Highly conductive, multi-layer composite precursor composition to fuel cell flow field plate or bipolar plate
View Patent ↗This invention provides a moldable, multiple-layer composite composition, which is a precursor to an electrically conductive composite flow field plate or bipolar plate. In one preferred embodiment, the composition comprises a plurality of conductive sheets and a plurality of mixture layers of a curable resin and conductive fillers, wherein (A) each conductive sheet is attached to at least one resin-filler mixture layer; (B) at least one of the conductive sheets comprises flexible graphite; and (C) at least one resin-filler mixture layer comprises a thermosetting resin and conductive fillers with the fillers being present in a sufficient quantity to render the resulting flow field plate or bipolar plate electrically conductive with a conductivity no less than 100 S/cm and thickness-direction areal conductivity no less than 200 S/cm 2 .
1. A moldable, multiple-layer precursor composition to an electrically conductive composite flow field plate or bipolar plate, said composition comprising at least a first conductive sheet, a second conductive sheet, and a first conductive filler-resin mixture layer disposed between said first conductive sheet and said second conductive sheet, wherein
(a) at least one of said first conductive sheet and second conductive sheet comprises a flexible graphite sheet; and
(b) said conductive filler is present in a sufficient quantity to render said composition, after being molded into a plate, electrically conductive with a conductivity normal to said flexible graphite sheet no less than 10 S/cm or a conductivity parallel to said flexible graphite sheet no less than 100 S/cm.
2. The precursor composition as defined in claim 1 wherein each of the first conductive sheet and the second conductive sheet comprises a flexible graphite sheet.
3. The precursor composition as defined in claim 1 further comprising a third conductive sheet and a second conductive filler-resin mixture layer to form a five-layer laminate precursor, wherein these five layers are overlaid to one another in the following sequence: the first conductive sheet, the first mixture layer, the second conductive sheet, the second mixture layer, and the third conductive sheet.
4. The precursor composition as defined in claim 3 wherein at least two of the three conductive sheets comprise a flexible graphite sheet.
5. The precursor composition as defined in claim 3 wherein each of the three conductive sheets comprises a flexible graphite sheet.
6. The precursor composition as defined in claim 1 wherein one of the conductive sheets comprises a carbon paper, carbon or graphite fabric, conductive polymer film, or metal foil.
7. The precursor composition as defined in claim 3 wherein at least one but no more than two of the three conductive sheets comprise a carbon paper, carbon or graphite fabric, conductive polymer film, or metal foil.
8. The precursor composition as defined in claim 3 further comprising a third conductive filler-resin mixture layer and a fourth conductive sheet wherein said third mixture layer is attached to the third conductive sheet and said fourth conductive sheet is attached to said third mixture layer to form a seven-layer precursor laminate.
9. The precursor composition as defined in claim 8 wherein at least two of the four conductive sheets comprise a flexible graphite sheet.
10. The precursor composition as defined in claim 8 wherein each of the four conductive sheets comprises a flexible graphite sheet.
11. The precursor composition as defined in claim 8 wherein at least one but no more than three of the conductive sheets comprises a carbon paper, carbon or graphite fabric, conductive polymer film, or metal foil.
12. The precursor composition as defined in claim 1 wherein said resin is selected from the group consisting of unsaturated polyester resin, vinyl ester resin, epoxy resin, phenolic resin, polyimide resin, bismaleimide resin, polyurethane resin, thermoplastic resin, and combinations thereof.
13. The precursor composition as defined in claim 3 wherein said resin is selected from the group consisting of unsaturated polyester resin, vinyl ester, epoxy resin, phenolic resin, polyimide resin, bismaleimide resin, polyurethane resin, thermoplastic resin, and combinations thereof.
14. The precursor composition as defined in claim 1 wherein said conductive filler comprises a conductive material selected from the group consisting of carbon fibers, metal fibers, carbon nano-tubes, graphitic nano-fibers, nano-scaled graphene plates, carbon blacks, metal particles, and combinations thereof.
15. The precursor composition as defined in claim 3 wherein said conductive filler comprises a conductive material selected from the group consisting of carbon fibers, metal fibers, carbon nano-tubes, graphitic nano-fibers, nano-scaled graphene plates, carbon blacks, metal particles, and combinations thereof.
16. The precursor composition as defined in claim 1 wherein said resin comprises a polymerizable, curable, or cross-linkable resin with a catalyst, an accelerator, or a curing agent contained therein.
17. The precursor composition as defined in claim 1 wherein said composition, after molding to form a flow field plate or bipolar plate, has an electrical conductivity parallel to said flexible graphite sheet no less than 200 S/cm.
18. The precursor composition as defined in claim 1 wherein said composition, after molding to form a flow field plate or bipolar plate, has an areal electrical conductivity no less than 200 S/cm 2 .
19. The precursor composition as defined in claim 3 wherein said composition, after molding to form a flow field plate or bipolar plate, has an electrical conductivity parallel to said flexible graphite sheet no less than 200 S/cm or an areal electrical conductivity no less than 200 S/cm 2 .
20. The precursor composition as defined in claim 8 wherein said composition, after molding to form a flow field plate or bipolar plate, has an electrical conductivity no less than 100 S/cm.
21. The precursor composition as defined in claim 1 , wherein said first mixture layer is approximately 40 μm or thinner.
22. The precursor composition as defined in claim 3 wherein said first mixture layer or second mixture layer is approximately 40 μm or thinner.
23. A moldable, multiple-layer precursor composition to an electrically conductive composite flow field plate or bipolar plate, said composition comprising a plurality of conductive sheets and a plurality of conductive filler-resin mixture layers wherein
(A) each conductive sheet is attached to at least one filler-resin mixture layer;
(B) at least one of said conductive sheets comprises flexible graphite; and
(C) at least one filler-resin mixture layer comprises a thermosetting resin and conductive fillers with the fillers being present in a sufficient quantity to render said flow field plate or bipolar plate, after molding, electrically conductive with an electrical conductivity no less than 100 S/cm or an areal electrical conductivity no less than 200 S/cm 2 .
24. The multiple-layer precursor composition as defined in claim 23 wherein said composition has two opposing outer sheets, which are a top sheet and a bottom sheet, each comprising flexible graphite.
25. The multiple-layer precursor composition as defined in claim 23 wherein a conductivity of said molded plate is greater than 200 S/cm.
26. The multiple-layer precursor composition as defined in claim 23 , wherein said conductive fillers comprise a conductive material selected from the group consisting of carbon fibers, metal fibers, carbon nano-tubes, graphitic nano-fibers, nano-scaled graphene plates, carbon blacks, metal particles, and combinations thereof.
27. A moldable, bi-layer precursor composition to an electrically conductive composite flow field plate or bipolar plate, said composition comprising a first flexible graphite sheet and a first conductive filler-resin mixture layer overlaying said first conductive sheet, wherein said conductive filler is present in a sufficient quantity to render said composition, after being molded into a plate, electrically conductive with a conductivity normal to said flexible graphite sheet no less than 10 S/cm or a conductivity parallel to said flexible graphite sheet no less than 100 S/cm.
28. The precursor composition as defined in claim 27 , further comprising a non-sticking protective layer overlaying said first conductive filler-resin layer.
29. The precursor composition as defined in claim 3 , wherein a resin in a filler-resin mixture is cured or solidified to form a fuel cell bipolar plate or flow field plate comprising a flow field channel on at least a surface of said plate.
30. The precursor composition as defined in claim 8 , wherein a resin in a filler-resin mixture is cured or solidified to form a fuel cell bipolar plate or flow field plate comprising a flow field channel on at least a surface of said plate.