Non-aqueous electrolyte secondary battery having positive electrode with high potential
View Patent ↗The storage characteristics in a charged state are improved in a non-aqueous electrolyte secondary battery containing a lithium cobalt oxide as a positive electrode active material. The non-aqueous electrolyte secondary battery includes a positive electrode containing a positive electrode active material; a negative electrode containing a negative electrode active material other than metallic lithium; and a non-aqueous electrolyte. The positive electrode active material contains a lithium cobalt oxide as its main component. The non-aqueous electrolyte contains 0.1 to 10 volume % of a compound having an ether group. The positive electrode active material and the negative electrode active material are contained so that the charge capacity ratio of the negative electrode to the positive electrode is from 1.0 to 1.2 when the battery is charged until the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li + )
1. A non-aqueous electrolyte secondary battery comprising:
a positive electrode containing a positive electrode active material;
a negative electrode containing a negative electrode active material other than metallic lithium; and
a non-aqueous electrolyte, wherein:
the positive electrode active material contains a lithium cobalt oxide as its main component and having a potential of 4.4 to 4.5 V (vs. Li/Li + );
the non-aqueous electrolyte contains 0.1 to 10 volume % of compound having an ether group; and the battery is charged until the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li + ), wherein the compound having an ether group is at least one compound selected from the group consisting of diethyl ether, 2-methyltetrahydrofuran, tetrahydrofuran, diethylene glycol dimethyl ether, 1,4-dioxane, 12-crown-4-ether, and 15-crown-5-ether.
2. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium cobalt oxide is represented by the chemical formula Li a Co 1-x-y-z Zr x Mg y M z O 2 , where M is at least one element selected from the group consisting of Al, Ti, and Sn; 0≦a≦1.1; x>0; y>0; z≧0; and 0<x+y+z≦0.03.
3. The non-aqueous electrolyte secondary battery according to claim 2 , wherein the lithium cobalt oxide has a zirconium-containing compound in particulate form that has been sintered on a surface thereof.
4. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the negative electrode active material is a graphite material, and a battery voltage is 4.3 to 4.4 V when the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li + ).
5. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the non-aqueous electrolyte contains diethyl carbonate as a solvent.
6. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the non-aqueous electrolyte contains 1 to 10 volume % of diethyl ether as the compound having an ether group.
7. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the non-aqueous electrolyte contains 0.1 to 1 volume % of tetrahydrofuran as the compound having an ether group.
8. The non-aqueous electrolyte secondary battery according to claim 1 , wherein the non-aqueous electrolyte further contains 0.5 to 4 weight % of vinylene carbonate.
9. The non-aqueous electrolyte secondary battery according to claim 2 , wherein the negative electrode active material is a graphite material, and a battery voltage is 4.3 to 4.4 V when the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li + ).
10. The non-aqueous electrolyte secondary battery according to claim 2 , wherein the non-aqueous electrolyte contains diethyl carbonate as a solvent.
11. The non-aqueous electrolyte secondary battery according to claim 2 , wherein the non-aqueous electrolyte further contains 0.5 to 4 weight % of vinylene carbonate.
12. The non-aqueous electrolyte secondary battery according to claim 3 , wherein the negative electrode active material is a graphite material, and a battery voltage is 4.3 to 4.4 V when the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li + ).
13. The non-aqueous electrolyte secondary battery according to claim 3 , wherein the non-aqueous electrolyte contains diethyl carbonate as a solvent.
14. The non-aqueous electrolyte secondary battery according to claim 3 , wherein the non-aqueous electrolyte further contains 0.5 to 4 weight % of vinylene carbonate.
15. The non-aqueous electrolyte secondary battery according to claim 4 , wherein the non-aqueous electrolyte further contains 0.5 to 4 weight % of vinylene carbonate.
16. A method of increasing charge voltage and battery capacity of a non-aqueous electrolyte secondary battery comprising a positive electrode containing lithium cobalt oxide as a primary positive electrode active material and having a potential of 4.4 to 4.5 V (vs. Li/Li + ), a negative electrode containing a negative electrode active material other than metallic lithium, and a non-aqueous electrolyte, comprising:
adding 0.1 to 10 volume % of a compound having an ether group to the non-aqueous electrolyte;
charging the battery until the potential of the positive electrode reaches 4.4 to 4.5 V (vs. Li/Li + ), and
maintaining the amounts of the positive electrode active material and the negative electrode active material such that when the battery is charged to said potential of the positive electrode the charge capacity ratio of the negative electrode to the positive electrode is from 1.0 to 1.2, wherein the compound having an ether group is at least one compound selected from the group consisting of diethyl ether, 2-methyltetrahydrofuran, tetrahydrofuran, diethylene glycol dimethyl ether, 1,4-dioxane, 12-crown-4-ether, and 15-crown-5-ether.