Polyimide film having high adhesiveness and method for producing same
View Patent ↗A non-thermoplastic polyimide film exhibits high adherability without expensive surface treatment and is made from a precursor solution having high storage stability. The non-thermoplastic polyimide film comprises a non-thermoplastic polyimide resin having a block component derived from a thermoplastic polyimide. Preferably, the block component of the thermoplastic polyimide is present in an amount of 20 to 60 mol % of the entire polyimide so that the precursor solution thereof exhibits high storage stability and that the film can exhibit high adherability, in particular, high adherability to polyimide adhesives.
1. A non-thermoplastic polyimide film comprising:
a non-thermoplastic polyimide resin having a block component derived from a thermoplastic polyimide, wherein the non-thermoplastic polyimide film, when fixed onto a metal frame and heated at 450° C. for 1 minute, retains its original film shape.
2. The non-thermoplastic polyimide film according to claim 1 , wherein the thermoplastic block component is present in an amount of 20 to 60 mol % of the entire non-thermoplastic polyimide resin.
3. The non-thermoplastic polyimide film according to claim 1 , wherein the diamine component in the thermoplastic polyimide block component contains 2,2-bis(4-aminophenoxyphenyl) propane.
4. The non-thermoplastic polyimide film according to claim 1 , wherein the acid component in the thermoplastic polyimide block component contains a benzophenonetetracarboxylic acid and/or a biphenyltetracarboxylic acid.
5. The non-thermoplastic polyimide film according to claim 1 , wherein the number n of repeating units of the thermoplastic polyimide block component is 3 to 99.
6. The on-thermoplastic polyimide film according to claim 5 , wherein the number n of repeating units of the thermoplastic polyimide block component is 4 to 90.
7. The non-thermoplastic polyimide film according to claim 1 , wherein the non-thermoplastic polyimide film is a polyimide film consisting of a non-thermoplastic polyimide resin having a block component derived from a thermoplastic polyimide.
8. The non-thermoplastic polyimide film according to claim 1 , further comprising a filler.
9. The non-thermoplastic polyimide film according to claim 8 , wherein the non-thermoplastic polyimide resin is 50 wt % or more of the film.
10. The non-thermoplastic polyimide film according to claim 8 , wherein the filler is 50 wt % or less of the film.
11. The non-thermoplastic polyimide film according to claim 1 , wherein the thermoplastic polyimide block component has a glass transition temperature in the range of 150° C. to 300° C.
12. A non-thermoplastic polyimide film comprising:
a non-thermoplastic polyimide resin having at least one residue unit derived from a compound having diamine functionality and at least one residue unit derived from a compound having acid dianhydride functionality,
wherein either the residue unit derived from a compound having diamine functionality or the residue unit derived from a compound having acid dianhydride functionality has at least one amic acid group and exhibits a thermoplastic character when bound linearly using pyromellitic acid dianhydride (in the case of the compound having diamine functionality) or p-phenylenediamine (in the case of the compound having acid dianhydride functionality) and then imidized
wherein the non-thermoplastic polyimide film, when fixed onto a metal frame and heated at 450° C. for 1 minute, retains its original film shape.
13. A non-thermoplastic polyimide film comprising:
a non-thermoplastic polyimide resin having at least one residue unit derived from a compound having diamine functionality and at least one residue unit derived from a compound having acid dianhydride functionality,
wherein either the residue unit derived from a compound having diamine functionality or the residue unit derived from a compound having acid dianhydride functionality has at least one imide group and exhibits a thermoplastic character when bound linearly using pyromellitic acid dianhydride (in the case of the compound having diamine functionality) or p-phenylenediamine (in the case of the compound having acid dianhydride functionality) and then imidized,
wherein the non-thermoplastic polyimide film, when fixed onto a metal frame and heated at 450° C. for 1 minute, retains its original film shape.
14. A non-thermoplastic polyimide film made from monomer components polymerized in an arrangement that provides thermoplastic polyimide regions having the following properties as compared to a comparative film having the same monomer components that are randomly polymerized:
i) the non-thermoplastic polyimide film has an elasticity modulus higher than that of the comparative film by at least 0.3 GPa;
ii) the non-thermoplastic polyimide film has a linear expansion coefficient and moisture expansion coefficient smaller than those of the comparative film by at least 1 ppm;
iii) the non-thermoplastic polyimide film and the comparative film maintain substantially the same tensile elongation;
iv) the storage elasticity modulus of the non-thermoplastic polyimide film at 380° C. determined by dynamic viscoelasticity analysis is lower than that of the comparative film by at least 0.1 GPa; and
v) the tan δ peak value of the non-thermoplastic polyimide film is larger than that of the comparative film by at least 0.01.
wherein the non-thermoplastic polyimide film, when fixed onto a metal frame and heated at 450° C. for 1 minute, retains its original film shape.