Peroxide decomposition catalyst particles
View Patent ↗A catalytically active component is provided which comprises particles containing a metal oxide such as silica, metal or metalloid ions such as ions that include boron, and a catalyst. When introduced into the membrane electrode assembly of a fuel cell, the particles increase peroxide radical resistance in a membrane electrode.
1. A fuel cell comprising particles for increasing the hydrogen peroxide radical resistance, said particles comprising:
a metal oxide comprising colloid particles selected from the group consisting of alumina, silica, TiO 2 , Ti 2 O 3 , zirconium oxide, manganese dioxide, manganese oxide, Y 2 O 3 , Fe 2 O 3 , FeO, tin oxide, copper oxide, nickel oxide, tungsten oxide, germania, CeO 2 , Ce 2 O 3 , and combinations thereof,
a stabilizer selected from the group consisting of metal ions and metalloid ions, and combinations thereof, and
at least one catalyst different from the stabilizer and selected from the group consisting of cerium metal, cerium ions, ruthenium metal, and ruthenium ions; wherein the stabilizer metal ions or metalloid ions and catalyst metal or metal ions have been reacted onto the metal oxide particles to obtain multi-metal surface-modified particles.
2. The fuel cell of claim 1 wherein the stabilizer is one or more ions containing an element selected from the group consisting of aluminum, boron, tungsten, titanium, zirconium and vanadium.
3. The fuel cell of claim 1 wherein the colloidal particles have a mean particle diameter of less than 200 nanometers.
4. The fuel cell of claim 3 wherein the colloidal particles contain silica.
5. The fuel cell of claim 3 wherein the metal and metalloid ions include boron ions.
6. The fuel cell of claim 1 wherein the colloidal particles have a mean particle diameter of less than 100 nanometers.
7. The fuel cell of claim 6 wherein the colloidal particles contain silica and boron ions.
8. The fuel cell of claim 1 wherein the colloidal particles have a mean particle diameter of less than 25 nanometers.
9. The fuel cell of claim 8 wherein the colloidal particles contain silica and boron ions.