Methods for feedstock pretreatment and transport to gasification

1. A method for pretreating feedstock for gasification comprising:

combining a coal based feedstock and supercritical carbon dioxide within a pretreatment system to provide a treated feedstock;

passing at least a portion of the treated feedstock to a gasifier to produce a synthesis gas comprising less than 50% by volume carbon dioxide, at least 5% by volume carbon monoxide and at least 1% by volume hydrogen;

combusting at least a portion of the synthesis gas comprising less than 50% by volume carbon dioxide to form an exhaust gas comprising carbon dioxide;

compressing at least a portion of the exhaust gas to produce compressed carbon dioxide; and

recycling at least a portion of the compressed carbon dioxide at supercritical conditions to the pretreatment system.

2. The method of claim 1 wherein the coal based feedstock comprises feedstock having an average particle size ranging from 150 μm to 450 μm.

3. The method of claim 1 wherein the coal based feedstock is selected from the group consisting of high-sodium lignite, low-sodium lignite, subbituminous, bituminous and anthracite.

4. The method of claim 1 wherein the supercritical carbon dioxide is combined with the feedstock in an amount sufficient to increase distribution of the feedstock to the gasifier.

5. The method of claim 1 wherein the coal based feedstock and supercritical carbon dioxide are mixed within an intermediate vessel of a lockhopper in the pretreatment system.

6. The method of claim 5 wherein the coal based feedstock within the intermediate vessel of the lockhopper is pressurized using the supercritical carbon dioxide.

7. The method of claim 1 , further comprising introducing one or more oxidants to the gasifier, wherein the one or more oxidants is present in an amount less than about 5% of the stoichiometric amount of oxygen required for complete combustion of all the carbon dioxide introduced to the gasifier.

8. The method of claim 7 , wherein the coal based feedstock comprises one or more polymeric materials.

9. The method of claim 8 , wherein the one or more polymeric materials comprise polypropylene, polyethylene, polystyrene, copolymers thereof, blends thereof, or any combination thereof.

10. A method for pretreating feedstock for gasification comprising:

mixing a coal based feedstock with supercritical carbon dioxide to increase the volatile content of the feedstock;

passing at least a portion of the feedstock to a gasifier to produce a synthesis gas;

combusting at least a portion of the synthesis gas comprising less than 50% by volume carbon dioxide to form an exhaust gas comprising carbon dioxide;

purifying, compressing, and heating the carbon dioxide to produce a compressed carbon dioxide at supercritical conditions; and

recycling at least a portion of the supercritical carbon dioxide at to the feedstock prior to the gasifier.

11. The method of claim 10 wherein the coal based feedstock comprises feedstock having an average particle size ranging from 150 μm to 450 μm.

12. The method of claim 10 wherein the coal based feedstock is selected from the group consisting of high-sodium lignite, low-sodium lignite, subbituminous, bituminous and anthracite.

13. The method of claim 10 wherein the exhaust gas is from one or more combustion turbines.

14. The method of claim 10 , further comprising coupling the compression of the carbon dioxide with the combustion of the synthesis gas.

15. The method of claim 14 , wherein the coupling provides additional carbon dioxide.

16. The method of claim 10 , wherein the supercritical carbon dioxide is mixed with the feedstock in an amount sufficient to increase distribution of the feedstock to the gasifier.