Pressureless polymer pipe, a compositon therefore, and a process for preparing it
View Patent ↗A pressureless polymer pipe, a composition therefore, and a process of preparing the composition are described. The pipe is characterized in that the polymer comprises a propylene polymer composition where the propylene base polymer is a heterophasic propylene copolymer having a matrix of a propylene homopolymer and a dispersed phase of an elastomeric copolymer of propylene and at least one olefin comonomer; has a comonomer content of 2-7% by weight, based on the weight of the heterophasic propylene copolymer; has a melt flow rate MFR (2/230), determined according to ISO 1133 C4, of 0.1-2.0 g/10 min; has a broad molecular weight distribution as defined by its rheology shear thinning index, SHI 0/50 , measured at 200° C. of 9-30; has a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min and 23° C. of at least 1800 MPa; has an impact strength, determined according to ISO 179/1 eA of at least 6 kJ/m 2 at 0° C. and at least 2 kJ/m 2 at −20° C. The composition is a polymer composition as defined above. The process is characterized by polymerizing in the presence of a stereospecific Ziegler-Natta catalyst including an electron donor:(i) a propylene homopolymer matrix in at least one loop reactor at a temperature of at least 80° C. and a pressure of 4600-10000 kPa; and (ii) an elastomeric copolymer of propylene and at least one olefin comonomer in at least one gas-phase reactor at a lower temperature than in stage (i); to obtain a base polymer of heterophasic propylene copolymer as defined above.
1. A pressureless polymer pipe, wherein the polymer pipe comprises a propylene polymer composition comprising a propylene base polymer, wherein the propylene base polymer is a heterophasic propylene copolymer having a matrix of a multimodal propylene homopolymer, wherein the multimodal propylene homopolymer is produced in two or more reactors in series in the presence of different concentrations of hydrogen, and a dispersed phase of an elastomeric copolymer of propylene and at least one olefin comonomer;
has a comonomer content of 2-7% by weight, based on the weight of the heterophasic propylene copolymer;
has a melt flow rate MFR (2/230), determined according to ISO 1133 C4, of 0.1-2.0 g/10 min;
has a broad molecular weight distribution as defined by its rheology shear thinning index, SHI 0/50 , measured at 200° C. of 9-30;
has a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min and 23° C. of at least 1800 MPa;
has an impact strength, determined according to ISO 179/1 eA of at least 6 kJ/m 2 at 0° C. and at least 2 kJ/m 2 at −20° C.;
the propylene polymer composition comprises a nucleating agent;
the heterophasic propylene copolymer has a content of xylene soluble material (XS) of 4-10% by weight, and
the pipe has an E modulus, calculated from the ring stiffness, determined according to EN ISO 9969 for a pipe having a diameter of 110 mm and a wall thickness of 4 mm at 23° C., of at least 1800 MPa, said calculation being made according to formula (I):
E =Ring stiffness×12×[( D−t )/ t] 3 (I)
where
E is the elasticity modulus in MPa,
D is the outer diameter of the pipe in mm, and
t is the wall thickness of the pipe in mm.
2. The pipe according to claim 1 , wherein the olefin comonomer is at least one olefin selected from the group of consisting of ethylene and C 4 -C 10 -α-olefins.
3. The pipe according to claim 1 , wherein the comonomer is ethylene.
4. The pipe according to claim 1 , wherein the propylene polymer composition comprises adjuvants selected from additives, fillers and reinforcing agents.
5. The pipe according to claim 4 , wherein the composition comprises talc in an amount of up to 30% by weight.
6. The pipe according to claim 1 , wherein the propylene base polymer has a tensile modulus of up to 2500 MPa.
7. The pipe according to claim 1 , wherein the heterophasic propylene copolymer has a melt flow rate MFR (2/230) of 0.2-0.5 g/10 min.
8. The pipe according to claim 1 , wherein the pipe has a pipe pressure resistance, determined according to EN 921 in water conditions on a pipe with 32 mm/3.0 mm or 110 mm/4.0 mm outer diameter/wall thickness, of more than 200 hrs at 4.2 MPa/80° C. and more than 1500 hrs at 2.5 MPa/95° C.
9. A propylene polymer composition for a pressureless polymer pipe, wherein the propylene polymer composition comprises a propylene base polymer and the propylene base polymer is a heterophasic propylene copolymer comprising a matrix of a multimodal propylene homopolymer, wherein the multimodal propylene homopolymer is produced in two or more reactors in series in the presence of different concentrations of hydrogen, and a dispersed phase of an elastomeric copolymer of propylene and at least one olefin comonomer;
has a comonomer content of 2-7% by weight, based on the weight of the heterophasic propylene copolymer;
has a melt flow rate MFR (2/230), determined according to ISO 1133 C4, of 0.1-2.0 g/10 min;
has a broad molecular weight distribution as defined by its rheology shear thinning index, SHI 0/50 , measured at 200° C. of 9-30;
has a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min and 23° C. of at least 1800 MPa;
has an impact strength, determined according to ISO 179/1 eA of at least 6 kJ/m 2 at 0° C. and at least 2 kJ/m 2 at −20° C.;
the propylene polymer composition comprises a nucleating agent, and
the heterophasic propylene copolymer has a content of xylene soluble material (XS) of 4-10% by weight.
10. The composition according to claim 9 , wherein the olefin comonomer is at least one olefin selected from the group consisting of ethylene and C 4 -C 10 -α-olefins.
11. The composition according to claim 9 , wherein the olefin comonomer is ethylene.
12. The composition according to claim 9 , wherein the composition includes adjuvants selected from the group consisting of additives, fillers and reinforcing agents.
13. The composition according to claim 9 , wherein the heterophasic propylene copolymer has a melt flow rate MFR (2/230) of 0.2-0.5 g/10 min.
14. A process of preparing a polymer composition for a pressureless polymer pipe according to claim 9 , wherein the process comprises polymerizing in the presence of a stereospecific Ziegler-Natta catalyst including an electron donor:
(i) a propylene homopolymer matrix in at least one loop reactor at a temperature of at least 80° C. and a pressure of 4600-10000 kPa and at least one other reactor in series wherein the loop reactor and the at least one other reacter are provided having different concentrations of hydrogen to produce a multimodal propylene homopolymer; and
(ii) an elastomeric copolymer of propylene and at least one olefin comonomer in at least one gas-phase reactor at a lower temperature than in stage (i);
to obtain a base polymer of heterophasic propylene copolymer comprising a matrix of a multimodal propylene homopolymer, and a dispersed phase of said elastomeric propylene copolymer; said heterophasic propylene copolymer having
a comonomer content of 2-7% by weight, based on the weight of the heterophasic propylene copolymer;
a melt flow rate MFR (2/230), determined according to ISO 1133 C4, of 0.1-2.0 g/10 min;
a broad molecular weight distribution as defined by its rheology shear thinning index, SHI0 0/50 , measured at 200° C. of 9-30;
a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min and 23° C. of at least 1800 MPa;
an impact strength, determined according to ISO 179/1 eA of at least 6 kJ/m 2 at 0° C. and at least 2 kJ/m 2 at −20° C.; and
a content of xylene soluble material (XS) of 4-10% by weight;
and the propylene polymer composition comprises a nucleating agent.
15. The process according to claim 14 , wherein said at least one olefin comonomer is selected from the group of consisting of ethylene and C 4 -C 10 -α-olefins.
16. The process according to claim 14 , wherein the olefin comonomer is ethylene.
17. The process according to claim 14 , wherein stage (i) comprises polymerizations in a loop reactor and a gas-phase reactor.
18. The process according to claim 14 , wherein the polymerization in the loop reactor is carried out at supercritical conditions.
19. The process according to claim 18 , wherein the polymerization in the loop reactor is carried out at a temperature of 92-100° C. and a pressure of 4600-10000 kPa.
20. The process according to claim 14 , wherein the polymerization in stage (ii) is carried out at a temperature of 40-90° C. and a pressure of 500-3000 kPa.
21. The process according to claim 17 , wherein the polymerization in the gas-phase reactor of stage (i) is carried out at a temperature of 50-115° C. and a pressure of 500-5000 kPa.