IP Library Granted Patent US 7,485,728
Granted Patent B2
US 7,485,728 · App. 11/702,758 · Granted Feb 3, 2009

Colorant compounds

Assignee: Xerox Corporation
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Quick Facts
Patent No.
US 7,485,728
App. No.
11/702,758
Granted
Feb 3, 2009
Kind
B2
Abstract

A compound of the formula wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R, Y, CA, A − , m and n each, independently of the others are as defined herein.

Claims (33)

1. A compound of the formula

wherein R 1 , R 2 , R 3 , and R 4 each, independently of the others, is (i) a hydrogen atom, (ii) an alkyl group, (iii) an aryl group, (iv) an arylalkyl group, or (v) an alkylaryl group, wherein R 1 and R 2 can be joined together to form a ring, wherein R 3 and R 4 can be joined together to form a ring, and wherein R 1 , R 2 , R 3 , and R 4 can each be joined to a phenyl ring in the central structure;

wherein a and b each, independently of the others, is an integer which is 0, 1, 2, or 3,

wherein R 5 and R 6 are hydrogen or alkyl;

wherein A is an anion selected from the group consisting of Cl − , Br − , I − , HSO 4 − , HSO 3 − , SO 4 2 − , SO 3 2 − , CH 3 SO 3 − , CH 3 C 6 H 4 SO 3 − , NO 3 − , HCOO − , CH 3 COO − , H 2 PO 4 − , HPO 4 2 − , SCN − , BF 4 − , ClO 4 − , SSO 3 − , PF 6 − , and SbCl 6 − ;

wherein CA is either a hydrogen atom an alkali metal cation, or a quaternary amine cation of the formula

 wherein each of R 21 , R 22 , R 23 , and R 24 are independently selected from an alkyl group having 1 to 6 carbon atoms;

wherein R is (i) an alkyl group, (ii) an aryl group, (iii) an arylalkyl group, (iv) an alkylaryl group, (v) an alkoxy group, (vi) an acetate group, or (vii) a co-polymer of maleic anhydride;

wherein n is an integer which is 1 to 1,000; and

wherein m is an integer which is 1 to 1,000.

2. A compound according to claim 1 , wherein a and b are each zero.

3. A compound according to claim 1 , wherein at least one of R 1 , R 2 , R 3 , and R 4 is an alkyl group.

4. A compound according to claim 1 , wherein R 1 and R 2 are joined together to form a ring.

5. A compound according to claim 1 , wherein R 1 and R 2 are joined together to form a ring and wherein R 3 and R 4 are joined together to form a ring.

6. A compound according to claim 1 , wherein at least one of R 1 , R 2 , R 3 , and R 4 is joined to a phenyl ring in the central structure.

7. A compound according to claim 1 , wherein R is an alkyl group.

8. A compound according to claim 1 , wherein R is an aryl group.

9. A compound according to claim 1 , wherein R is C 6 H 5 .

10. A compound according to claim 1 , wherein R is CH 2 CH 2 .

11. A compound of the formula

wherein n is 1 to 1,000 and wherein m is 1 to 1,000.

12. A compound of the formula

wherein n is 1 to 1,000 and wherein m is 1 to 1,000.

13. A compound of the formula

wherein R 1 , R 2 , R 3 , and R 4 each, independently of the others, is (i) a hydrogen atom, (ii) an alkyl group, (iii) an aryl group, (iv) an arylalkyl group, or (v) an alkylaryl group, wherein R 1 and R 2 can be joined together to form a ring, wherein R 3 and R 4 can be joined together to form a ring, and wherein R 1 , R 2 , R 3 , and R 4 can each be joined to a phenyl ring in the central structure;

wherein a and b each, independently of the others, is an integer which is 0, 1, 2, or 3;

wherein R 5 and R 6 are hydrogen or alkyl;

wherein A is an anion selected from the group consisting of Cl − , Br − , I − , HSO 4 − , HSO 3 − , SO 4 2 − , SO 3 2 − , CH 3 SO 3 − , CH 3 C 6 H 4 SO 3 − , NO 3 − , HCOO − , CH 3 COO − , H 2 PO 4 − , HPO 4 2 − , SCN − , BF 4 − , ClO 4 − , SSO 3 − , PF 6 − , and SbCl 6 − ;

wherein CA is either a hydrogen atom an alkali metal cation, or a quaternary amine cation of the formula

 wherein each of R 21 , R 22 , R 23 , and R 24 are independently selected from an alkyl group having 1 to 6 carbon atoms;

wherein R is (i) an alkyl group, (ii) an aryl group, (iii) an arylalkyl group, (iv) an alkylaryl group, (v) an alkoxy group, (vi) an acetate group, or (vii) a co-polymer of maleic anhydride;

wherein R 30 and R 31 each, independently of the other, is an alkyl group, an aryl group, an alkylaryl group, or an arylalkyl group; and

wherein n is 1 to 1,000, m is 1 to 1,000, p is 1 to 1,000 and s is 1 to 1,000.

Assignments (10)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 6, 2025
From: XEROX CORPORATION
To: GENESEE VALLEY INNOVATIONS, LLC
Reel/Frame 073842/0479 →
SECOND LIEN NOTES PATENT SECURITY AGREEMENT Recorded Jul 2, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 071785/0550 →
FIRST LIEN NOTES PATENT SECURITY AGREEMENT Recorded Apr 11, 2025
From: XEROX CORPORATION
To: U.S. BANK TRUST COMPANY, NATIONAL ASSOCIATION, AS COLLATERAL AGENT
Reel/Frame 070824/0001 →
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS RECORDED AT RF 064760/0389 Recorded Feb 13, 2024
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: XEROX CORPORATION
Reel/Frame 068261/0001 →
SECURITY INTEREST Recorded Feb 13, 2024
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 066741/0001 →
SECURITY INTEREST Recorded Nov 20, 2023
From: XEROX CORPORATION
To: JEFFERIES FINANCE LLC, AS COLLATERAL AGENT
Reel/Frame 065628/0019 →
SECURITY INTEREST Recorded Jun 22, 2023
From: XEROX CORPORATION
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 064760/0389 →
RELEASE OF SECURITY INTEREST IN PATENTS AT R/F 062740/0214 Recorded May 18, 2023
From: CITIBANK, N.A., AS AGENT
To: XEROX CORPORATION
Reel/Frame 063694/0122 →
SECURITY INTEREST Recorded Nov 10, 2022
From: XEROX CORPORATION
To: CITIBANK, N.A., AS AGENT
Reel/Frame 062740/0214 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Feb 26, 2007
From: BANNING, JEFFREY H.
To: XEROX CORPORATION
Reel/Frame 018978/0828 →
Continuity (1)
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