Viscosity index improver for lubricating oils
View Patent ↗A polymeric viscosity index improver that includes a hydrogenated block copolymer having at least one controlled distribution block copolymer having a minimized crystallinity is provided. An oil composition including at least a base oil and the aforementioned viscosity index improver is also provided. A polymeric concentrate including the aforementioned viscosity index improver is further provided.
1. A liquid oil composition comprising:
a base oil; and
a viscosity index improving amount of about 0.2 to 2.0% by weight of the composition of a hydrogenated block copolymer having at least one polymer block B and optionally at least one polymer block A, and wherein:
a. prior to hydrogenation each A block is a mono alkenyl arene homopolymer block and each B block is a controlled distribution copolymer block of at least one conjugated diene and at least one mono alkenyl arene;
b. subsequent to hydrogenation about 0-10% of the arene double bonds have been reduced, and at least about 90% of the conjugated diene double bonds have been reduced;
c. each A block has a number average molecular weight between about 3,000 and about 60,000 and each B block has a number average molecular weight between about 20,000 and about 300,000;
d. each B block comprises terminal regions adjacent to the A blocks that are rich in conjugated diene units and one or more regions not adjacent to the A blocks that are rich in mono alkenyl arene units;
e. the total amount of mono alkenyl arene in the hydrogenated block copolymer is from about 20 percent weight to about 80 percent weight; and
f. the weight percent of mono alkenyl arene in each B block is between about 10 percent and about 75 percent, with the proviso that when no A blocks are present, then each B block comprises terminal regions that are rich in conjugated diene units and one or more non-terminal units that are rich in mono alkenyl arene units, and with the further proviso that when more than one A block is present, then each A block has a molecular weight of less than about 5000; and optionally one or more components selected from an anti-corrosive additive, an antioxidant, a detergent, a pour point depressant or additional VI improvers that are different from said hydrogenated anionic block copolymer.
2. The oil composition of claim 1 wherein said mono alkenyl arene is styrene, said conjugated diene is selected from the group consisting of isoprene and butadiene, and said polymer block B has mono alkenyl arene blockiness index of less than 40 mol percent.
3. The oil composition of claim 2 wherein said conjugated diene is butadiene, and wherein from about 15 to about 30 mol percent of the condensed butadiene units in block B have a 1,2-configuration.
4. The oil composition of claim 2 wherein the polymer is an ABA polymer and each block B has a center region with a minimum ratio of butadiene units to styrene units.
5. The oil composition of claim 2 wherein the weight percent of styrene in each B block is between about 10 percent and about 50 percent, and the styrene blockiness index of each block B is less than about 10 percent, said styrene blockiness index being defined to be the proportion of styrene units in the block B having two styrene neighbors on the polymer chain.
6. The oil composition of claim 1 wherein said hydrogenated block copolymer has a general configuration (B)m, A-B, A-B-A, (A-B)n, (A-B-A)n, (A-B)n-A, (A-B-A)nX, (A-B)nX, (B-A-B)n, (B-A-B)nX or a mixture thereof, where n is an integer from 2 to about 60, X is coupling agent residue, and m is an integer from 1 to about 60.
7. The oil composition of claim 6 wherein said hydrogenated block polymer has the general configuration (B)m wherein each of the B blocks comprises terminal regions that are rich in conjugated diene units and one or more non-terminal regions that are rich in mono alkenyl arene.
8. The oil composition of claim 1 wherein said hydrogenated block copolymer is a S-EB/S type polymer, wherein the S block has a molecular weight from about 30,000 to about 50,000, the EB unit of the EB/S block has a molecular weight from about 50,000 to about 65,000, the S unit of the EB/S block has a molecular weight from about 30,000 to about 40,000, the EB/S block is selectively hydrogenated to remove at least 90% of the butadiene double bonds, the styrene content of the EB/S block is from about 30 to about 40 weight percent, the 1,2/1,4-butadiene ratio is from about 15/85 to about 30/70, and the total styrene content of the S-EB/S type polymer is from about 50 to about 65.