Reduced foam dispersions and formulations therefor
View Patent ↗A composition and method for dispersing an agriculturally active agent are disclosed. In an embodiment, a solid agrochemical formulation is disclosed. The solid agrochemical formulation comprises an agriculturally active agent, a fatty acid salt, and a chelating agent.
1. A solid agrochemical formulation comprising an agriculturally active agent and a defoaming composition comprising a fatty acid salt and a chelating agent, wherein a level of the defoaming composition is from about 0.1% w/w to about 20% w/w.
2. The formulation of claim 1 wherein the agriculturally active agent comprises herbicides, insecticides, fungicides, biocides, molluscicides, algaicides, plant growth regulators, anthelminthics, rodenticides, nematocides, acaricides, amoebicides, protozoacides, crop safeners, adjuvants, or combinations thereof.
3. The formulation of claim 1 wherein the agriculturally active agent comprises triazine, urea, or combinations thereof.
4. The formulation of claim 3 wherein the solid agrochemical formulation is in a WDG or WP formulation.
5. The formulation of claim 1 wherein the agriculturally active agent comprises atrazine, simazine, or combinations thereof.
6. The formulation of claim 1 wherein the fatty acid salt comprises C 8 to C 21 fatty acids.
7. The formulation of claim 1 wherein the fatty acid salt comprises sodium stearate, sodium oleate, aluminum stearate, or combinations thereof.
8. The formulation of claim 1 wherein the chelating agent comprises ethylene diamine tetraacetic acid, gluconic acid, nitrilotriacetic acid, diethylenetriamine pentaacetic acid, salts thereof, hydrates thereof or combinations thereof.
9. The formulation of claim 7 wherein the chelating agent comprises ethylene diamine tetraacetic acid.
10. The formulation of claim 1 wherein the ratio of fatty acid salt to chelating agent is from about 1:100 to about 100:1.
11. The formulation of claim 1 wherein the fatty acid salt and chelating agent are present in the ratio of about 1:1.5 to about 1:3.
12. The formulation of claim 1 , wherein the defoaming composition further comprises a polyacid polymer.
13. The formulation of claim 12 wherein the polyacid polymer comprises sodium polyacrylate.
14. The formulation of claim 13 wherein the sodium polyacrylate has a molecular weight of from about 500 daltons to about 20,000 daltons.
15. The formulation of claim 12 wherein the ratio of polyacid polymer to fatty acid salt and chelating agent is from about 1:3 to about 1:1.
16. The formulation of claim 1 further comprising a wetting agent.
17. The formulation of claim 16 wherein the wetting agent is present in the formulation in amounts from about 1% w/w to about 3% w/w.
18. The formulation of claim 1 further comprising a dispersing agent.
19. The formulation of claim 1 wherein the formulation comprises a pH from about 4 to about 9.
20. The formulation of claim 1 wherein the formulation is in the form of a water dispersible granule or wettable powder.
21. The formulation of claim 15 , wherein the sodium polyacrylate has a molecular weight of from about 2,100 daltons to about 3,500 daltons.
22. The formulation of claim 7 , wherein the chelating agent comprises ethylene diamine tetraacetic acid, gluconic acid, nitrilotriacetic acid, diethylenetriamine pentaacetic acid, salts thereof, hydrates thereof or combinations thereof.
23. The formulation of claim 1 , wherein the defoaming composition further comprises a sodium salt of a polyacrylic acid copolymer and a pH from about 6 to 7, and a level of the defoaming composition is from about 1.2 wt % to about 2.5 wt % of the formulation.
24. A suspension concentrate formulation comprising water and a solid agrochemical formulation comprising an agriculturally active agent and a defoaming composition comprising a fatty acid salt and a chelating agent, wherein a level of the defoaming composition in the agrochemical formulation is from about 0.1% w/w to about 20% w/w.
25. The formulation of claim 24 wherein the agriculturally active agent comprises atrazine, simazine, or combinations thereof.
26. The formulation of claim 24 wherein the fatty acid salt comprises C 8 to C 21 fatty acids.
27. The formulation of claim 24 further comprising a polyacid polymer.
28. A method for preparing an aqueous dispersion of an agriculturally active agent in solid form comprising the steps of:
(A) providing a composition comprising an agriculturally active agent and a defoaming composition comprising a fatty acid salt, a chelating agent, and a polyacid polymer; and
(B) dispersing the composition in water.
29. The method of claim 28 wherein the level of the defoaming composition is from about 0.1% w/w to about 20% w/w.
30. The method of claim 29 wherein the ratio of polyacid polymer to fatty acid salt and chelating agent is from about 1:50 to about 50:1.
31. The method of claim 30 , wherein the polyacid polymer is added as a sodium salt having molecular weight less than about 10,000 daltons.