Poly(arylene ether) composition, method, and article
View Patent ↗A thermoplastic composition includes particular amounts of a poly(arylene ether), a hydrogenated block copolymer, a plasticizer, a white pigment, and an ultraviolet radiation stabilizer. The composition exhibits excellent light stability, and it is particularly useful for forming white or off-white cable insulation.
1. A composition, comprising:
about 10 to about 45 weight percent of a poly(arylene ether);
about 9 to about 80 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene;
about 8 to about 25 weight percent of a plasticizer;
about 1 to about 12 weight percent of a white pigment; and
about 0.1 to about 5 weight percent of an ultraviolet radiation stabilizer;
wherein the hydrogenated block copolymer and the poly(arylene ether) are present in a weight ratio of about 0.3:1 to about 4:1;
wherein the composition comprises less than or equal to 20 weight percent of rubber-modified polystyrene;
wherein the composition is substantially free of polyethylene homopolymers and polypropylene homopolymers;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition exhibits
a CIE lightness value, L*, value of at least 70 measured according to ASTM D2244, and
a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 300 hours exposure to xenon arc exposure according to ASTM D4459.
2. The composition of claim 1 , exhibiting a CIE lightness value, L*, value of at least 80.
3. The composition of claim 1 , exhibiting a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 500 hours exposure to xenon arc exposure according to ASTM D4459.
4. The composition of claim 1 , exhibiting a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 1000 hours exposure to xenon arc exposure according to ASTM D4459.
5. The composition of claim 1 , exhibiting a flexural modulus less than or equal to 300 megapascals, measured at 23° C. according to ASTM D790.
6. The composition of claim 1 , exhibiting a tensile elongation at 23° C. greater than or equal to 100 percent, measured according to ASTM D638.
7. The composition of claim 1 , wherein hydrogenated block copolymer of is a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer.
8. The composition of claim 1 , wherein at least a portion of the hydrogenated block copolymer is provided in the form of a melt-kneaded blend comprising hydrogenated block copolymer, and further comprising an ethylene-propylene copolymer, and mineral oil.
9. The composition of claim 1 , wherein the hydrogenated block copolymer and the poly(arylene ether) are present in a weight ratio of about 1.2:1 to about 3:1.
10. The composition of claim 1 , wherein the plasticizer is selected from the group consisting of benzoate esters, pentaerythritol esters, phthalate esters, trimellitate esters, pyromellitate esters, triaryl phosphates, and mixtures thereof.
11. The composition of claim 1 , wherein the plasticizer is a triaryl phosphate.
12. The composition of claim 1 , wherein the plasticizer is bisphenol A bis(diphenyl phosphate).
13. The composition of claim 1 , wherein the white pigment is zinc sulfide, titanium dioxide, or a mixture thereof.
14. The composition of claim 1 , wherein the ultraviolet radiation stabilizer is a UV absorber selected from the group consisting of benzophenone UV absorbers, benzotriazole UV absorbers, hindered amine light stabilizers, cinnamate UV absorbers, oxanilide UV absorbers, 2-(2′-hydroxyphenyl)-1,3,5-triazine UV absorbers, benzoxazinone-type UV absorbers, and mixtures thereof.
15. The composition of claim 14 , wherein the ultraviolet radiation stabilizer further comprises a cycloaliphatic epoxy compound.
16. The composition of claim 1 , further comprising a polybutene.
17. The composition of claim 16 , wherein the polybutene has a number average molecular weight of about 700 to about 1,000 atomic mass units.
18. The composition of claim 1 , further comprising 0.5 to about 6 weight percent of a copolymer of ethylene and a C 3 -C 12 alpha-olefin.
19. The composition of claim 18 , wherein the copolymer of ethylene and a C 3 -C 12 alpha-olefin is an ethylene-propylene rubber.
20. The composition of claim 1 , wherein the composition excludes copolymers of ethylene and a C 3 -C 12 alpha-olefin copolymer.
21. The composition of claim 1 , wherein the composition excludes polyethylene homopolymers and polypropylene homopolymers.
22. The composition of claim 1 , further comprising about 2 to about 20 weight percent of mineral oil.
23. The composition of claim 1 , further comprising a flame retardant selected from the group consisting of magnesium hydroxide, melamine phosphate, melamine pyrophosphate, melamine polyphosphate, and combinations thereof.
24. The composition of claim 1 , further comprising a flame retardant comprising magnesium hydroxide and melamine polyphosphate; wherein the composition exhibits a UL94 rating of V-0 at a thickness of 3.2 millimeters.
25. The composition of claim 1 , further comprising a flame retardant comprising magnesium hydroxide and melamine polyphosphate; wherein the composition exhibits a UL94 rating of V-1 at a thickness of 3.2 millimeters.
26. The composition of claim 1 , comprising a dispersed phase comprising the poly(arylene ether), and a continuous phase comprising the hydrogenated block copolymer.
27. A composition, comprising:
about 18 to about 30 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether);
about 23 to about 35 weight percent of a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer;
about 4 to about 10 weight percent of a polybutene;
about 0.5 to about 3 weight percent of an ethylene-propylene rubber;
about 3 to about 10 weight percent of mineral oil;
about 8 to about 16 weight percent of bisphenol A bis(diphenyl phosphate);
about 2 to about 10 weight percent of magnesium hydroxide;
about 4 to about 16 weight percent of melamine polyphosphate;
about 2 to about 6 weight percent of titanium dioxide;
about 0.1 to about 0.6 weight percent of a cycloaliphatic epoxy resin;
about 0.3 to about 1 weight percent of a hydroxyphenyl benzotriazole; and
about 0.6 to about 1.5 weight percent of a bis(piperidinyl) sebacate;
wherein the composition is substantially free of rubber-modified polystyrene, polyethylene homopolymer, and polypropylene homopolymer;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition exhibits
a CIE lightness value, L*, value of about 80 to about 90,
a CIE a* value of about −1.5 to about 0.5,
a CIE b* value of about −2.5 to about 1.5,
a CIELAB color shift, ΔE, of about 0.1 to about 2, measured according to ASTM D2244 after 300 hours exposure to xenon arc exposure according to ASTM D4459, and
a flexural modulus of about 50 to about 100 megapascals, measured at 23° C. according to ASTM D790.
28. The composition of claim 27 , wherein the composition exhibits a color shift, ΔE, of about 0.1 to about 2, measured according to ASTM D2244 after 500 hours exposure to xenon arc exposure according to ASTM D4459.
29. The composition of claim 27 , wherein the composition exhibits a color shift, ΔE, of about 0.1 to about 2, measured according to ASTM D2244 after 1,000 hours exposure to xenon arc exposure according to ASTM D4459.
30. A method of preparing a thermoplastic composition, comprising:
melt kneading
about 10 to about 45 weight percent of a poly(arylene ether),
about 9 to about 80 weight percent of a hydrogenated block copolymer of
an alkenyl aromatic compound and a conjugated diene,
about 8 to about 25 weight percent of a plasticizer,
about 1 to about 12 weight percent of a white pigment, and
about 0.1 to about 5 weight percent of an ultraviolet radiation stabilizer;
wherein the hydrogenated block copolymer and the poly(arylene ether) are present in a weight ratio of about 0.3:1 to about 4:1;
wherein the composition comprises less than or equal to 20 weight percent of rubber-modified polystyrene;
wherein the composition is substantially free of polyethylene homopolymer and polypropylene homopolymer;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition exhibits
a CIE lightness value, L*, value of at least 70 measured according to ASTM D2244, and
a CIE color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 300 hours exposure to xenon arc exposure according to ASTM D4459.
31. The method of claim 30 , wherein the poly(arylene ether) and the plasticizer are blended with each other before being blended with the hydrogenated block copolymer.
32. The method of claim 30 , wherein the poly(arylene ether), the plasticizer, and the ultraviolet radiation stabilizer are blended with each other before being blended with the hydrogenated block copolymer.
33. A method of preparing a thermoplastic composition, comprising:
melt kneading
about 18 to about 30 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether);
about 23 to about 35 weight percent of a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer;
about 4 to about 10 weight percent of a polybutene;
about 0.5 to about 3 weight percent of an ethylene-propylene rubber;
about 3 to about 10 weight percent of mineral oil;
about 8 to about 16 weight percent of bisphenol A bis(diphenyl phosphate);
about 2 to about 10 weight percent of magnesium hydroxide;
about 4 to about 16 weight percent of melamine polyphosphate;
about 2 to about 6 weight percent of titanium dioxide;
about 0.1 to about 0.6 weight percent of a cycloaliphatic epoxy resin;
about 0.3 to about 1 weight percent of a hydroxyphenyl benzotriazole; and
about 0.6 to about 1.5 weight percent of a bis(piperidinyl) sebacate;
wherein the composition is substantially free of rubber-modified polystyrene, polyethylene homopolymer, and polypropylene homopolymer;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition exhibits
a CIE lightness value, L*, value of about 80 to about 90,
a CIE a* value of about −1.5 to about 0.5,
a CIE b* value of about −2.5 to about 1.5,
a CIELAB color shift, ΔE, of about 0.1 to about 2, measured according to ASTM D2244 after 300 hours exposure to xenon arc exposure according to ASTM D4459, and
a flexural modulus of about 50 to about 100 megapascals, measured at 23° C. according to ASTM D790.
34. The method of claim 33 , wherein the poly(2,6-dimethyl-1,4-phenylene ether) and the bisphenol A bis(diphenyl phosphate) are blended with each other before being blended with the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer.
35. The method of claim 33 , wherein the poly(2,6-dimethyl-1,4-phenylene ether), the bisphenol A bis(diphenyl phosphate), the cycloaliphatic epoxy resin, the hydroxyphenyl benzotriazole, and the bis(piperidinyl) sebacate are blended with each other before being blended with the polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer.
36. An article comprising the composition of claim 1 .
37. An article comprising the composition of claim 27 .
38. Cable insulation comprising the composition of claim 1 .
39. Cable insulation comprising the composition of claim 27 .
40. A method of insulating an electrical wire, comprising:
extrusion coating an electrical wire with a composition comprising
about 10 to about 45 weight percent of a poly(arylene ether);
about 9 to about 80 weight percent of a hydrogenated block copolymer of an alkenyl aromatic compound and a conjugated diene;
about 8 to about 25 weight percent of a plasticizer;
about 1 to about 12 weight percent of a white pigment; and
about 0.1 to about 5 weight percent of an ultraviolet radiation stabilizer;
wherein the hydrogenated block copolymer and the poly(arylene ether) are present in a weight ratio of about 0.3:1 to about 4.1;
wherein the composition comprises less than or equal to 20 weight percent of rubber-modified polystyrene;
wherein the composition is substantially free of polyethylene homopolymer and polypropylene homopolymer;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition exhibits
a CIE lightness value, L*, value of at least 70 measured according to ASTM D2244, and
a CIELAB color shift, ΔE, less than or equal to 3 measured according to ASTM D2244 after 300 hours exposure to xenon arc exposure according to ASTM D4459.
41. A method of insulating an electrical wire, comprising:
extrusion coating an electrical wire with a composition comprising
about 18 to about 30 weight percent of a poly(2,6-dimethyl-1,4-phenylene ether);
about 23 to about 35 weight percent of a polystyrene-poly(ethylene-butylene)-polystyrene triblock copolymer;
about 4 to about 10 weight percent of a polybutene;
about 0.5 to about 3 weight percent of an ethylene-propylene rubber;
about 3 to about 10 weight percent of mineral oil;
about 8 to about 16 weight percent of bisphenol A bis(diphenyl phosphate);
about 2 to about 10 weight percent of magnesium hydroxide;
about 4 to about 16 weight percent of melamine polyphosphate;
about 2 to about 6 weight percent of titanium dioxide;
about 0.1 to about 0.6 weight percent of a cycloaliphatic epoxy resin;
about 0.3 to about 1 weight percent of a hydroxyphenyl benzotriazole; and
about 0.6 to about 1.5 weight percent of a bis(piperidinyl) sebacate;
wherein the composition is substantially free of rubber-modified polystyrene, polyethylene homopolymer, and polypropylene homopolymer;
wherein all weight percents are based on the total weight of the composition; and
wherein the composition exhibits
a CIE lightness value, L*, value of about 80 to about 90,
a CIE a* value of about −1.5 to about 0.5,
a CIE b* value of about −2.5 to about 1.5,
a CIELAB color shift, ΔE, of about 0.1 to about 2, measured according to ASTM D2244 after 300 hours exposure to xenon arc exposure according to ASTM D4459, and
a flexural modulus of about 50 to about 100 megapascals, measured at 23° C. according to ASTM D790.
42. The composition of claim 1 , wherein the hydrogenated block copolymer has a weight average molecular weight of about 200,000 to about 400,000 atomic mass units.
43. The composition of claim 1 , wherein the hydrogenated block copolymer and the poly(arylene ether) are present in a weight ratio of about 1.2:1 to about 3:1.