of (meth)acrylic acid represented by the following Formula (III) as a substituent at a terminal thereof:

wherein R 9 represents a hydrogen atom or a methyl group; and

(C) a colorant.

7. The method for producing a planographic printing plate according to claim 6 , wherein the amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is represented by the following Formula (I):

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, and at least one of R 1 to R 8 has a structure of an amide of (meth)acrylic acid as a substituent at a terminal thereof.

8. The method for producing a planographic printing plate according to claim 6 , wherein the ink composition further comprises a vinyl ether compound.

9. The inkjet recording composition according to claim 1 , wherein the amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is represented by the following Formula (I):

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group having 1 to 18 carbon atoms, and at least one of R 1 to R 8 has a structure of an amide of (meth)acrylic acid as a substituent at a terminal thereof.

10. An inkjet recording composition

wherein the ink composition comprises:

(A) a polymerization initiator;

(B) an ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton which is a compound selected from (B-2)

(C) a colorant.

11. The inkjet recording composition according to claim 1 , wherein a viscosity of the ink composition is from 7 mPa·s to 20 mPa·s at a temperature of from 25° C. to 50° C.

12. An inkjet recording method, comprising:

(i) ejecting an ink composition onto a recording medium; and

(ii) irradiating the ejected ink composition with active radiation to cure the ink composition,

wherein the ink composition comprises:

(A) a polymerization initiator;

(B) an ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton which is a compound selected from the following (B-2)

(C) a colorant.

13. The inkjet recording method according to claim 3 , wherein the viscosity of the ink composition is from 7 mPa·s to 20 mPa·s at a temperature of from 25° C. to 50° C.

14. A method for producing a planographic printing plate, comprising:

(I) ejecting an ink composition onto a hydrophilic support; and

(II) curing the ink composition by irradiating the ejected ink composition with active radiation so as to form a hydrophobic image region on the hydrophilic support,

wherein the ink composition comprises:

(A) a polymerization initiator;

(B) an ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton; and

(C) a colorant,

wherein (B) the ester or amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is a compound selected from the following (B-2)

15. The method for producing a planographic printing plate according to claim 6 , wherein the viscosity of the ink composition is from 7 mPa·s to 20 mPa·s at a temperature of from 25° C. to 50° C.

16. The inkjet recording composition according to claim 1 , wherein the amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is represented by the following Formula (I)′:

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group; one of R 1 to R 8 has a structure of an amide of (meth)acrylic acid represented by the following Formula (IV) as a substituent at a terminal thereof:

wherein R 9 represents a hydrogen atom or a methyl group, and R 10 represents a hydrogen atom or a hydrocarbon group.

17. The inkjet recording method according to claim 3 , wherein the amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is represented by the following Formula (I)′:

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group; one of R 1 to R 8 has a structure of an amide of (meth)acrylic acid represented by the following Formula (IV) as a substituent at a terminal thereof:

wherein R 9 represents a hydrogen atom or a methyl group, and R 10 represents a hydrogen atom or a hydrocarbon group.

18. The method for producing a planographic printing plate according to claim 6 , wherein the amide of (meth)acrylic acid having a 1,3-dioxane ring skeleton is represented by the following Formula (I)′:

wherein each of R 1 to R 8 independently represents a hydrogen atom or a hydrocarbon group; one of R 1 to R 8 has a structure of an amide of (meth)acrylic acid represented by the following Formula (IV) as a substituent at a terminal thereof:

wherein R 9 represents a hydrogen atom or a methyl group, and R 10 represents a hydrogen atom or a hydrocarbon group.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 8, 2016
From: FUJIFILM CORPORATION
To: FUJIFILM SPECIALITY INK SYSTEMS LIMITED; FUJIFILM CORPORATION
Reel/Frame 038226/0097 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 5, 2007
From: NAKAMURA, IPPEI; SUGAI, MASAHARU
To: FUJIFILM CORPORATION
Reel/Frame 018957/0116 →