IP Library Granted Patent US 7,703,403
Granted Patent B2
US 7,703,403 · App. 11/654,332 · Granted Apr 27, 2010

System and method for recomposing ammonia from fly ash

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Quick Facts
Patent No.
US 7,703,403
App. No.
11/654,332
Granted
Apr 27, 2010
Kind
B2
Abstract

A system and method for decomposing ammonia from fly ash contaminated with ammonia is provided which includes maintaining the temperature of a bed of ammonia-contaminated fly ash at a decomposition temperature greater than 500° F. and less than 842° F. to decompose the ammonia from the fly ash. In a preferred embodiment, the ammonia-laden fly ash is maintained at a temperatures less than a lowest carbon combustion temperature at which substantial combustion of carbon in fly ash begins to occur. A preferred embodiment includes a first chamber operating at a decomposition temperature greater than 500° F. and less than 842° F. followed by a second chamber operating at a higher carbon combustion temperature for carbon burn-out.

Claims (13)

1. An apparatus for removing ammonia from ammonia-laden fly ash containing carbon, the system comprising:

a first chamber to receive ammonia-laden fly ash, the first chamber adapted to maintain the ammonia-laden fly ash at a decomposition temperature both a) greater than 500° F. and less than 800° F. to decompose the ammonia in the ammonia-laden fly ash, and b) less than a lowest carbon combustion temperature of at least 800° F. at which substantial combustion of carbon in the ammonia-laden fly ash begins to occur; and

a second chamber positioned downstream of the first chamber to receive resultant ammonia-free fly ash from the first chamber, the second chamber adapted to maintain the resultant ammonia-free fly ash at a carbon combustion temperature to remove carbon from the fly ash.

2. The apparatus of claim 1 wherein the second chamber is adapted to increase the temperature of the resultant ammonia-free fly ash to the carbon combustion temperature, the carbon combustion temperature being between 1100° F. and 1500° F.

3. The apparatus of claim 1 wherein the temperature of the first chamber is controlled by a temperature control unit.

4. The apparatus of claim 3 wherein the temperature control unit comprises a controller, a thermocouple, and a heat source.

5. The apparatus of claim 4 wherein the heat source is selected from a group consisting of: hot fly ash, hot exhaust gas, a heated air input, a liquefied petroleum gas burner and a natural gas burner.

6. A apparatus for removing ammonia from ammonia-laden fly ash, the system comprising:

a chamber to receive the ammonia-laden fly ash, the chamber adapted to maintain the ammonia-laden fly ash at a decomposition temperature greater than 500° F. and less than 800° F. to decompose the ammonia in the ammonia-laden fly ash.

7. The apparatus of claim 6 wherein the chamber is adapted to maintain the ammonia-laden fly ash at a temperature less than a lowest carbon combustion temperature at which substantial combustion of carbon in fly ash begins to occur.

8. The apparatus of claim 6 wherein the temperature of the chamber is controlled by a temperature control unit.

9. The apparatus of claim 8 wherein the temperature control unit comprises a controller, a thermocouple, and a heat source.

10. The apparatus of claim 9 wherein the heat source is one of hot fly ash, hot exhaust gas, a heated air input, a liquefied petroleum gas burner and a natural gas burner.

Assignments (15)
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME NO. 67963/0364 Recorded Sep 16, 2025
From: MIZUHO BANK, LTD., AS AGENT
To: EM RESOURCES LLC
Reel/Frame 072872/0638 →
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME NO. 70696/0397 Recorded Sep 15, 2025
From: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
To: EM RESOURCES LLC
Reel/Frame 072910/0155 →
SECURITY INTEREST Recorded Apr 1, 2025
From: EM RESOURCES LLC
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 070696/0397 →
RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT R/F 059002/0270 Recorded Feb 12, 2025
From: UMB BANK, N.A.
To: EM RESOURCES LLC (F/K/A BORAL RESOURCES LLC)
Reel/Frame 070191/0325 →
PATENT SECURITY AGREEMENT Recorded Jun 28, 2024
From: EM RESOURCES LLC
To: MIZUHO BANK, LTD.
Reel/Frame 067963/0364 →
RELEASE OF SECURITY INTEREST Recorded Jun 20, 2024
From: MUFG BANK, LTD
To: EM RESOURCES LLC (FORMERLY KNOWN AS BORAL RESOURCES LLC)
Reel/Frame 067799/0395 →
CHANGE OF NAME Recorded Mar 25, 2022
From: BORAL RESOURCES LLC
To: EM RESOURCES LLC
Reel/Frame 059510/0851 →
SECURITY INTEREST Recorded Feb 10, 2022
From: BORAL RESOURCES LLC
To: UMB BANK, N.A.
Reel/Frame 059002/0270 →
SECURITY INTEREST Recorded Feb 10, 2022
From: BORAL RESOURCES LLC
To: MUFG BANK, LTD.
Reel/Frame 059003/0211 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2018
From: PMI ASH TECHNOLOGIES, LLC
To: BORAL RESOURCES LLC
Reel/Frame 045924/0885 →
TERMINATION AND RELEASE OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 20, 2012
From: WELLS FARGO BANK, NATIONAL ASSOCIATION
To: PMI ASH TECHNOLOGIES, LLC
Reel/Frame 028604/0551 →
SECURITY AGREEMENT Recorded Jan 8, 2010
From: PMI ASH TECHNOLOGIES, LLC
To: WACHOVIA BANK, NATIONAL ASSOCIATION
Reel/Frame 023768/0442 →
MERGER Recorded Jul 17, 2008
From: PMI TARGET, LLC
To: PMI ASH TECHNOLOGIES, LLC
Reel/Frame 021253/0132 →
CHANGE OF NAME Recorded Jun 6, 2008
From: PROGRESS MATERIALS, INC.
To: PMI TARGET, LLC
Reel/Frame 021050/0887 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 17, 2007
From: GIAMPA, VINCENT M.; COCHRAN, JOSEPH W.
To: PROGRESS MATERIALS, INC.
Reel/Frame 018807/0337 →