Polymer and liquid gasket for In-Place forming
View Patent ↗A liquid sealing agent used for automobile parts, electric parts, various kinds of machine parts and the like exhibits good oil resistance, heat resistance, adhesiveness and flexibility. A vinyl polymer has at least one crosslinkable silyl group and can yield a cured product exhibiting an oil resistance superior to that of a cured product from a reference polymer obtained by replacing the repeating unit thereof with butyl acrylate alone, in any one item of the immersion test according to JIS K 6258 for the land use 3-5 lubricating oil specified in JIS K 2215.
1. A vinyl polymer which has at least one crosslinkable silyl group and yields a cured product exhibiting an oil resistance superior to that of a cured product from a polymer obtained by replacing the repeating unit in the main chain thereof with butyl acrylate alone, in any one item of the immersion test according to JIS K 6258 for the land use 3-5 lubricating oil specified in JIS K 2215,
wherein the main chain of the vinyl polymer is a (meth)acrylic polymer produced by polymerizing mainly ethyl acrylate monomer in a living radical polymerization.
2. A vinyl polymer which has at least one crosslinkable silyl group and yields a cured product exhibiting an oil resistance represented by mass change between before and after immersion of at most 50% in the immersion test according to JIS K 6258 for the land use 3-5 lubricating oil specified in JIS K 2215.
3. The vinyl polymer according to claim 1 , which yields a cured product with smaller mass change between before and after immersion than that of a cured product from a polymer obtained by replacing the repeating unit in the main chain thereof with butyl acrylate alone, in the immersion test according to JIS K 6258 for the land use 3-5 lubricating oil specified in JIS K 2215.
4. The vinyl polymer according to claim 1 , which yields a cured product with smaller volume change between before and after immersion than that of a cured product from a polymer obtained by replacing the repeating unit in the main chain thereof with butyl acrylate alone, in the immersion test according to JIS K 6258 for the land use 3-5 lubricating oil specified in JIS K 2215.
5. The vinyl polymer according to claim 1 , a molecular terminus of the main chain of which is a crosslinkable silyl group.
6. The vinyl polymer according to claim 1 , which has a molecular weight distribution of less than 1.8.
7. The vinyl polymer according to claim 1 , wherein the living radical polymerization is an atom transfer radical polymerization.
8. The vinyl polymer according to claim 7 , wherein a catalyst used for the atom transfer radical polymerization is a transition metal complex containing a central metal selected from the group consisting of an element belonging to the group 7, 8, 9, 10 or 11 of the periodic table.
9. The vinyl polymer according to claim 8 , wherein the metal complex used for the catalyst is a complex selected from the group consisting of copper, nickel, ruthenium or iron complex.
10. The vinyl polymer according to claim 9 , wherein the metal complex is a copper complex.
11. A curable composition which comprises 100 parts by weight of the vinyl polymer according to claim 1 and 0.1 to 20 parts by weight of a curing catalyst.
12. The curable composition according to claim 11 , which comprises a curing catalyst containing tin.
13. A curable composition which comprises 100 parts by weight of the vinyl polymer according to claim 1 and 0.1 to 20 parts by weight of an adhesiveness-providing agent.
14. The curable composition according to claim 13 , wherein the adhesiveness-providing agent is a silane coupling agent.
15. A curable composition which comprises
100 parts by weight of the vinyl polymer according to claim 1 , and
5 to 150 parts by weight of a plasticizer.
16. The curable composition according to claim 15 , wherein the plasticizer is a phthalic acid plasticizer.
17. The curable composition according to claim 15 , wherein the plasticizer is a polymer plasticizer.
18. A curable composition which comprises
100 parts by weight of the vinyl polymer according to claim 1 , and
5 to 1000 parts of a filler.
19. The curable composition according to claim 18 , which comprises at least one member selected from the group consisting of silica, calcium carbonate and carbon black.
20. The vinyl polymer according to claim 1 ,
wherein the vinyl polymer is a copolymer of ethyl acrylate, butyl acrylate and 2-methoxyethyl acrylate.
21. The vinyl polymer according to claim 20 ,
wherein the vinyl polymer is a copolymer of ethyl acrylate/butyl acrylate/2-methoxyethyl acrylate at a weight ratio of 40 to 50/20 to 30/30 to 20.