Strain sensor and method for manufacture thereof

1. A strain sensor comprising:

a substrate;

a crystallized glass laminated on the substrate;

a strain sensitive resistor laminated on the crystallized glass; and

a noncrystalline glass interposed between the crystallized glass and the strain sensitive resistor,

wherein the crystallized glass is a composite crystallized glass formed by baking plural types of crystallized glass powder mutually different in thermomechanical constant.

2. The strain sensor of claim 1 , wherein the thermomechanical constant is a crystallizing temperature.

3. The strain sensor of claim 2 , wherein the crystallized glass powder further contains at least one of ceramic powder and noncrystalline glass powder.

4. The strain sensor of claim 1 , wherein the thermomechanical constant is a coefficient of thermal expansion.

5. The strain sensor of claim 4 , wherein the crystallized glass powder further contains at least one of ceramic powder and noncrystalline glass powder.

6. The strain sensor of claim 1 , wherein the thermomechanical constant is a transition point temperature.

7. The strain sensor of claim 6 , wherein the crystallized glass powder further contains at least one of ceramic powder and noncrystalline glass powder.

8. The strain sensor of claim 1 , wherein the substrate is a metal substrate.

9. The strain sensor of claim 1 , wherein the noncrystalline glass is 5 to 50 μm.

10. The strain sensor of claim 1 , wherein a plurality of the strain sensitive resistors are formed to constitute a bridge circuit by way of wiring, and the mutual resistance values are within a range of plus or minus 5%.

11. The strain sensor of claim 1 , wherein an internal electrode of thickness of 0.5 to 30 μm is embedded inside of the composite crystallized glass.

12. The strain sensor of claim 1 , wherein the composite crystallized glass is formed by baking plural types of crystallized glass powder forming crystal seeds composed of at least two elements or more selected from the group of Ba, Mg, and Si.

13. The strain sensor of claim 12 , wherein the composite crystallized glass powder forms crystal seeds composed of BaMg 2 SiO 7 .

14. The strain sensor of claim 1 , wherein the composition of different types of crystallized glass powder is composed of MgO by 35 to 50 wt. %, B 2 O 3 by 10 to 30 wt. %, SiO 2 by 10 to 25 wt. %, BaO by 3 to 25 wt. %, Al 2 O 3 by 1 to 30 wt. %, SnO 2 by 1 to 5 wt. %, and P 2 O 5 by 5 wt. % or less, and at least one of the differences in contents of the group consisting of MgO, BaO, and Al 2 O 3 is in a range of 1 to 20 wt. %.

15. The strain sensor of claim 1 , wherein the composition of different types of crystallized glass powder is composed of MgO by 35 to 50 wt. %, B 2 O 3 by 10 to 30 wt. %, SiO 2 by 10 to 25 wt. %, BaO by 3 to 25 wt. %, Al 2 O 3 by 1 to 30 wt. %, SnO 2 by 1 to 5 wt. %, and P 2 O 5 by 5 wt. % or less, and the difference in contents of SiO 2 and B 3 O 3 is in a range of 0.1 to 10 wt. %.

16. The strain sensor of claim 1 , wherein the average particle size of plural types of crystallized glass powder is 0.5 to 20 μm.

17. The strain sensor of claim 16 , wherein the difference in the average particles sizes of plural types of crystallized glass powder is 5 μm or less.

18. The strain sensor of any one of claims 3 to 7 , wherein the noncrystalline glass is composed of SiO 2 by 40 to 80 wt. %, CaO by 5 to 15 wt. %, PbO by 3 to 15 wt. %, Al 2 O 3 by 1 to 20 wt. %, and ZrO 2 by 1 to 20 wt. %.

19. The strain sensor of any one of claims 3 to 7 , wherein the content of the ceramic powder is 1 to 30 parts by weight in 100 parts by weight of the crystallized glass powder.

20. The strain sensor of any one of claims 3 to 7 , wherein the ceramic powder is oxide or hydroxide of average particle size of 0.1 to 10 μm.

21. The strain sensor of any one of claims 3 to 7 , wherein the ceramic powder is at least one oxide or hydroxide of the group consisting of aluminum, magnesium, zirconium, calcium, and silicon.