Method for the hydrogenation of ketones
View Patent ↗The invention relates to a process for hydrogenating ketones, wherein the ketone is fed in a mixture with hydrogen to a catalyst bed which comprises a copper chromite catalyst which has a proportion of SiO 2 as catalyst.
1. A process for hydrogenating phenyl ketones, comprising feeding the ketone in a mixture with hydrogen to a catalyst bed containing catalysts which comprise a copper chromite catalyst which has a proportion of SiO 2 , wherein the catalyst comprises copper in a proportion of 30 to 40% by weight, and chromium in a proportion of 20 to 30% by weight, and the proportion of SiO 2 is within the range from 5 to 15% by weight, base on the oxidized form of the catalyst, and wherein the catalyst is provided by preparing and combining aqueous solution of metal salts, so that a precipitate is obtained, wherein SiO 2 is added to at least one of the metal salt solutions.
2. The process as claimed in claim 1 wherein the copper chromite catalyst, based on the oxidized catalyst, contains promoter metals in a proportion of from 1 to 6% by weight.
3. The process as claimed in claim 2 wherein the promoter metals are selected form barium and/or manganese.
4. The process as claimed in claim 1 , wherein the hydrogenation is performed within a pressure range of from 10 to 200 bar, at a temperature of more than 70° C. and at an LHSV in the range of from 0.5 to 1.5.
5. The process as claimed in claim 1 wherein no inert carrier gas is added to the hydrogen and to the ketone.
6. The process as claimed in claim 1 wherein the phenyl ketone is acetophenone.
7. A process for hydrogenating phenyl ketones, comprising feeding the ketone in a mixture with hydrogen to a catalyst bed containing catalysts which comprise a copper chromite catalyst which has a proportion of SiO 2 , wherein the catalyst is provided by preparing and combining aqueous solutions of metal salts, so that a precipitate is obtained, wherein SiO 2 is added to at least one of the metal salt solutions.
8. The process as claimed in claim 1 , wherein the copper chromite catalyst has a specific surface area of from about 50 to 80 m 2 /g.
9. The process as claimed in claim 1 , wherein the catalyst bed is configured as a fixed bed.
10. The process as claimed in claim 7 wherein the copper chromite catalyst has a specific surface area of from about 50 to 80 m 2 /g.
11. The process as claimed in claim 7 wherein the catalyst bed is configured as a fixed bed.