Sodium percarbonate particles having a shell layer comprising thiosulfate
View Patent ↗Coated sodium percarbonate particles, having an inner shell layer which comprises at least one inorganic, hydrate-forming salt as the main constituent, and an outer shell layer which comprises an alkali metal thiosulfate, an alkaline earth metal thiosulfate and/or an ammonium thiosulfate, are stable to storage and have an improved storage stability in detergents and cleaning agents. Detergents and cleaning agents which comprise such sodium percarbonate particles show a reduced oxidative attack on oxidation-sensitive constituents of the composition during storage. Machine dishwashing agents in the form of tablets which comprise such sodium percarbonate particles and a corrosion protection agent for silver show a reduced yellowing of the tablets during storage.
1. Coated sodium percarbonate particles, comprising
a) a core of sodium percarbonate;
b) an inner shell layer comprising at least one inorganic, hydrate-forming salt as the main constituent; and
c) an outer shell layer comprising an alkali metal thiosulfate, an alkaline earth metal thiosulfate and/or an ammonium thiosulfate.
2. The sodium percarbonate particles of claim 1 , wherein said core has been prepared by fluidized bed build-up granulation or by crystallization.
3. The sodium percarbonate particles of claim 1 , wherein said inner shell layer constitutes from 0.1 to 10 wt. % of said coated sodium percarbonate particles.
4. The sodium percarbonate particles of claim 1 , wherein said inner shell layer comprises at least 50 wt. % of said inorganic, hydrate-forming salt.
5. The sodium percarbonate particles of claim 1 , wherein said inorganic, hydrate-forming salt is selected from the group consisting of sodium sulfate, sodium carbonate, sodium bicarbonate, magnesium sulfate, and mixtures or mixed salts of these compounds.
6. The sodium percarbonate particles of claim 1 , wherein said inorganic, hydrate-forming salt is sodium sulfate.
7. The sodium percarbonate particles of claim 1 , wherein said inner shell consists of sodium sulfate.
8. The sodium percarbonate particles of claim 1 , wherein said outer shell layer constitutes from 0.1 to 10 wt. % of said coated sodium percarbonate particles.
9. The sodium percarbonate particles of claim 1 , wherein said outer shell layer comprises at least 50 wt. %. of said alkali metal thiosulfate, alkaline earth metal thiosulfate and/or ammonium thiosulfate.
10. The sodium percarbonate particles of claim 1 , wherein said outer shell layer comprises sodium thiosulfate.
11. The sodium percarbonate particles of claim 1 , wherein said outer shell layer consists of sodium thiosulfate.
12. The sodium percarbonate particles of claim 1 , further comprising an additional shell layer which comprises an alkali metal silicate having a modulus of SiO 2 to alkali metal oxide of more than 2.5 as a main constituent.
13. The sodium percarbonate particles of claim 1 , comprising additionally on their surface 0.01 to 1 wt. % of a hydrophobized finely divided oxide of the elements Si, Al or Ti or of a mixed oxide of these elements.
14. The sodium percarbonate particles of claim 13 , wherein said finely divided oxide is a hydrophobized pyrogenic or precipitated silica.
15. A process for the preparation of coated sodium percarbonate particles, comprising the steps of:
a) applying an inner shell layer to a core material of sodium percarbonate by spraying on an aqueous solution in which at least one hydrate-forming inorganic salt is dissolved and
b) applying an outer shell layer to the coated material from step a) by spraying on an aqueous solution in which at least one alkali metal thiosulfate, alkaline earth metal thiosulfate and/or ammonium thiosulfate is dissolved.
16. The process of claim 15 , wherein said core material is prepared by fluidized bed build-up granulation by spraying an aqueous hydrogen peroxide solution and an aqueous soda solution into a fluidized bed of sodium percarbonate particles and simultaneously evaporating water.
17. The process of claim 15 , wherein in steps a) and b) the application of said shell layers is carried out by spraying in a fluidized bed and more than 90% of the water contained in said aqueous solutions is evaporated during the application of the shell layers.
18. A detergent or cleaning agent comprising the coated sodium percarbonate particles of claim 1 .
19. The detergent or cleaning agent of claim 18 , comprising 1 to 40 wt % of said sodium percarbonate particles.
20. The detergent or cleaning agent of claim 18 , comprising pressed shaped bodies wherein said sodium percarbonate particles are a constituent of said pressed shaped bodies.
21. A machine dishwashing agent in the form of tablets, comprising the coated sodium percarbonate particles of claim 1 and a corrosion protection agent for silver.
22. The machine dishwashing agent of claim 21 , wherein said corrosion protection agent for silver one or more compounds is selected from the group consisting of: triazoles, benzotriazoles, bisbenzotriazoles, aminotriazoles, alkylaminotriazoles and transition metal complexes thereof.