Nonaqueous secondary battery and method of using the same
View Patent ↗A nonaqueous secondary battery containing a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, in which the positive electrode comprises, as active materials, three or more lithium-containing transition metal oxides having different average particle sizes, those transition metal oxides comprise a transition metal element, the transition metal element of the transition metal oxide having the smallest average particle size is partially substituted with a metal element other than the transition metal element, and the density of the positive electrode mixture layer is t 3.8 g/cm 3 or more.
1. A nonaqueous secondary battery comprising: a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, wherein the positive electrode comprises an active material consisting of at least three lithium-containing transition metal oxides having different average particle sizes and at least five inflection points in a particle size distribution curve of the mixture of said at least three lithium-containing transition metal oxides, wherein the lithium-containing transition metal oxides comprise at least one transition metal element M 1 selected from the group consisting of Co, Ni and Mn, and the transition metal element M 1 of the lithium-containing transition metal oxide having the smallest average particle size is partially substituted with a metal element M 2 other than the transition metal element M 1 , wherein the transition metal element M 2 comprises Mg and at least one metal element selected from the group consisting of Ti, Zr, Ge, Nb, Al and Sn, wherein a content of the transition metal element M 2 in the lithium-containing transition metal oxide having the smallest average particle size is largest among said at least three lithium-containing transition metal oxides.
2. The nonaqueous secondary battery according to claim 1 , wherein said transition metal element M 1 of at least one of the lithium-containing transition metal oxides other than one having the smallest average particle size is partially substituted with a metal element M 2 other than the transition metal element M 1 .
3. A method of using a nonaqueous secondary battery according to any one of claims 1 to 2 comprising the step of:
charging the battery so that a positive electrode voltage is in a range of 4.35 to 4.6 V with reference to the potential of lithium when the battery is fully charged.
4. The aqueous secondary battery according to claim 1 , wherein the particle size of the lithium-containing transition metal oxide having the smallest average particle size is 0.5 to 4 μm.
5. The aqueous secondary battery according to claim 1 , wherein the particle size of the lithium-containing transition metal oxide having the second largest average particle size is 2 to 10 μm.
6. The aqueous secondary battery according to claim 1 , wherein the particle size of the lithium-containing transition metal oxide having the smallest average particle size is 0.5 to 4 μm, and the particle size of the lithium-containing transition metal oxide having the second largest average particle size is 2 to 10 μm.
7. The nonaqueous secondary battery according to claim 1 , wherein the positive electrode comprises an active material consisting of three lithium-containing transition metal oxides having different average particle sizes.
8. The nonaqueous secondary battery according to claim 1 , wherein a thickness obtained by subtracting a thickness of an electrode current collector from a total thickness of the positive electrode is from 30 to 200 μm.
9. The nonaqueous secondary battery according to claim 1 , wherein a particle size of the lithium-containing transition metal oxide having the largest average particle size is 5 to 25 μm.
10. The nonaqueous secondary battery according to claim 1 , wherein the density of the positive electrode mixture layer is at least 3.8 g/cm 3 .