Organic compound containing at least two carbazolyl-substituted phenyl structures; charge-transporting material and organic el element containing the compound
View Patent ↗An organic compound and a charge-transporting material which are excellent in both a hole-transporting property and an electron-transporting property and have excellent electrical oxidation/reduction durability and a high triplet excitation level are provided, and an organic electroluminescent device which uses this organic compound and has high luminous efficiency and high driving stability and long lifetime is provided, wherein the organic compound has two or more partial structures represented by the following Formula (I): wherein Cz denotes a carbazolyl group; Z is as defined; and Q denotes a direct link connected to G present in a moiety represented by the following Formula (II): wherein B 1 ring is a six-membered aromatic heterocycle containing n N atoms as a hetero atom; n is an integer of 1 to 3; G is as defined; and m is an integer of 3 to 5.
1. An organic compound comprising two or more partial structures represented by the following Formula (I):
wherein Cz denotes a carbazolyl group;
Z denotes a direct link or an optional linking group;
Cz, Z, and an A 1 ring may have a substituent;
the Cz's may be the same or different;
the Z's may be the same or different;
the A 1 rings may be the same or different;
Q denotes a direct link connecting to G present in a moiety represented by one of the following Formulae (II-1) to (II-4), and the number of groups represented by any of Formulae (II-1) to (II-4) in said compound is one,
when G is linked to Q, the G denotes a direct link or an optional linking group which links to Q;
when G is not linked to Q, the G denotes an aromatic hydrocarbon group;
the G's may be the same or different; and
rings in the Formulae (II-1) to (II-4) may have a substituent in addition to G.
2. The organic compound according to claim 1 , wherein the moiety represented by Formula (II-1) is present.
3. The organic compound according to claim 1 , wherein Formula (I) is represented by the following Formula (I-1):
wherein Z, A 1 ring, and Q are the same as those in Formula (I).
4. The organic compound according to claim 1 , wherein G and Z are each a direct link or -(Ph) p - (where Ph denotes a phenylene group which may have a substituent, and p is an integer of 1 to 8).
5. The organic compound according to claim 1 , the organic compound being represented by the following Formula (III):
wherein Cz, Z, A 1 ring, and Q are the same as those in Formula (I), and G is the same as that in Formulae (II-1) to (II-4);
a, b, and c each denote the number of Z-Cz;
a, b, and c are each independently an integer of 0 to 5;
a+b+c is an integer not less than 2; and
the 3-position and/or 5-position of C 1 ring may be substituted with an optional substituent, and wherein
Z-Cz groups are present in a meta position to Q on at least two A 1 rings.
6. The organic compound according to claim 5 , wherein a and c in Formula (III) are each 1.
7. The organic compound according to claim 5 , wherein b in Formula (III) is 0 or 1.
8. The organic compound according to claim 5 , wherein G in Formula (III) is represented by -(Ph) p - (where Ph denotes a phenylene group which may have a substituent, and p is an integer of 1 to 8).
9. The organic compound according to claim 1 , wherein N atoms which do not conjugate with each other are not linked with the following partial structures:
wherein G 1 , G 2 , and G 3 each independently denote a hydrogen atom or an optional substituent or constitute part of an aromatic hydrocarbon ring or an aromatic heterocycle.
10. The organic compound according to claim 1 , wherein one molecule of the organic compound comprises two or three partial structures represented by Formula (I).
11. The organic compound according to claim 1 , wherein A 1 ring has only Z and Q as substituents.
12. The organic compound according to claim 1 , wherein the partial structure represented by Formula (I) excluding the part represented by one of Formulae (II-1) to (II-4)
is selected from the following V-1, V-2, V-3, V-5, V-6, and V-12:
13. The organic compound according to claim 1 , wherein the organic compound has a molecular weight of 200 to 4000.
14. The organic compound according to claim 1 , wherein the organic compound has a glass transition temperature of 90° C. or more, a vaporization temperature of 700° C. or less, and a melting point of 150° C. or more.
15. The organic compound according to claim 5 , wherein Formula (III) is represented by the following Formula (IV):
wherein Cz, Z, Q, and A 1 ring are the same as those in Formula (I), G is the same as that in Formulae (II-1) to (II-4), and C 1 ring is the same as that in Formula (III).
16. The organic compound according to claim 5 , wherein Formula (III) is represented by the following Formula (V):
wherein Cz, Z, Q, and A 1 ring are the same as those in Formula (I), G is the same as that in Formulae (II-1) to (II-4), and C 1 ring is the same as that in Formula (III).
17. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
18. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
19. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
20. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
21. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
22. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
23. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
24. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
25. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
26. The organic compound according to claim 1 , the organic compound being represented by the following structural formula:
27. A charge-transporting material, the material contains an organic compound according to claim 1 .
28. An organic electroluminescent device comprising an anode, a cathode, and an organic light-emitting layer disposed between the both electrodes on a substrate, the organic electroluminescent device having a layer containing an organic compound according to claim 1 .
29. The organic electroluminescent device according to claim 28 , wherein the layer containing the organic compound is the organic light-emitting layer.
30. The organic electroluminescent device according to claim 29 , wherein the organic compound according to claim 1 is a host material of the organic light-emitting layer, and the host material is doped with an organometallic complex.