Fuel cell assembly having long life characteristics
View Patent ↗A fuel cell assembly ( 20 ) has a plurality of characteristics that extend the useful life of the assembly. In one example, flow field layers are non-porous and hydrophobic such that they have an acid absorption rate of less than about 0.10 mg/khr-cm 2 . An electrolyte retaining matrix has a reaction rate with phosphoric acid of less than about 0.010 mg/khr-cm 2 . Hydrophilic substrates associated with catalyst layers have an initial transferable phosphoric acid content of less than about 25 mg/cm 2 . A condensation zone provides an evaporative phosphoric acid loss rate that is less than about 0.17 mg/khr-cm 2 .
1. A fuel cell assembly, comprising:
a separator plate;
a first flow field layer and a second flow field layer associated with the separator plate, the flow field layers having an acid absorption rate of less than about 0.10 mg/khr-cm 2 ;
an electrolyte retaining matrix having a reaction rate with phosphoric acid of less than about 0.010 mg/khr-cm 2 ;
a cathode catalyst layer;
an anode catalyst layer;
hydrophilic substrates associated with the catalyst layers, the hydrophilic substrates having an initial transferable phosphoric acid content of less than about 45 mg/cm 2 ; and
a condensation zone that provides an evaporative phosphoric acid loss rate of less than about 0.27 mg/khr-cm 2 .
2. The assembly of claim 1 , wherein the hydrophilic substrates are about 70% porous and have a void volume that is about 40% filled in an initial condition with the transferable phosphoric acid and have a thickness of about 0.46 mm.
3. The assembly of claim 1 , wherein the transferable phosphoric acid content of the hydrophilic substrates are less than about 35 mg/cm 2 .
4. The assembly of claim 3 , wherein the hydrophilic substrates are about 70% porous and have a void volume that is about 40% filled in an initial condition with the transferable phosphoric acid and have a thickness of about 0.37 mm.
5. The assembly of claim 1 , wherein the transferable phosphoric acid content of the hydrophilic substrates are less than about 25 mg/cm 2 .
6. The assembly of claim 5 , wherein the hydrophilic substrates are about 70% porous and have a void volume that is about 40% filled in an initial condition with the transferable phosphoric acid and have a thickness of about 0.25 mm.
7. The assembly of claim 1 , wherein the electrolyte retaining matrix comprises silicon carbide powder having a mean particle size of about 3 microns and has a thickness of about 0.05 mm.
8. The assembly of claim 1 , wherein the condensation zone is near an edge of the assembly and has a length and wherein at least the cathode catalyst layer is spaced from the edge by at least the length of the condensation zone.
9. The assembly of claim 8 , including a cooling portion having a higher rate of cooling near the condensation zone than near other portions of the assembly.
10. The assembly of claim 1 , wherein the condensation zone cools a vapor passing from the assembly to less than about 140° C.
11. The assembly of claim 1 , wherein the condensation zone provides an evaporative phosphoric acid loss rate of less than about 0.17 mg/khr-cm 2 .
12. The assembly of claim 1 , wherein the flow field layers are hydrophobic and non-porous.
13. The assembly of claim 12 , wherein the flow field layers comprise flake graphite and a hydrophobic resin.
14. A method of operating a phosphoric acid fuel cell assembly, comprising the steps of:
maintaining an acid absorption rate of less than about 0.10 mg/khr-cm 2 ;
maintaining a reaction rate of an electrolyte matrix with phosphoric acid of less than about 0.010 mg/khr-cm 2 ;
providing hydrophilic substrates with an initial transferable phosphoric acid content of less than about 45 mg/cm 2 ; and
maintaining an evaporative phosphoric acid loss rate of less than about 0.27 mg/khr-cm 2 .
15. The method of claim 14 , including maintaining an evaporative phosphoric acid loss rate of less than about 0.17 mg/khr-cm 2 .
16. The method of claim 15 , including cooling vapor exiting the assembly to a temperature that is less than about 140° C.
17. The method of claim 14 , including providing the hydrophilic substrates with less than about 35 mg/cm 2 phosphoric acid.
18. The method of claim 17 , including providing the hydrophilic substrates with less than about 25 mg/cm 2 phosphoric acid.