Orgasol synthesis method with large grain silica
View Patent ↗The invention relates to a method for obtaining polyamide or copolyamide particles which are spheroidal and whose average diameter is between 40 and 150 μm, preferably between 60 and 100 μm. Said method consists of introducing a mineral charge, preferably silica, having an average diameter of 1-30 μm into the reaction mixture. The invention also relates to a polyamide or copolyester amide powder and to the use thereof in order to manufacture coatings, ink compositions, paint compositions, cosmetic compositions, pharmaceutical compositions, alloys with metal powders or metal oxide powders and parts by agglomerating said powder by laser sintering, IR radiation or UV radiation.
1. A process for the production of polyamide or copolyesteramide powder particles comprising the steps of
a) admixing into a reaction medium an inorganic filler with a mean diameter of between 1 and 30 μm, and at least one polymerizable monomer; and
b) polymerizing said admixture, resulting in powder particles having a mean diameter of between 60 and 150 μm and a standard deviation of 1.22 or less.
2. The process as claimed in claim 1 , wherein the polyamide or copolyesteramide powder particles have a mean diameter of between 60 and 100 μm.
3. The process as claimed in claim 1 , wherein the polyamide or copolyesteramide powder particles have a spheroidal shape.
4. The process as claimed in claim 1 , wherein the mean diameter of the inorganic filler is between 2 and 20 μm.
5. The process as claimed in claim 4 , wherein the mean diameter of the inorganic filler is between 3 and 11 μm.
6. The process as claimed in claim 5 , wherein the mean diameter of the inorganic filler is between 4 and 8 μm.
7. The process as claimed in claim 1 , wherein the inorganic filler is chosen from silicas, aluminosilicates, aluminum oxides or alumina and/or titanium dioxide.
8. The process as claimed in claim 7 , wherein the inorganic filler is a silica.
9. The process as claimed in claim 8 , wherein the silica is chosen from the silicas manufactured according to a precipitation process.
10. The process as claimed in claim 8 , wherein the silica is chosen from the silicas sold under the trade name SIPERNAT® 320 DS or SIPERNAT® 50 S from Degussa or from the silicas sold under the trade name SYLOID® 807, SYLOID® ED2 or SYLOID® ED5 from Grace.
11. The process as claimed in claim 1 , wherein the ratio by weight of the inorganic filler with respect to the polymerizable monomer or monomers is between 10 and 50 000 ppm.
12. The process as claimed in claim 1 , wherein the polymerizable monomer or monomers is or are chosen from lauryllactam, caprolactam, enantholactam and capryllactam.
13. The process as claimed in claim 1 , wherein the polymer particles are made of polyamide 12, polyamide 6 or polyamide 6/12.
14. The process as claimed in claim 1 , wherein a mixture comprising, in molar %, the total being 100%:
from 1 to 98% of a lactam chosen from lauryllactam, caprolactam, enantholactam and capryllactam;
from 1 to 98% of a lactam, other than the above, chosen from lauryllactam, caprolactam, enantholactam and capryllactam;
from 1 to 98% of a lactone chosen from caprolactone, valerolactone and butyrolactone,
is polymerized.
15. The process as claimed in claim 1 , wherein at least one N,N′-alkylenebisamide is added to the reaction medium.
16. The process as claimed in claim 1 , wherein use is made, as solvent, of a paraffinic hydrocarbon fraction, the boiling range of which is between 120 and 170° C.
17. The process as claimed in claim 11 , wherein the ratio by weight of the inorganic filler with respect to the polymerizable monomer or monomers is between 100 and 20 000 ppm.
18. A process for the production of polyamide or copolyesteramide powder particles having a mean diameter of between 60 and 100 μm, the process consisting of:
a) adjusting the mean diameter of the powder particles to be within the range of 60 and 100 μm by admixing at least one inorganic filler with a mean diameter of between 2 and 20 μm, at least one polymerizable monomer, and a reaction medium;
b) maintaining a mixing speed at or above 350 revolutions/minute; and
c) polymerizing the admixture.