Ethylene/tetrafluoroethylene copolymer composition
View Patent ↗The present invention provides an ethylene/tetrafluoroethylene copolymer composition having a high melt flowability while maintaining satisfactory mechanical properties in the obtainable molded product are maintained. The ethylene/tetrafluoroethylene copolymer composition (C) has a melt viscosity of from 80 to 500 Pa·s, preferably from 100 to 300 Pa·s and a tensile elongation of from 200 to 500%, preferably from 350 to 450%. The copolymer composition (C) is may be obtained by melt kneading an ethylene/tetrafluoroethylene copolymer (A) having a low melt viscosity of from 60 to 400 Pa·s, preferably from 80 to 300 Pa·s and an ethylene/tetrafluoroethylene copolymer (B) having a melt viscosity higher than this i.e. from 600 to 10,000 Pa·s, preferably from 1,000 to 7,000 Pa·s in a mass ratio of (A)/(B)=50/50 to 99/1, preferably (A)/(B)=60/40 to 97/3.
1. An ethylene/tetrafluoroethylene copolymer composition (C) with a high melt flowability, which has a melt viscosity of from 100 to 350 Pa·s and a tensile elongation of from 250 to 450%, and which comprises
an ethylene/tetrafluoroethylene copolymer (A) having a melt viscosity of from 80 to 300 Pa·s and a melting point of 120 to 260° C., and
an ethylene/tetrafluoroethylene copolymer (B) having a melt viscosity of from 1000 to 7,000 Pa·s
in a mass ratio of (A)/(B)=60/40 to 97/3.
2. The ethylene/tetrafluoroethylene copolymer composition (C) according to claim 1 , wherein the tensile elongation is measured according to ASTM D3159.
3. The ethylene/tetrafluoroethylene copolymer composition (C) according to claim 1 , wherein the melt viscosity is measured as follows:
an orifice having a diameter of 1 mm and a length of 10 mm is set on a capillary rheometer “Capriograph,” manufactured by Toyo Seiki Ltd. and a molten ethylene/tetrafluoroethylene copolymer is extruded under such conditions that a cylinder temperature is 240° C. and a piston speed is 10 mm/min and the melt viscosity is measured.
4. The ethylene/tetrafluoroethylene copolymer composition (C) according to claim 1 , wherein the tensile elongation is measured according to ASTM D3159, and wherein the melt viscosity is measured as follows:
an orifice having a diameter of 1 mm and a length of 10 mm is set on a capillary rheometer “Capriograph,” manufactured by Toyo Seiki Ltd. and a molten ethylene/tetrafluoroethylene copolymer is extruded under such conditions that a cylinder temperature is 240° C. and a piston speed is 10 mm/min and the melt viscosity is measured.
5. The ethylene/tetrafluoroethylene copolymer composition (C) according to claim 1 , wherein the melt viscosity is from 100 to 300 Pa·s and the tensile elongation is from 350 to 450%.
6. The ethylene/tetrafluoroethylene copolymer composition (C) according to claim 1 , wherein the mass ratio is (A)/(B)=70/30 to 95/5.
7. A process for producing the ethylene/tetrafluoroethylene copolymer composition (C) as defined in claim 1 , which comprises melting and kneading the ethylene/tetrafluoroethylene copolymer (A) and the ethylene/tetrafluoroethylene copolymer (B).