Non-halogenated rubber compounds for use in conveyor belts
View Patent ↗A non-halogenated rubber compound is provided for use in conveyor belts, particularly those used in underground mining. The non-halogenated rubber compound is fire-resistant in accordance with MSHA standards and produces acceptable levels of toxicity and smoke upon burning. Such non-halogenated rubber compound includes a blend of rubbery polymers in combination with aluminum trihydrate, which is a fire retardant, and optionally a phosphate plasticizer, which can provide the rubber compound with a more desirable workability. The blend of rubbery polymers is composed of natural rubber and butadiene rubber, and optionally styrene-butadiene rubber, such blend being present in a total amount of 100 phr. In one embodiment, the aluminum trihydrate is present in an amount of about 30 phr to about 150 phr. In another embodiment, the phosphate plasticizer is present in an amount of about 10 phr to about 60 phr.
1. A fire-resistant conveyor belt comprising:
a first and second outer cover layer situated on the outer opposing surfaces of the conveyor belt, the first and second outer cover layers defining a non-halogenated rubber compound consisting of aluminum trihydrate, about 10 phr to about 60 phr of a phosphate plasticizer, carbon black, an antidegradant, optionally a silica filler, optionally a processing oil, optionally zinc oxide, optionally a wax, and a blend of rubbery polymers present in a total amount of 100 phr, the blend of rubbery polymers consisting of 30 phr to 70 phr of natural rubber and 30 phr to 70 phr of butadiene rubber, wherein the butadiene rubber consists of butadiene repeat units; and
at least one reinforcement layer situated between the first cover layer and the second cover layer, wherein the conveyor belt is fire-resistant, and wherein the at least one reinforcement layer includes outer first and second skim layers on opposing surfaces of the reinforcement layers, the outer first and second skim layers being comprised of the non-halogenated rubber.
2. The fire-resistant conveyor belt of claim 1 wherein the aluminum trihydrate is present in an amount of about 30 phr to about 150 phr.
3. The fire-resistant conveyor belt of claim 1 wherein the aluminum trihydrate is present in an amount of about 65 phr to about 135 phr.
4. The fire-resistant conveyor belt of claim 1 wherein the phosphate plasticizer is 2-ethylhexyl diphenyl phosphate.
5. The fire-resistant conveyor belt of claim 1 wherein the phosphate plasticizer is isodecyl diphenyl phosphate.
6. The fire-resistant conveyor belt of claim 1 wherein the phosphate plasticizer is trioctyl phosphate.
7. The fire-resistant conveyor belt of claim 1 wherein the phosphate plasticizer is butylphenyl diphenyl phosphate.
8. The fire-resistant conveyor belt of claim 1 wherein the phosphate plasticizer is isopropylated triphenyl phosphate.
9. The fire-resistant conveyor belt of claim 1 wherein the aluminum trihydrate is present in an amount of about 85 phr to about 125 phr.
10. The fire-resistant conveyor belt of claim 1 wherein the phosphate plasticizer is present in an amount of about 20 phr to about 40 phr.
11. The fire-resistant conveyor belt of claim 1 wherein the phosphate plasticizer is present in an amount of about 25 phr to about 35 phr.