Films for use in high strength bags
View Patent ↗Thermoplastic films particularly suited for use in bags including at least a core layer comprising an ethylene copolymer, wherein the films are subjected to post-quench biaxial orientation are provided. Optionally, the films may have a first skin layer and/or a second skin layer located on each side of the core layer. Embodiments may have the desirable combination of improved puncture toughness and ultimate tensile strength, low manufacturing cost and desirable optical and tactile properties.
1. A thermoplastic film comprising at least a core layer, and first and second skin layers,
said core layer comprising from 5 to 15 wt % CaCO 3 by weight of the core layer and an ethylene-hexene copolymer prepared by a single site catalyst and having a density equal to or less than 0.927 g/cm 3 , and
said first and second skin layers comprising LLDPE and from 3 to 20 wt % TiO 2 by weight of the skin layer; and
from 3 to 20 wt %, by weight of the core or skin layer, of a plasticizer in either one skin layer or the core layer;
said thermoplastic film having been subjected to a post-quench biaxial orientation process whereby said thermoplastic film has a machine direction orientation ratio of at least 2, a transverse direction orientation ratio of at least 4, a machine direction ultimate tensile strength of at least 45 MPa, and a transverse direction ultimate tensile strength of at least 65 MPa.
2. The thermoplastic film of claim 1 , wherein said plasticizer is selected from the group consisting of high pressure low density polyethylene, very low density polyethylene, propylene plastomers and elastomers, ethylene plastomers and elastomers, low melt temperature ethylene polymers or copolymers, ethylene propylene copolymers or terpolymers, or combinations thereof.
3. The thermoplastic film of claim 1 , wherein said core layer optionally further comprises opacifying agents, pigments and/or colorants.
4. The thermoplastic film of claim 3 , wherein said opacifying agents, pigments and/or colorants are selected from the group consisting of iron oxide, carbon black, colored pigments, aluminum, titanium dioxide, polybutylene terephthalate, talc, and combinations thereof.
5. The thermoplastic film of claim 1 , wherein said single site catalyst is a metallocene catalyst.
6. The thermoplastic film of claim 1 , wherein said post-quench biaxial orientation process results in a biaxial orientation ratio ranging from about 8 to about 60.
7. The thermoplastic film of claim 1 , wherein said post-quench biaxial orientation process is selected from the group consisting of a tenter frame process, a double-bubble process and a LISIM orientation process.
8. The thermoplastic film of claim 1 , wherein the machine direction orientation and the transverse direction orientation of said post-quench biaxial orientation process are performed sequentially.
9. The thermoplastic film of claim 1 , wherein the machine direction orientation and the transverse direction orientation of said post-quench biaxial orientation process are performed simultaneously.
10. The thermoplastic film of claim 1 , wherein said thermoplastic film has a machine direction ultimate tensile strength of at least 55 MPa.
11. The thermoplastic film of claim 1 , wherein said thermoplastic film has a machine direction ultimate tensile strength of at least 60 MPa.
12. The thermoplastic film of claim 1 , wherein said thermoplastic film has a transverse direction ultimate tensile strength of at least 80 MPa.
13. The thermoplastic film of claim 1 , wherein said thermoplastic film has a transverse direction ultimate tensile strength of at least 100 MPa.
14. The thermoplastic film of claim 1 , wherein said ethylene copolymer has a Melt Index ranging from about 0.1 g/10 min. to about 20 g/10 min.
15. The thermoplastic film of claim 1 , wherein said thermoplastic film has puncture force of at least 10.0 kg/cm.
16. A multi-layer thermoplastic film comprising:
(a) a core layer, said core layer comprising from 5 to 15 wt % CaCO 3 by weight of the core layer and an ethylene-hexene copolymer prepared by a single site catalyst and having a density equal to or less than 0.927 g/cm 3 ;
(b) a first skin layer on a side of said core layer comprising LLDPE and from 3 to 20 wt % TiO 2 by weight of the skin layer; and
(c) a second skin layer on a side of said core layer opposite said first skin layer comprising LLDPE and from 3 to 20 wt % TiO 2 by weight of the skin layer, and
from 3 to 20 wt %, by weight of the core or skin layer, of a plasticizer in either one skin layer or the core layer;
said thermoplastic film having been subjected to a post-quench biaxial orientation process whereby said thermoplastic film has a machine direction orientation ratio of at least 2, a transverse direction orientation ratio of at least 4, a machine direction ultimate tensile strength of at least 45 MPa, and a transverse direction ultimate tensile strength of at least 65 MPa.
17. The thermoplastic film of claim 16 , wherein said plasticizer is selected from the group consisting of high pressure low density polyethylene, very low density polyethylene, propylene plastomers and elastomers, ethylene plastomers and elastomers, low melt temperature ethylene polymers or copolymers, ethylene propylene copolymers or terpolymers, or combinations thereof.
18. The thermoplastic film of claim 16 , wherein said single site catalyst is a metallocene catalyst.
19. The thermoplastic film of claim 16 , wherein said post-quench biaxial orientation process results in a biaxial orientation ratio ranging from about 5 to about 60.
20. The thermoplastic film of claim 16 , wherein said post-quench biaxial orientation process is selected from the group consisting of a tenter frame process, a double-bubble process and a LISIM orientation process.
21. The thermoplastic film of claim 16 , wherein the machine direction orientation and the transverse direction orientation of said post-quench biaxial orientation process are performed sequentially.
22. The thermoplastic film of claim 16 , wherein the machine direction orientation and the transverse direction orientation of said post-quench biaxial orientation process are performed simultaneously.
23. The thermoplastic film of claim 16 , wherein said thermoplastic film has a machine direction ultimate tensile strength of at least 55 MPa.
24. The thermoplastic film of claim 16 , wherein said thermoplastic film has a machine direction ultimate tensile strength of at least 60 MPa.
25. The thermoplastic film of claim 16 , wherein said thermoplastic film has a transverse direction ultimate tensile strength of at least 80 MPa.
26. The thermoplastic film of claim 16 , wherein said thermoplastic film has a transverse direction ultimate tensile strength of at least 100 MPa.
27. The thermoplastic film of claim 16 , wherein said ethylene copolymer has a Melt Index ranging from about 0.1 g/10 min. to about 20 g/10 min.
28. The thermoplastic film of claim 16 , wherein said thermoplastic film has puncture strength of at least 10.0 kg/cm.
29. A label comprising a thermoplastic film of claim 1 .