IP Library Granted Patent US 7,763,178
Granted Patent B2
US 7,763,178 · App. 11/701,032 · Granted Jul 27, 2010

Biodegradable surface layer film for pools or spas to prevent evaporation and heat loss

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Quick Facts
Patent No.
US 7,763,178
App. No.
11/701,032
Granted
Jul 27, 2010
Kind
B2
Abstract

The present invention relates to swimming pools and other pools of standing water, and in particular to a dispensing unit that distributes a chemical solution that reduces evaporation and heat loss by forming a film or monomolecular layer over the surface or substantial surface area of the swimming pool or water pond.

Claims (9)

1. A method of forming a film or monomolecular, non-toxic, biodegradable surface layer film for swimming pools, spas, hot tubs or water ponds in order to prevent evaporation, limit heat loss, and maintain chemical balance comprising:

forming a dispensing container having a volume of between 0.1 and less than 24 cubic inches, said dispensing container being resistant to attack by water and chemical, said dispensing container perforated by a plurality of small holes, each of less than three square mm in cross section and greater than 5,000ths of an inch in diameter, and with an aggregate area of said holes less than 0.2% of the surface area of said dispensing container, said dispensing container being spherical in shape and having neutral buoyancy dependant upon water velocity flow so as to cause said dispensing container to move about freely and roll on the surface of the water, said dispensing container having a chamber of sufficient size to contain a solution for forming said monomolecular, biodegradable surface layer film;

forming a solution of deionized water, propylene glycol, methyl paraben, poly-oxy-ethylene sorbitan monolaurate, cetyl alcohol, sorbitan monopalmitate, cetyl ether, antifoaming agent, and propyl paraben, and introducing said solution into said dispensing container and sealing same;

puncturing said plurality of small holes in said dispensing container;

positioning said dispensing container in said swimming pool, hot tub, spa, or water pond so as to move freely under the influence of said water velocity and to dispense said solution, forming said film or monomolecular, biodegradable surface layer film on said surface of said swimming pool, hot tub, spa or water pond so as to prevent evaporation, heat loss and to maintain chemical balance.

2. The method of forming a film or monomolecular, non-toxic, biodegradable surface layer film for swimming pools, spas, hot tubs or water ponds in accordance with claim 1 comprising a solution of water, deionized water, or filtered water in the weight percent range of from 92.0% to 99.0%; propylene glycol is present in a maximum of 2.0%;

methyl paraben is present in a maximum of 0.15%; poly-oxy-ethylene (20) sorbitan monolaurate is present in a range of from 0.10% to 4.0%; cetyl alcohol is present in a range of from 1. 0% to 8.0%; sorbitan monopalmitate is present in a range of from 0.10% to 4.0%; poly-oxy-ethylene (20 cetyl ether) is present in a range of from 0.10% to 4.0%; antifoaming agent is present in a range of from 0.10% to 4.0%; and propyl paraben is present in a maximum of from 0.05%.

3. The method of forming a film or monomolecular, non-toxic, biodegradable surface layer film for swimming pools, spas, hot tubs or water ponds in accordance with claim 2 comprising a solution of constituents in the following weight percentages:

deionized water 93.1%; propylene glycol 2.0%; methyl paraben 0.15%, poly-oxy-ethylene (20) sorbitan monolaurate 0.2%; cetyl alcohol 4.0%; sorbitan monopalmitate 0.20%; poly-oxy-ethylene (20 cetyl ether) 58 0.20%; an antifoaming agent 0.10%; and propyl paraben 0.05%.

Assignments (14)
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Dec 12, 2025
From: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; KIK CUSTOM PRODUCTS INC.; NC BRANDS L.P.; SOLSKYN PERSONAL CARE LLC
To: KIK LUX FINCO SARL
Reel/Frame 073924/0557 →
RELEASE AND TERMINATION OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 10, 2024
From: BARCLAYS BANK PLC
To: NC BRANDS L.P.
Reel/Frame 068263/0358 →
SECURITY INTEREST Recorded Jul 8, 2024
From: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; CYGNUS CORPORATION; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; NC BRANDS L.P.; SOLSKYN PERSONAL CARE LLC
To: JEFFERIES FINANCE LLC
Reel/Frame 067928/0718 →
RELEASE/TERMINATION OF INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 8, 2024
From: WILMINGTON TRUST, NATIONAL ASSOCIATION
To: BIO-LAB, INC.; KIK CUSTOM PRODUCTS INC.; NC BRANDS, L.P.; PRESTONE PRODUCTS CORPORATION
Reel/Frame 068220/0306 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT Recorded Jul 8, 2024
From: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC; CYGNUS CORPORATION; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; NC BRANDS L.P.; SOLSKYN PERSONAL CARE LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION
Reel/Frame 068220/0368 →
RELEASE AND TERMINATION OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded Jul 8, 2024
From: BARCLAYS BANK PLC
To: AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS, INC.; KIK INTERNATIONAL, LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; NC BRANDS L.P.; CYGNUS CORPORATION
Reel/Frame 068220/0455 →
SECURITY AGREEMENT Recorded Dec 27, 2021
From: AQUA CLEAR INDUSTRIES, LLC; ASEPIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; CYGNUS CORPORATION; NC BRANDS L.P.
To: BARCLAYS BANK PLC
Reel/Frame 058592/0835 →
RELEASE OF INTELLECTUAL PROPERTY SECURITY INTEREST Recorded Jul 29, 2021
From: BARCLAYS BANK PLC, AS COLLATERAL AGENT
To: BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; JAMES AUSTIN COMPANY; KIK INTERNATIONAL LLC; NC BRANDS L.P.; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC
Reel/Frame 057650/0125 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (NOTES) Recorded Dec 22, 2020
From: BIO-LAB, INC.; KIK CUSTOM PRODUCTS INC.; KIK INTERNATIONAL LLC; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; JAMES AUSTIN COMPANY; CYGNUS CORPORATION; NC BRANDS L.P.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; HI-LEX LLC; HOMECARE LABS, INC.; SUNBELT POOL PRODUCTS, LLC
To: WILMINGTON TRUST, NATIONAL ASSOCIATION, AS NOTES COLLATERAL AGENT
Reel/Frame 055327/0754 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (TERM LOAN) Recorded Jan 28, 2019
From: NC BRANDS L.P.
To: BARCLAYS BANK PLC, AS AGENT
Reel/Frame 048180/0154 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (2019) Recorded Jan 28, 2019
From: APG, INC.; AQUA CLEAR INDUSTRIES, LLC; ASEPSIS, INC.; BIO-LAB, INC.; HI-LEX LLC; HOMECARE LABS, INC.; KIK CUSTOM PRODUCTS INC.; KIK CUSTOM PRODUCTS, INC; KIK INTERNATIONAL LLC; MARIETTA CORPORATION; PRESTONE PRODUCTS CORPORATION; SOLSKYN PERSONAL CARE LLC; SUNBELT POOL PRODUCTS, LLC; JAMES AUSTIN COMPANY; CBI LABORATORIES, INC.; CYGNUS CORPORATION; NC BRANDS L.P.
To: BARCLAYS BANK PLC, AS AGENT
Reel/Frame 048180/0101 →
INTELLECTUAL PROPERTY SECURITY AGREEMENT (ABL) Recorded Jan 28, 2019
From: NC BRANDS L.P.
To: BARCLAYS BANK PLC, AS AGENT
Reel/Frame 049671/0121 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 20, 2016
From: HALOSOURCE, INC.
To: NC BRANDS L.P.
Reel/Frame 038957/0255 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 18, 2016
From: SEAKLEAR POOL PILLS LLC
To: HALOSOURCE, INC.
Reel/Frame 038639/0293 →