Semiconductive polymer composition
View Patent ↗A semiconductive polymer composition for use in power cables, wherein the composition has a multimodal ethylene homo- or copolymer produced in a polymerization process having a single site catalyst whereby the polymer composition has a density of 870-930 kg/m 3 , a MFR 2 of 1 to 30 g/10 min and a Mw/Mn of less than or equal to 10.
1. A semiconductive polymer composition comprising:
a multimodal ethylene homo- or copolymer, produced in a polymerisation process comprising a single site catalyst;
up to 10 wt % polar copolymer; and
carbon black;
wherein the polymer composition has a density of 870 to 930 kg/m 3 , a MFR 2 of 1 to 30 g/10 min and a Mw/Mn of less than or equal to 10, whereby the ranges given are measured without additives.
2. A polymer composition according to claim 1 , wherein the composition has a Mw/Mn of greater than or equal to 2.0.
3. A polymer composition according to claim 2 , wherein the multimodal ethylene homo- or copolymer is a bimodal ethylene homo- or copolymer.
4. A polymer composition according to claim 1 , wherein the multimodal ethylene homo- or copolymer is a bimodal ethylene homo- or copolymer.
5. A polymer composition according to claim 1 , wherein the copolymer comprises at least one C 3 -C 8 alpha-olefin.
6. A polymer composition according to claim 1 , wherein the polar copolymer is a high pressure copolymer.
7. A polymer composition according to claim 6 , wherein the high pressure polymer is selected from the group consisting of ethylene-butyl-acrylate, ethylene-ethyl-acrylate and ethylene-methyl-acrylate, ethylene-vinyl-acrylate.
8. A polymer according to claim 7 , wherein the polar copolymer contains 5-30 wt % of polar comonomers.
9. A polymer composition according to claim 6 , wherein the copolymer is a vinyl-silane-copolymer.
10. A polymer composition according to claim 1 , wherein the carbon black is acetylene black.
11. A polymer composition according to claim 10 , wherein the carbon black is present in an amount of less than or equal to 40 wt % of the total composition.
12. A polymer composition according to claim 1 , wherein the carbon black is present in an amount of less than or equal to 40 wt % of the total composition.
13. A polymer composition according to claim 12 , wherein the carbon black is present in an amount of 10-35 wt % of the total composition.
14. A polymer composition according to claim 1 , wherein the composition is partially cross-linked.
15. A polymer composition according to claim 1 , wherein the polymer composition is extrudable at a temperature of less than 120°C.
16. A process for producing a polymer in accordance with claim 1 , wherein in a first stage a first fraction is produced, and in a second stage a second fraction is produced in the presence of a single site catalyst.
17. A process according to claim 16 , wherein in the first stage a loop reactor is used, and in the second stage a gas phase reactor is used.
18. An insulted electric DC-cable comprising a conductor, an inner semiconductive layer, an insulating layer and an outer semiconductive layer whereby at least one of the two semiconductive layers comprises a composition according to claim 1 .
19. An insulated electric cable according to claim 18 , wherein the insulating layer comprises a multimodal ethylene polymer produced in a process comprising a single site catalyst.
20. An insulated electric AC-cable comprising a conductor, an inner semiconductive layer, an insulating layer and an outer semiconductive layer whereby at least one of the two semiconductive layers comprises a composition according to claim 1 .
21. An insulated electric cable according to claim 20 , wherein the insulating layer comprises a multimodal ethylene polymer produced in a process comprising a single site catalyst.