IP Library Granted Patent US 8,419,868
Granted Patent B2
US 8,419,868 · App. 11/690,763 · Granted Apr 16, 2013

Process and method to increase the hardness of Fe-Cr-C weld overlay alloy

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Quick Facts
Patent No.
US 8,419,868
App. No.
11/690,763
Granted
Apr 16, 2013
Kind
B2
Abstract

A method of preparing a mechanical component with an Fe—Cr—C hardfacing weld overlay alloy for improving the resistance of the mechanical component to abrasion, erosion or erosion/corrosion for use in very abrasive, erosion or erosive/corrosive environments by significantly increasing the hardness of the weld overlay is disclosed. To improve the resistance to abrasion, erosion or corrosion, a weld overlay of a Fe—Cr—C hardfacing alloy is applied onto the surface of a metallic component, such as tubes, pipes, or vessels. Welding and cladding methods including gas-metal-arc welding (GMAW), gas-tungsten-arc welding (GTAW), and laser cladding may be utilized. Then, the component is heat-treated at elevated temperatures for a sufficient time, resulting in additional hardening and thus further increasing the weld overlay's resistance to abrasion, erosion, or erosion/corrosion.

Claims (12)

1. A method of improving the resistance of a mechanical component to abrasion, erosion or erosion/corrosion for use in very abrasive, erosion or erosive/corrosive environments, comprising:

(a) applying a weld overlay of a Fe—Cr—C hardfacing alloy onto the surface of a metallic component using welding and cladding methods; and

(b) heat-treating the weld overlay and component at a temperature between about 1400 to 2000 degrees Fahrenheit for about one hour, resulting in additional hardening of the weld overlay to a final hardness of between Rockwell C-50 to C-60 increasing the weld overlay's resistance to abrasion, erosion, or erosion/corrosion;

wherein the hardfacing alloy comprises 10-30% chromium; the cooling from the heat-treatment temperature is furnace cooled or air cooled at a rate slow enough to eliminate the forming of martensite or bainite phases during cooling; and the hardening resulting from the heat-treating is not a result of martensite or bainite formation during cooling from the heat-treating.

2. The method of claim 1 wherein the Fe—Cr—C hardfacing alloys are produced in castings.

3. The method of claim 1 wherein a HF35 hardfacing alloy wire is utilized for preparing the weld overlay, the HF35 hardfacing alloy wire comprises about 0.8-1.2% carbon, about 20-23% chromium, about 2.5-3.5% nickel, about 0.2-0.5% zirconium, about 0.5-1.0% molybdenum, about 1.0-2.0% manganese, about 1.0-2.0% silicon, and balance iron along with impurities and incidental elements.

4. The alloy of claim 1 wherein an initial hardness of the weld overlay in the as-overlaid condition is between Rockwell C-35 and C-40 and said final hardness of between Rockwell C-50 and C-60 is achieved after the heat-treatment.

5. The method of claim 1 wherein a hardfacing alloy wire is utilized for preparing the weld overlay, the hardfacing alloy wire is an alloy composition within the following chemical compositional ranges: about 0.5-2.0% carbon, about 10-30% chromium, about 1.0-8.0% nickel, about 0.2-0.5% zirconium, about 1.0-2.0% manganese, about 0.5-3.0% silicon, about 0.5-3.0% molybdenum, about 0.0-3.0% tungsten, about 0.0-0.5% boron, and balance iron along with impurities and incidental elements.

6. The method of claim 1 wherein the weld overlay is applied to pressure boundary components including tubes, pipes, and vessels.

7. The method of claim 1 wherein the weld overlay is applied using gas-metal-arc welding (GMAW), or gas-tungsten-arc welding (GTAW).

8. The method of claim 1 wherein the weld overlay is applied using arc welding methods selected from the group of submerged arc welding, electrostag welding and plasma transfer arc welding.

9. The method of claim 1 wherein the weld overlay is applied using laser cladding.

Assignments (17)
SECURITY INTEREST Recorded Jan 7, 2026
From: AIS WSI LLC
To: CADENCE BANK
Reel/Frame 073392/0768 →
CHANGE OF NAME Recorded Dec 18, 2025
From: AZZ WSI LLC
To: AIS WSI LLC
Reel/Frame 074003/0961 →
RELEASE OF SECURITY INTEREST IN PATENTS AT REEL/FRAME NO. 061277/0664 Recorded May 5, 2025
From: BANK OF AMERICA, N.A.
To: AZZ WSI LLC
Reel/Frame 071176/0377 →
TERMINATION AND RELEASE OF PATENT SECURITY AGREEMENT Recorded Oct 4, 2022
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: AZZ WSI LLC; CENTRAL ELECTRIC COMPANY
Reel/Frame 061604/0802 →
SECURITY INTEREST Recorded Sep 30, 2022
From: AZZ WSI LLC
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 061277/0664 →
PATENT SECURITY AGREEMENT Recorded May 13, 2022
From: AZZ WSI LLC
To: CITIBANK, N.A. AS COLLATERAL AGENT
Reel/Frame 060062/0864 →
CHANGE OF NAME Recorded Nov 24, 2014
From: AQUILEX WSI LLC
To: AZZ WSI, LLC
Reel/Frame 034432/0749 →
CHANGE OF NAME Recorded Nov 24, 2014
From: AZZ WSI, LLC
To: AZZ WSI LLC
Reel/Frame 034432/0764 →
RELEASE BY SECURED PARTY AS PREVIOUSLY RECORDED AT REEL 022034 FRAME 0216 Recorded Apr 3, 2013
From: ROYAL BANK OF CANADA
To: AQUILEX LLC; AQUILEX HYDROCHEM LLC; AQUILEX WSI LLC
Reel/Frame 030147/0676 →
PARTIAL RELEASE OF PATENT SECURITY AGREEMENT Recorded Apr 1, 2013
From: GENERAL ELECTRIC CAPITAL CORPORATION, AS GRANTEE
To: AQUILEX SMS LLC; AQUILEX WSI LLC; AQUILEX SPECIALTY REPAIR AND OVERHAULD LLC
Reel/Frame 030128/0109 →
RELEASE OF SECURITY INTEREST Recorded Feb 6, 2012
From: U.S. BANK NATIONAL ASSOCIATION
To: AQUILEX HOLDINGS LLC
Reel/Frame 027659/0273 →
SECURITY AGREEMENT Recorded Feb 3, 2012
From: AQUILEX LLC; AQUILEX INTERMEDIATE HOLDINGS LLC; AQUILEX HYDROCHEM LLC; AQUILEX HYDROCHEM INDUSTRIAL CLEANING LLC; AQUILEX SMS LLC; AQUILEX WSI LLC; AQUILEX FINANCE LLC; AQUILEX SPECIALTY REPAIR AND OVERHAUL LLC
To: GENERAL ELECTRIC CAPITAL CORPORATION, AS AGENT
Reel/Frame 027648/0515 →
CHANGE OF NAME Recorded Feb 3, 2012
From: AQUILEX WSI, INC.
To: AQUILEX WSI LLC
Reel/Frame 027651/0252 →
SECURITY AGREEMENT Recorded Nov 16, 2011
From: AQUILEX HOLDINGS LLC
To: U.S. BANK NATIONAL ASSOCIATION
Reel/Frame 027241/0531 →
CHANGE OF NAME Recorded Dec 15, 2009
From: WELDING SERVICES INC.
To: AQUILEX WSI, INC.
Reel/Frame 023649/0856 →
SECURITY AGREEMENT Recorded Dec 29, 2008
From: AQUILEX HOLDINGS LLC; AQUILEX CORP.; HYDROCHEM HOLDING, INC.; HYDROCHEM INDUSTRIAL CLEANING, INC.; HYDROCHEM INDUSTRIAL SERVICES, INC.; HYDROCHEM INTERNATIONAL, INC.; SOUTHEASTERN MECHANICAL SERVICES, INC.; WELDING SERVICES INC.
To: ROYAL BANK OF CANADA
Reel/Frame 022034/0216 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 23, 2007
From: LAI, GEORGE Y
To: WELDING SERVICES, INC.
Reel/Frame 019060/0187 →