Storage stable one component polyurethane system

1. A storage-stable flowable, one component polyurethane composition comprising

(a) one or more isocyanate-terminated polyurethane prepolymers derived from one or more hydrocarbon ring-containing diisocyanates or triisocyanates and one or more polyols;

(b) one or more metal salt complexes of methylenedianiline; and

(c) one or more organic acid halide compounds having one or more acid halide groups, wherein the acid halide groups are present in a concentration of from about 100 parts per million to about 20,000 parts per million by weight of the polyurethane prepolymer,

prepared by a process comprising adding one or more organic acid halide compounds having one or more acid halide groups, to one or more isocyanate-terminated polyurethane prepolymers, said prepolymer prepared from a polyol and a hydrocarbon ring-containing diisocyanate or triisocyanate, to form a prepolymer/acid halide mixture, mixing said mixture,

and then adding to the mixture, under agitation, one or more metal salt complexes of methylenedianiline and mixing to obtain the storage-stable flowable, one component polyurethane composition,

which composition has a viscosity below 100,000 centipoise at 50° C., and remains flowable and non-elastomeric, as determined at about 50° C., for at least ninety days at a temperature of about 35° C., and at least about fourteen days at a temperature of about 50° C. to about 70° C. which composition forms a polyurethane elastomer product upon heating to a temperature in a range of about 100° C. to 150° C.

2. The storage-stable flowable, one component polyurethane composition according to claim 1 , wherein the polyurethane prepolymer is prepared from a polyol and one or more hydrocarbon ring-containing diisocyanates selected from the group consisting of paraphenylene diisocyanate, tolidene diisocyanate, isophorone diisocyanate, isomers of methylene bis(phenylisocyanate), isomers of toluene diisocyanate, diphenyl-4,4′-diisocyanate, dibenzyl-4,4′-diisocyanate, stilbene-4,4′-diisocyanate, benzophenone-4,4′diisocyanate, 1,3- and 1,4-xylene diisocyanates, 1,3-cyclohexyl diisocyanate, 1,4-cyclohexyl diisocyanate, 4,4′-methylene bis(phenylisocyanate), isomers of 1,1′-methylene-bis(4-isocyanatocyclohexane), isomers of benzenetriisocyanate, toluene-2,4,6-triisocyanate, 2,4,4′-triisocyanatediphenylether, and tolylene and xylylene diisocyanate derivatives of trimethylolpropane.

3. The storage-stable flowable, one component polyurethane composition according to claim 1 , wherein the one or more organic acid halide compounds having one or more acid halide groups is selected from the group consisting of adipoyl chloride, benzoyl chloride, phthaloyl chloride, isophthaloyl chloride, terephthaloyl chloride, acetyl chloride, palmitoyl chloride, p-nitrobenzoyl chloride, 2-chlorobenzoyl chloride, 3-chlorobenzoyl chloride, 4-chlorobenzoyl chloride, oleoyl chloride, and stearoyl chloride.

4. The storage-stable flowable, one component polyurethane composition according to claim 1 wherein the polyurethane prepolymer is prepared from a polyol and one or more hydrocarbon ring-containing diisocyanates selected from the group consisting of methylene diphenyl diisocyanate, paraphenylene diisocyanate and toluene diisocyanate and the one or more organic acid halide compounds having one or more acid halide groups is selected from the group consisting of benzoyl chloride, phthaloyl chloride, isophthaloyl chloride, terephthaloyl chloride, p-nitrobenzoyl chloride, 2-chlorobenzoyl chloride, 3-chlorobenzoyl chloride and 4-chlorobenzoyl chloride.

5. The storage-stable flowable, one component polyurethane composition according to claim 1 having a viscosity below 30,000 centipoise at 50° C.