Process for the production of di- and polyamines of the diphenylmethane series
View Patent ↗The present invention relates to a process for the production of mixtures of di- and polyamines of the diphenylmethane series (MDA) containing less than 1,000 ppm of water and less than 200 ppm of aniline by reaction of aniline and formaldehyde in the presence of acid catalysts and subsequent separation of the acid catalyst and subsequent distillative separation of water and aniline in an at least a two-stage distillation including a flash evaporation and subsequent cooling.
1. A process for the production of di- and polyamines of the diphenylmethane series comprising:
a) reacting aniline and formaldehyde in the presence of an acid catalyst to produce a reaction mixture containing di- and polyamines;
b) neutralizing the reaction mixture containing di- and polyamines;
c) separating the neutralized reaction mixture containing di- and polyamines into an organic phase containing di- and polyamines and an aqueous phase;
d) separating by distillation the water and aniline from the organic phase containing di- and polyamines;
wherein
d1) the distillation in step d) comprises at least one pre-evaporation stage and at least one distillation stage,
d2) aniline and water are partially separated off in the pre-evaporation stage from the organic phase containing di- and polyamines by flash evaporation, and
d3) in the subsequent distillation stage, the remaining aniline and water are separated off, such that di- and polyamines containing less than about 1,000 ppm of water and less than about 200 ppm of aniline, based on the weight of the di- and polyamines, are obtained and
e) cooling the di- and polyamines containing less than about 1,000 ppm of water and less than about 200 ppm of aniline.
2. The process according to claim 1 , wherein the cooling of the di- and polyamines containing less than about 1,000 ppm of water and less than about 200 ppm of aniline in step e) takes place by heat exchange with the organic phase containing di- and polyamines before or during the distillation thereof in step d).
3. The process according to claim 1 , wherein the pre-evaporation of the organic phase containing di- and polyamines in step d2) takes place by at least a two-stage flash evaporation and with feed of heat which is exchanged by heat exchange of the organic phase containing di- and polyamines with the stream of di- and polyamines containing less than about 1,000 ppm of water and less than about 200 ppm of aniline.
4. The process according to claim 1 , wherein the mixture of aniline and water obtained in step d3) as distillate contains less than about 0.5 wt. % of di- and polyamines, based on the weight of the aniline.
5. The process for the production of di- and polyisocyanates of the diphenylmethane series, wherein di- and polyamines are produced according to the process of claim 1 and reacted with phosgene to the corresponding di- and polyisocyanates.