High-tensile steel with excellent weldability and toughness and with tensile strength of 550 MPa class or more and method of production of the same
View Patent ↗The present invention provides a high-tensile steel material having a tensile strength of the 550 MPa class or more which can simultaneously raise the strength and toughness of the heat affected zone of weld to equal those of the matrix and a method of production of the same, that is, a high-tensile steel material with excellent weldability and toughness and with tensile strength of the 550 MPa class or more containing, by mass %, C: 0.005 to 0.10%, W: 0.10 to 3.0%, Nb: 0.010 to 0.080%, and V: 0.010 to 0.50%, limiting the Ti to less than 0.005%, satisfying equation; EC=2[C]−[Nb]/9−[V]/12>0.020, having an amount of precipitation of W contained in the steel material, in terms of analytical value obtained by quantitative analysis of potential electrolysis extraction residue by fluorescent X-ray analysis, of 0.0050% or less, and having 60% or more of its structural composition in a cross-section of the steel as a bainite structure.
1. High-tensile steel material with excellent weldability and toughness, and with a tensile strength in at least the 550 MPa class, the high-tensile steel material consisting of, by mass %:
C: 0.005 to 0.10%,
Si: 0.01 to 0.40%,
Mn: 0.10 to 3.0%,
Al: 0.010 to 0.10%,
W: 0.10 to 3.0%,
V: 0.010 to 0.50%, and
Nb: 0.010 to 0.080%, and
a balance of Fe and unavoidable impurities, wherein
B: 0.0003 to 0.0035%, Ca: 0.0003 to 0.0045%, Mg: 0.0003 to 0.0045%, Y: 0.001 to 0.050%, Ce: 0.001 to 0.050%, and La: 0.001 to 0.050% are optionally present, and
P, S, N, O, and Ti are present at most as impurities in amounts of: to
P: 0.020% or less,
S: 0.0040% or less,
N: 0.006% or less,
O: 0.0060% or less,
Ti: less than 0.005%, and
Cr: 0.020 to 0.60%; wherein
EC* as given by the following equation is greater than 0.020:
EC*= 2[ C ]−[ Nb ]/9−[ V ]/12−[ M ]
where, [M]=[Cr]/23, and
where [C], [Nb], [V], and [Cr] represent the mass % of C, Nb, and V; and wherein
W precipitation is present in the steel material in an amount of 0.0050 mass % or less, based on an analytical value obtained by quantitative analysis of potential electrolysis extraction residue by fluorescent X-ray analysis, and
60 area % or more of the structural composition of the high-tensile steel material in a cross-section of the steel has a bainite structure.
2. The high-tensile steel material according to claim 1 , wherein the W is present in an amount of 0.851 to 3.0%.
3. High-tensile steel material with excellent weldability and toughness, and with a tensile strength in at least the 550 MPa class, the high-tensile steel material consisting of, by mass %,
C: 0.005 to 0.10%,
Si: 0.01 to 0.40%,
Mn: 0.10 to 3.0%,
Al: 0.010 to 0.10%,
W: 0.10 to 3.0%,
V: 0.010 to 0.50%,
Nb: 0.010 to 0.080%, and
a balance of Fe and unavoidable impurities, wherein
one or more of
Ni: 0.010 to 0.50%,
Cu: 0.010 to 0.50%, and
Co: 0.010 to 0.50% are optionally present, and
one or more of B: 0.0003 to 0.0035%, Ca: 0.0003 to 0.0045%, Mg: 0.0003 to 0.0045%, Y: 0.001 to 0.050%, Ce: 0.001 to 0.050%, and La: 0.001 to 0.050% are optionally present, and
P, S, N, O, and Ti are present at most as impurities in amounts of:
P: 0.020% or less,
S: 0.0040% or less,
N: 0.006% or less,
O: 0.0060% or less, and
Ti: less than 0.0038%, wherein
EC given by the following equation is greater than 0.020:
EC= 2[ C ]−[ Nb ]/9−[ V ]/12, wherein
[C], [Nb], [V] represent the mass % of C, Nb, and V; and wherein
W precipitation is present in the steel material in an amount of 0.0039 mass % or less, based on an analytical value obtained by quantitative analysis of potential electrolysis extraction residue by fluorescent X-ray analysis, and
60 area % or more of the structural composition of the high-tensile steel material in a cross-section of the steel has a bainite structure.
4. The high-tensile steel material according to claim 3 , wherein the W is present in an amount of 0.851 to 3.0%.
5. A method of production of high-tensile steel material according to claim 3 , with excellent weldability and toughness and with tensile strength of the 550 MPa class or more, wherein 60% or more of the structural composition of the high-tensile steel material in a cross-section of the steel has a bainite structure, and W precipitation is present in the high tensile steel material in an amount of 0.0050% or less, based on an analytical value obtained by quantitative analysis of potential electrolysis extraction residue by fluorescent X-ray analysis, the method comprising:
rough rolling and final rolling a steel slab without heating or heating by sensible heat after casting,
then immediately cooling the rolled slab by accelerated or natural cooling at a cooling rate of 1° C./s or more to provide a rolled steel having a bainite structure,
raising the temperature of the cooled rolled steel to a temperature of 200° to 700° C. in time period of 1 to 240 minutes,
holding the heated steel at 200° to 700° C. for 10 minutes to 10 hours, and
then cooling the heated steel by accelerated or natural cooling at a cooling rate of 1° C./s or more; wherein
the steel slab comprises, by mass %, C: 0.005 to 0.10%, Si: 0.01 to 0.40%, Mn: 0.10 to 3.0%, Al: 0.010 to 0.10%, W: 0.10 to 3.0%, V: 0.010 to 0.50%, Nb: 0.010 to 0.080%, and a balance of Fe and unavoidable impurities, wherein
P, S, N, O, and Ti are present at most as impurities in amounts of: P: 0.020% or less, S: 0.0040% or less, N: 0.006% or less, O: 0.0060% or less, and Ti: less than (0.005%) 0.0038%.