Heat resistant air hose
View Patent ↗A heat resistant air hose which is excellent in oil-bleeding resistance and causes reduced vibration noise is provided. The heat resistant air hose has an inner layer formed of an inner layer material comprising silicone rubber as a major component thereof; and an outer layer provided on an outer periphery of the inner layer and formed of an outer layer material comprising acrylic rubber as a major component thereof, and the acrylic rubber contains not less than 50 wt % of ethyl acrylate and has a dissipation factor (tan δ) of not less than 0.09 at 150 ° C. and a storage elastic modulus (E′) of not less than 7.0 MPa.
1. A heat resistant air hose having an inner layer formed of an inner layer material comprising silicone rubber as a sole rubber component thereof; and an outer layer provided on an outer periphery of the inner layer and formed of an outer layer material comprising acrylic rubber as a sole rubber component thereof, the acrylic rubber containing n-butyl acrylate and not less than 70 wt % of ethyl acrylate and having a dissipation factor (tan δ) of not less than 0.10 at 150° C. and a storage elastic modulus (E′) of not less than 7.8 MPa.
2. A heat resistant air hose as set forth in claim 1 , wherein the acrylic rubber in the outer layer material contains a crosslinking group comprising at least one of an epoxy group and a carboxyl group.
3. A heat resistant air hose as set forth in claim 1 , further comprising a reinforcing fiber layer interposed between the inner layer and the outer layer.
4. A heat resistant air hose as set forth in claim 3 , wherein the reinforcing fiber layer comprises braided para-type aromatic polyamide materials.
5. A heat resistant air hose as set forth in claim 3 , wherein the reinforcing fiber layer comprises spirally wound, braided, or knitted reinforcing fiber.
6. A heat resistant air hose as set forth in claim 5 , wherein the reinforcing fiber layer comprising the braided fibers has warp counts of 2 to 4 and pick counts of 30 to 50.
7. A heat resistant air hose as set forth in claim 1 , wherein the air hose is a heat resistant air hose for transportation systems.
8. A heat resistant air hose as set forth in claim 1 , wherein methylvinyl silicone rubber (VMQ) is used as the silicone rubber in the inner layer material.
9. A heat resistant air hose as set forth in claim 1 , wherein the acrylic rubber in the outer layer material has a dissipation factor (tan δ) in the range between 0.10 and 0.12 at 150° C. and a storage elastic modulus (E′) in the range between 7.8 MPa and 9.2 MPa.
10. A heat resistant air hose as set forth in claim 1 , wherein the outer layer material contains at least one of 1-methyl-2-methylimidazol and hexamethylenediamine carbamate as a vulcanizing agent.
11. A heat resistant air hose as set forth in claim 10 , wherein the vulcanizing agent is present in a proportion of 0.1 parts by weight to 10 parts by weight based on 100 parts by weight of the acrylic rubber.
12. A heat resistant air hose as set forth in claim 1 , wherein the outer layer material contains at least one vulcanizing agent selected from the group consisting of trimethylthiourea, stearyltrimethylammonium bromide, and di-o-tolylguanidine.
13. A heat resistant air hose as set forth in claim 12 , wherein the vulcanizing agent is present in a proportion of 0.3 parts by weight to 2 parts by weight based on 100 parts by weight of the acrylic rubber.