Process for preparing adhesive using planetary extruder
View Patent ↗A process for preparing a pressure sensitive adhesive using a modified planetary roller extruder is described. The process in accordance with one aspect of the invention includes introducing primary raw materials including a non-thermoplastic elastomer into a feeding section of the modified planetary roller extruder, conveying the raw materials from the feeding section to a compounding section of the modified planetary roller extruder, continuously mixing the primary raw materials in the compounding section to produce a homogeneous adhesive composition. The adhesive composition may be applied to a web-form material. The compounding section of the modified planetary roller extruder includes a main spindle surrounded by and intermeshed with a plurality of planetary spindles at least one of which is a double transversal mixing spindle having a plurality of back-cut helical flights.
1. An adhesive composition made according to a process comprising:
introducing primary raw materials comprising a non-thermoplastic elastomer into a feeding section of a planetary roller extruder;
conveying the primary raw materials from the feeding section to a compounding section of the planetary roller extruder;
mixing the primary raw materials in the compounding section;
providing a first means of crosslinking by adding a heat-activatable crosslinker to the compounding section;
providing a second means of crosslinking by adding an ionizing radiation crosslinker to the compounding section;
continuously producing a homogeneous adhesive composition while maintaining the temperature of the adhesive composition between about 25° C. and 100° C.;
applying the homogeneous adhesive composition to a web-form material; and
exposing the web-form material with the applied composition to ionizing radiation thereby crosslinking the adhesive composition with the ionizing radiation crosslinker;
wherein the non-thermoplastic elastomer is masticated during mixing in the compounding section such that its M w is reduced by about 50% to about 80% and the heat-activatable chemical crosslinker remains generally unactivated such that it is a residual latent curing agent available for later activation.
2. The adhesive composition of claim 1 wherein the ionizing radiation is electron beam radiation.
3. The adhesive composition of claim 2 wherein the non-thermoplastic elastomer includes natural rubber, synthetic rubber, or blends thereof.
4. The adhesive composition of claim 3 wherein the synthetic rubber includes styrene-butadiene rubbers, butadiene rubbers, synthetic polyisoprenes, butyl rubbers, polyisobutylene rubber, halogenated butyl rubbers, acrylate rubbers, ethylene vinyl acetate copolymers, polyurethanes, and blends thereof.
5. The adhesive composition of claim 1 wherein the heat-activatable crosslinker is selected from the group consisting of an accelerated sulphur or sulphur donor system, an isocyanate system, a reactive melamine resin, a formaldehyde resin, a phenol-formaldehyde resin, a reactive phenolic resin, a diisocyanate system, an epoxidized polyester resin, and combinations thereof.
6. The adhesive composition of claim 5 wherein the heat-activatable crosslinker includes an isocyanate system or a diisocyanate system.
7. The adhesive composition of claim 1 wherein the non-thermoplastic elastomer is masticated such that its M w is reduced to less than 1,000,000 as measured by GPC.
8. The adhesive composition of claim 1 wherein the step of applying includes slot-die coating, reverse roll, roll-over-roll coating, or knife-over-roll coating.
9. The adhesive composition of claim 1 wherein the planetary roller extruder contains adhesive at a temperature of about 29° C., 33° C., 52° C., 53° C., 57° C., 59° C., 60° C., 62° C., 64° C., or 72° C. in at least one barrel cylinder thereof.
10. The adhesive composition of claim 1 wherein the residence time of the homogeneous adhesive composition in the extruder does not exceed about three minutes.
11. The adhesive composition of claim 5 wherein the activation temperature of the heat-activatable crosslinker is about 110° C. to about 140° C.
12. The adhesive composition of claim 3 further comprising mixing a thermoplastic elastomer with the non-thermoplastic elastomer; wherein the thermoplastic elastomer is selected from the group consisting of styrene-isoprene-styrene, styrene-butadiene-styrene, styrene-isoprene-butadiene-styrene, styrene-ethylene-butadiene-styrene, styrene-ethylene-propylene-styrene, and combinations thereof.
13. An adhesive composition made according to a process comprising:
introducing a natural rubber, a synthetic rubber, or blends thereof into a planetary roller extruder, the natural rubber, the synthetic rubber, or the blend thereof having an initial molecular weight;
masticating the natural rubber, the synthetic rubber, or the blends thereof in the planetary roller extruder such that the initial molecular weight thereof is reduced by about 50% to about 80%;
adding a combination of an ionizing radiation crosslinker and a heat-activatable chemical crosslinker to the natural rubber, the synthetic rubber, or the blends thereof;
continuously producing a homogeneous adhesive composition while maintaining the temperature of the adhesive composition between about 25° C. and 100° C.;
applying the homogeneous adhesive composition to a web-form material; and
activating the ionizing radiation crosslinker to crosslink the adhesive composition;
wherein the heat-activatable chemical crosslinker remains generally unactivated such that it is a residual latent curing agent available for later activation.
14. The adhesive composition of claim 13 , further comprising introducing a solvent into the planetary roller extruder.
15. The adhesive composition of claim 13 wherein the heat-activatable crosslinker is the isocyanate system or the diisocyanate system.
16. The adhesive composition of claim 15 wherein the ionizing radiation crosslinker includes an acrylate resin.
17. The adhesive composition of claim 13 wherein activating the ionizing radiation crosslinker includes applying electron beam radiation.
18. The adhesive composition of claim 13 wherein the synthetic rubber includes styrene-butadiene rubbers, butadiene rubbers, synthetic polyisoprenes, butyl rubbers, polyisobutylene rubber, halogenated butyl rubbers, acrylate rubbers, ethylene vinyl acetate copolymers, polyurethanes, and blends thereof.
19. The adhesive composition of claim 13 wherein the heat-activatable crosslinker is selected from the group consisting of an accelerated sulphur or sulphur donor system, an isocyanate system, a reactive melamine resin, a formaldehyde resin, a phenol-formaldehyde resin, a reactive phenolic resin, a diisocyanate system, an epoxidized polyester resin, and combinations thereof.
20. The adhesive composition of claim 13 wherein the temperature of the adhesive composition within the planetary roller extruder is about 29° C., 33° C., 52° C., 53° C., 57° C., 59° C., 60° C., 62° C., 64° C., or 72° C.
21. The adhesive composition of claim 13 further comprising mixing a thermoplastic elastomer is selected from the group consisting of styrene-isoprene-styrene, styrene-butadiene-styrene, styrene-isoprene-butadiene-styrene, styrene-ethylene-butadiene-styrene, styrene-ethylene-propylene-styrene, and combinations thereof with the natural rubber, the synthetic rubber, or the blends thereof.
22. A process for preparing an adhesive comprising the steps of:
introducing primary raw materials comprising a non-thermoplastic elastomer into a feeding section of a planetary roller extruder;
conveying the primary raw materials from the feeding section to a compounding section of the planetary roller extruder;
mixing the primary raw materials in the compounding section;
providing a first means of crosslinking by adding a heat-activatable crosslinker to the compounding section;
providing a second means of crosslinking by adding an ionizing radiation crosslinker to the compounding section;
continuously producing a homogeneous adhesive composition while maintaining the temperature of the adhesive composition between about 25° C. and 100° C.;
applying the homogeneous adhesive composition to a web-form material; and
g) exposing the web-form material with the applied composition to ionizing radiation thereby crosslinking the adhesive composition with the ionizing radiation crosslinker;
wherein the non-thermoplastic elastomer is masticated during mixing in the compounding section such that its M w is reduced by about 50% to about 80% and the heat-activatable chemical crosslinker remains generally unactivated such that it is a residual latent curing agent available for later activation.
23. The process of claim 22 wherein the ionizing radiation is electron beam radiation.
24. The process of claim 22 wherein the primary raw materials comprise natural rubber and a tackifying resin.
25. The process of claim 22 wherein the heat-activatable crosslinker is an isocyanate.
26. The process of claim 25 wherein the isocyanate is a polyisocyanate.
27. A tape coated with the adhesive made according to the process of claim 22 .