Turbine engine components with non-aluminide silicon-containing and chromium-containing protective coatings and methods of forming such non-aluminide protective coatings
View Patent ↗A turbine engine component ( 10 ) with a non-aluminide protective coating ( 14 ) containing silicon and chromium and a process for forming such non-aluminide protective coatings ( 14 ). The non-aluminide protective coating ( 14 ) is formed by applying a silicon-containing fluid composition to the turbine engine component ( 10 ) as a silicon-containing layer ( 20 ) and heating the silicon-containing layer ( 20 ) to a temperature effective to form the non-aluminide protective coating ( 14 ).
1. A coating process for protecting a metal component ( 10 ), comprising:
applying a layer ( 20 ) of a silicon-containing fluid composition comprising a silane liquid to at least a portion of the metal component ( 10 ), wherein the silane liquid defines an amino silane or includes a mono, bis, or tri-functional trialkoxy silane;
applying a chromium-containing substance to the metal component ( 10 ) as a constituent of the silicon-containing fluid composition in layer ( 20 ),
curing the silicon-containing fluid composition after the layer ( 20 ) is applied to the metal component ( 10 );
and heating the cured silicon-containing fluid composition to a temperature effective to form a non-aluminide protective coating ( 14 ) on the metal component ( 10 ), the protective coating ( 14 ) including a diffusion zone that includes silicon diffused from the cured silicon-containing fluid composition and chromium;
wherein applying the chromium-containing substance further comprises:
applying a halide activator and an inert diluent powder to the metal component ( 10 ) as constituents of the silicon-containing fluid composition in layer ( 20 ), the inert diluent powder preventing sintering of the chromium-containing substance in the layer ( 20 ) during the heating of the cured silicon-containing fluid composition.
2. A coating process for protecting a turbine engine component ( 10 ) having a first section ( 28 ) with an airflow surface ( 34 ) and a second section ( 32 ) used to secure the first section ( 28 ) to the gas turbine engine, the coating process comprising:
applying a layer ( 20 ) of a silicon-containing fluid composition comprising a silane liquid into direct contact with at least a portion of the second section ( 32 ) of the turbine engine component ( 10 ), wherein the silane liquid defines an amino silane or includes a mono, bis, or tri-functional trialkoxy silane;
curing the silicon-containing fluid composition after the layer ( 20 ) is applied to the second section ( 32 ) of the turbine engine component ( 10 );
heating the cured silicon-containing fluid composition to a temperature effective to form a non-aluminide protective coating ( 14 ) on the second section ( 32 ) of the turbine engine component ( 10 ), the protective coating ( 14 ) including a diffusion zone that includes silicon diffused from the cured silicon-containing fluid composition and that further includes chromium diffused from the material of the turbine engine component ( 10 ); and
placing the silicon-containing fluid composition in an oxidizing atmosphere before heating the cured silicon-containing fluid composition, whereby, following heating in the oxidizing atmosphere, the protective coating ( 14 ) includes a compound containing silicon and oxygen.
3. A coating process for protecting a turbine engine component ( 10 ) having a first section ( 28 ) with an airflow surface ( 34 ) and a second section ( 32 ) used to secure the first section ( 28 ) to the gas turbine engine, the coating process comprising:
applying a layer ( 20 ) of a silicon-containing fluid composition comprising a silane liquid into direct contact with at least a portion of the second section ( 32 ) of the turbine engine component ( 10 ), wherein the silane liquid defines an amino silane or includes a mono, bis, or tri-functional trialkoxy silane;
curing the silicon-containing fluid composition after the layer ( 20 ) is applied to the second section ( 32 ) of the turbine engine component ( 10 ); and
heating the cured silicon-containing fluid composition to a temperature effective to form a non-aluminide protective coating ( 14 ) on the second section ( 32 ) of the turbine engine component ( 10 ), the protective coating ( 14 ) including a diffusion zone that includes silicon diffused from the cured silicon-containing fluid composition and that further includes chromium diffused from the material of the turbine engine component ( 10 ); and further comprising:
adding a dopant selected from the group consisting of yttrium, hafnium, and combinations thereof to the silane liquid, the dopant being dissolved in the silane liquid.