Process for the production of carbon nanotubes in a fluidized bed

1. Process for the production of carbon nanotubes comprising:

decomposing a gaseous hydrocarbon on a heterogeneous catalyst in a fluidized bed reactor, wherein the catalyst is in the form of a defined particle size fraction having a particle size distribution consisting of catalyst particles with diameters between 30 μm and 600 μm;

choosing particle sizes of catalyst and carbon nanotube agglomerates such that a ratio of gas empty tube speed to minimum fluidization speed for all the catalyst and agglomerate particles present in the fluidized bed reactor is between 1.1 and 60, and, at the same time;

setting the gas speed in the reactor below a sinking speed of the particles, or employing a device for recycling discharged particles; and

removing the carbon nanotubes formed from the reactor by means of a sifting device which removes from the reactor only carbon nanotube agglomerates above a defined minimum diameter.

2. Process according to claim 1 , wherein the carbon nanotubes produced have an average external diameter of from 3 nm to 150 nm.

3. Process according to claim 1 , wherein one or more hydrocarbons are employed, individually or as a mixture, as educts.

4. Process according to claim 3 , wherein the hydrocarbons are individuals or mixtures selected from the group consisting of methane, ethane, propane, butane, pentane, hexane, ethylene, propylene, butene, butadiene, short- and medium-chain aliphatic or olefinic hydrocarbons having a C number of from 1 or, respectively, 2 to 10 or mono- or dinuclear aromatic hydrocarbons as well as aliphatics (C x H 2x+2 ) and olefins (C x Hy) having a C number x of x=1-4 or, respectively, 2-4.

5. Process according to claim 1 , which further comprises introducing the catalyst into the reaction chamber in a form in which chief catalytically active components are in the form of oxides, in a partly or completely reduced form, or in the form of hydroxides.