IP Library Granted Patent US 8,404,365
Granted Patent B2
US 8,404,365 · App. 11/726,411 · Granted Mar 26, 2013

Paper for gypsum wallboard

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Quick Facts
Patent No.
US 8,404,365
App. No.
11/726,411
Granted
Mar 26, 2013
Kind
B2
Abstract

Paper useful in the manufacture of gypsum wallboard is surfaced treated with an additive to improve the bonding affinity of the paper for wet plaster thereby permitting the manufacture of gypsum wallboard with little or no added starch and reduced amounts of water. A surface treating adhesive, a method of converting the paper and wallboards containing the paper are also described.

Claims (18)

1. A wallboard comprising:

an interior gypsum plaster core; and

at least one treated paper adhered to a surface of the interior gypsum plaster core,

wherein the treated paper further comprises a paper sheet, a surface of the paper sheet is treated with a surface treating adhesive, the surface treating adhesive comprises water, a latex binder and a mineral filler, the latex binder is selected from the group consisting of ethylene polyvinyl acetate, poly(vinyl acetate) (PVOAc) latex, styrene butadiene (SBR), acrylic, and vinyl acrylic, the latex binder comprises about 1-55 wt % of the surface treating adhesive and the mineral filler comprises about 1-50 wt % of the surface treatment adhesive, and wherein the surface of the interior gypsum plaster core is adhered to the surface of the paper sheet treated with the surface treating adhesive.

2. The wallboard of claim 1 , wherein the latex binder comprises ethylene polyvinyl acetate latex.

3. The wallboard of claim 1 , wherein the mineral filler is selected from the group consisting of calcium sulfate hemi hydrate, calcium sulfate dihydrate, ground gypsum, Portland cement, calcium carbonate, clays, and powdered silica.

4. The wallboard of claim 3 , wherein the mineral filler comprises calcium sulfate hemi hydrate.

5. The wallboard of claim 1 , wherein the surface treating adhesive further comprises a water-soluble species selected from the group consisting of rheology modifiers, salts, accelerators and dispersants.

6. The wallboard of claim 5 , wherein the rheology modifier comprises a cellulose ether.

7. The wallboard of claim 6 , wherein the cellulose ether is selected from the group consisting of carboxymethylcellulose(CMC), hydroxypropylmethylcellulose (HPMC), methylcellulose(MC), hydroxypropylcellulose(HPC), hydrophobically modified hydroxypropylcellulose(HMHPC), hydroxyethylcellulose(HEC), ethyl hydroxyethylcellulose (EHEC), hydrophobically modified hydroxyethylcellulose(HMHEC), cationic hydrophobically modified hydroxyethylcellulose(cationic HMHEC), and anionic hydrophobically modified hydroxyethylcellulose (anionic HMHEC).

8. The wallboard of claim 7 , wherein the cellulose ether comprises hydroxyethylcellulose(HEC).

9. The wallboard of claim 5 , wherein the rheology modifier comprises xanthan gum.

10. The wallboard of claim 1 , wherein the amount of the surface treatment adhesive used to treat the paper is of a level of greater than about 0.1 g/m 2 .

11. The wallboard of claim 10 , wherein the amount of the surface treatment adhesive used to treat the paper is in the range of greater than about 0.1 g/m 2 to about 4 g/m 2 .

12. The wallboard of claim 1 , wherein the surface-treated paper has a Gurley porosity measurement of less than 20 seconds difference when compared to a the paper sheet without the surface treating adhesive using a Hagerty Porosimeter apparatus at a “low” setting.

13. The wallboard of claim 1 , wherein the latex binder comprises poly(vinyl acetate) (PVOAc) latex.

14. The wallboard of claim 11 , wherein the amount of the surface treatment adhesive used to treat the paper is in the range of about 0.1 to about 2 g/m 2 .

15. The wallboard of claim 14 , wherein the amount of the surface treatment adhesive used to treat the paper is in the range of about 0.5 to about 1 g/m 2 .

Assignments (9)
RELEASE OF PATENT SECURITY AGREEMENT Recorded Mar 18, 2013
From: THE BANK OF NOVA SCOTIA
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; ISP INVESTMENTS INC.; HERCULES INCORPORATED
Reel/Frame 030025/0320 →
SECURITY AGREEMENT Recorded Sep 16, 2011
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; HERCULES INCORPORATED; AQUALON COMPANY; ISP INVESTMENT INC.
To: THE BANK OF NOVA SCOTIA, AS ADMINISTRATIVE AGENT
Reel/Frame 026918/0052 →
RELEASE OF PATENT SECURITY AGREEMENT Recorded Sep 15, 2011
From: BANK OF AMERICA, N.A.
To: ASHLAND, INC.; ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
Reel/Frame 026927/0247 →
SECURITY AGREEMENT Recorded Apr 14, 2010
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
To: BANK OF AMERICA, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 024225/0289 →
RELEASE OF SECURITY INTEREST Recorded Apr 13, 2010
From: BANK OF AMERICA, N.A., AS COLLATERAL AGENT
To: ASHLAND LICENSING AND INTELLECTUAL PROPERTY LLC; AQUALON COMPANY; HERCULES INCORPORATED
Reel/Frame 024218/0928 →
SECURITY AGREEMENT Recorded Dec 3, 2008
From: ASHLAND LICENSING AND INTELLECTUAL PROPERTY...; AQUALON COMPANY; HERCULES INCORPORATED
To: BANK OF AMERICA, N.A. AS ADMINISTRATIVE AGENT
Reel/Frame 021924/0001 →
PATENT TERMINATION CS-019690-0452 Recorded Dec 1, 2008
From: CREDIT SUISSE, CAYMAN ISLANDS BRANCH
To: HERCULES INCORPORATED
Reel/Frame 021901/0360 →
NOTICE OF GRANT OF SECURITY INTEREST Recorded Aug 15, 2007
From: HERCULES INCORPORATED
To: CREDIT SUISSE, CAYMAN ISLANDS BRANCH (FORMERLY KNOWN AS CREDIT SUISSE FIRST BOSTON) AS COLLATERAL AGENT
Reel/Frame 019690/0452 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 3, 2007
From: BURDICK, CHARLES L.
To: HERCULES INCORPORATED
Reel/Frame 019516/0216 →