Polyurethane elastomer of high quality
View Patent ↗The present invention relates to cast polyurethane elastomers of high resilience, clarity, and attractive abrasion resistance derived from polyurethane systems comprising a customized selection of polycaprolactone polyol incorporated into the isocyanate and/or isocyanate-reactive composition.
1. A roller skate or roller blade wheel molded or shaped from a thermoset polyurethane elastomer comprising the reaction product of:
(a) a urethane-modified isocyanate, wherein said urethane-modified isocyanate comprises the reaction product of an aromatic polyisocyanate comprising methylene diphenylisocyanate with a polycaprolactone polyol and/or a caprolactone ether copolymer polyol, wherein said polycaprolactone polyol or said caprolactone ether copolymer polyol each has a molecular weight in the range of from 1,000 to 10,000 Dalton, wherein the methylene diphenylisocyanate comprises at least 80 percent by weight of the 4,4′-methylene diphenylisocyanate isomer;
(b) isocyanate reactive components comprising:
a polycaprolactone polyol and/or a caprolactone ether copolymer polyol, wherein said polycaprolactone polyol or said caprolactone ether copolymer polyol each have an average molecular weight of greater than 1000 Dalton; in the presence of a polycaprolactone polyol and/or a polyether polyol, wherein said polycaprolactone polyol or said polyether polyol each have an average molecular weight of 300 to 900 Dalton; and in the presence of an aliphatic chain extending agent which is a diol having from 2 to 16 carbon atoms;
wherein thermoset polyurethane elastomer has a rebound-resilience of at least 50 percent, according to test procedure ASTM-D-2632, a clarity index of at least 80 percent, and an abrasion resistance (loss) of less than 15 mg/1000 cycles, according to test procedure ASTM D-3389.
2. The roller skate or roller blade wheel according to claim 1 wherein the methylene diphenylisocyanate comprises at least 85 percent by weight of the 4,4′-methylene diphenylisocyanate isomer.
3. The roller skate or roller blade wheel according to claim 1 wherein the urethane-modified isocyanate has an isocyanate content of from 5 to 15 weight percent.
4. The roller skate or roller blade wheel according to claim 1 .