Catalyst for producing carbon nanotubes by means of the decomposition of gaseous carbon compounds on a heterogeneous catalyst
View Patent ↗The present invention relates to a process for the production of carbon nanotubes, in particular those having a diameter of 3-150 nm and an aspect ratio of length:diameter (L:D)>100, by decomposition of hydrocarbons on a heterogeneous catalyst which comprises Mn, Co, preferably also molybdenum, and an inert support material, and the catalyst and the carbon nanotubes themselves and the use thereof.
1. A process for producing carbon nanotubes comprising:
a) preparing a catalyst by joint precipitation:
b) thermally pretreating the catalyst in an oxidizing atmosphere at a temperature between 300° C. and 900° C.; and
c) decomposing a gaseous hydrocarbon on the catalyst to form carbon nanotubes;
wherein the catalyst consists essentially of
(1) catalytically active metal compounds based on Mn and Co and optionally one or more compounds based on Mo, Cu, W, V, Cr, or Sn; and
(2) an inert material selected from the group consisting of one or more compounds of Ca, Mg, Al, Ce, Ti, and La;
wherein said Mn is present in said catalyst in an amount in the range from 25-75 mol % and Co is present in said catalyst in an amount in the range of from 25-75 mol %, based on the total content of Mn and Co and optionally Mo, Cu, W, V, Cr, or Sn.
2. The process of claim 1 , wherein said catalyst further consists essentially of one or more compounds based on Mo.
3. The process of claim 1 , wherein said Mn is present in said catalyst in an amount in the range of from 10 to 90 mol %, based on the total content of Mn and Co and optionally Mo, Cu, W, V, Cr, or Sn, and said Co is present in said catalyst in an amount in the range of from 10 to 90 mol %, based on the total content of Mn and Co and optionally Mo, Cu, W, V, Cr, or Sn.
4. The process of claim 1 , wherein said catalyst further consists essentially of one or more compounds based on Cu, W, V, Cr, or Sn.
5. The process of claim 1 , wherein said catalyst further consists essentially of one or more compounds based on Cu, W, V, Cr, or Sn in an amount in the range of from 0.2 to 50 mol %.
6. The process as claimed in claim 1 , wherein the carbon nanotubes have a main diameter of from 3 nm to 150 nm and the process is conducted by decomposition of a gaseous hydrocarbon on said catalyst and said catalyst is a heterogenous catalyst.
7. The process according to claim 1 , wherein said hydrocarbon is in the form of an educt gas.
8. The process according to claim 7 , wherein said educt gas is a light hydrocarbon.
9. The process according to claim 8 , wherein said light hydrocarbon is an aliphatic, olefin, or mixture thereof.
10. The process according to claim 1 , wherein said process is performed in a reaction chamber and further comprises continuously feeding said catalyst and removing carbon nanotubes formed together with spent catalyst.
11. The process according to claim 1 , wherein said process is performed in a reaction chamber and further comprises discontinuously feeding said catalyst and removing carbon nanotubes formed together with spent catalyst.
12. The process according to claim 1 , wherein said process is performed in a reaction chamber and further comprises introducing said catalyst into said reaction chamber in a form wherein the-catalytically active metal compounds of said catalyst are in the form of partly or completely reduced oxides or as hydroxides.
13. The process according to claim 1 , wherein the inert material comprises Mg.