IP Library Granted Patent US 7,390,466
Granted Patent B2
US 7,390,466 · App. 11/705,969 · Granted Jun 24, 2008

Production of lithium compounds directly from lithium containing brines

Assignee: Chemetall Foote Corporation
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Quick Facts
Patent No.
US 7,390,466
App. No.
11/705,969
Granted
Jun 24, 2008
Kind
B2
Abstract

Methods and apparatus for the production of low sodium lithium carbonate and lithium chloride from a brine concentrated to about 6.0 wt % lithium are disclosed. Methods and apparatus for direct recovery of technical grade lithium chloride from the concentrated brine are also disclosed.

Claims (20)

1. An apparatus for continuously purifying lithium carbonate comprising:

a dissolver to dissolve lithium carbonate that includes a mixer/disperser,

a carbon dioxide gas dispersion tube,

a wash water filtrate/mother liquor filtrate recycle line,

a cooler,

a stilling well to separate gas and undissolved lithium carbonate solids from the resultant lithium bicarbonate solution,

a continuous chemical grade lithium carbonate crystal feeder;

an inline filter to remove insoluble impurities from the lithium bicarbonate solution coming from the stilling well;

a heat exchanger to recover heat from the hot mother liquor that is recycled to the dissolver;

a heated gas sealed crystallizer with mixer to decompose the lithium bicarbonate solution to form low sodium lithium carbonate crystals, carbon dioxide gas, and mother liquor;

a slurry valve to remove the low sodium lithium carbonate crystals and mother liquor from the gas sealed crystallizer;

a gas line to continuously return the carbon dioxide produced in the crystallizer to the dissolver;

a separator to separate the low sodium lithium carbonate from the mother liquor and a wash water section to wash the lithium carbonate crystals;

a pump and line to return the mother liquor and wash filtrate to the dissolver;

a mother liquor bleed to control the sodium level and to maintain a constant liquid volume; and

a carbon dioxide source.

2. The apparatus of claim 1 , comprising a reactor using absorption columns to facilitate absorption of carbon dioxide.

3. The apparatus of claim 2 , wherein the absorption column is a sieve tray.

4. the apparatus of claim 2 , wherein the absorption column is a Schiebel column.

5. The apparatus of claim 1 , wherein the absorption column is a sieve tray or a Schiebel column.

Assignments (4)
TERMINATION AND RELEASE OF SECURITY INTEREST IN PATENTS FILED AT R/F 025795/0627 Recorded Oct 1, 2013
From: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
To: CHEMETALL FOOTE CORP.
Reel/Frame 031324/0815 →
CHANGE OF NAME Recorded Apr 24, 2012
From: CHEMETALL FOOTE CORPORATION
To: ROCKWOOD LITHIUM INC.
Reel/Frame 028123/0563 →
CHANGE OF NAME Recorded Apr 23, 2012
From: CHEMETALL FOOTE CORP.
To: ROCKWOOD LITHIUM INC.
Reel/Frame 028093/0372 →
SECURITY AGREEMENT Recorded Feb 15, 2011
From: CHEMETALL FOOTE CORP.
To: CREDIT SUISSE AG, CAYMAN ISLANDS BRANCH, AS ADMINISTRATIVE AGENT
Reel/Frame 025795/0627 →
Continuity (5)
Division 1133213400 · Jan 13, 2006
Division 1039598400 · Mar 25, 2003
Continuation In Part 0970742700 · Nov 7, 2000
Division 0935318500 · Jul 14, 1999
Related Publication 20070160516A1 · Jul 12, 2007