Modified styrene-maleic acid copolymer and use thereof
View Patent ↗The present invention relates to a modified styrene-maleic acid copolymer obtained by reacting a carboxylic acid group in a styrene-maleic acid copolymer with a halogen and/or epoxy compound. The modified styrene-maleic acid copolymer is useful as a low profile additive for a thermosetting resin, a water-absorbing material, etc.
1. A modified styrene-maleic acid copolymer, which is produced by a process comprising reacting a carboxylic acid salt in a styrene-maleic acid copolymer with a halogen compound containing one halogen and no polymerizable unsaturated groups, the halogen compound being selected from the group consisting of benzyl chloride and a benzyl chloride compound having a substituent bound to the benzene ring, except for nitrobenzyl chloride, wherein the styrene-maleic acid copolymer to be modified is represented by a formula,
where A is a metal element, m is a number from 1 to 3, n is a number from 3 to 300, and both ends are hydrogen atoms, with the proviso that when A is a di- or more valent metal element, the metal element may form a salt with plural caboxy groups which are not limited to ones in a same molecule, and the modified styrene-maleic acid copolymer has at least one ester group formed by a reaction of at least one of carboxyl groups of the styrene-maleic acid copolymer and the group other than halogen of the halogen compound and wherein a modification rate of the carboxyl groups of the styrene-maleic acid copolymer is from 70% to 95%.
2. The modified styrene-maleic acid copolymer according to claim 1 , which is produced by the process comprising reacting the carboxylic acid salt in the styrene-maleic acid copolymer with the halogen compound such that the amount of the halogen in the compound is ⅘ or more equivalent relative to the amount of the carboxylic acid salt in the copolymer.
3. The modified styrene-maleic acid copolymer according to claim 1 , wherein the styrene-maleic acid copolymer to be modified is produced by a process comprising decomposing a thermosetting resin comprising a polyester and its crosslinking moiety with subcritical water.
4. The modified styrene-maleic acid copolymer according to claim 1 , wherein the benzyl chloride compound is methylbenzyl chloride.
5. The modified styrene-maleic acid copolymer according to claim 1 , wherein a modification rate of the carboxyl groups of the styrene-maleic acid copolymer is from 85% to 95%.