Method of monitoring and inhibiting scale deposition in pulp mill evaporators and concentrators
View Patent ↗A method of monitoring and inhibiting scale precipitation and deposition from spent liquor in pulp mill evaporators and concentrators is disclosed. The method includes connecting a black liquor deposition monitor to a pulp mill evaporator or concentrator and measuring the thermal conductivity on the outer surface of the monitor. A controller interprets the measured thermal conductivity and determines a level of scale deposition. If the level of scale deposition is above a predetermined level, the controller is operable to introduce a scale-inhibiting composition to the spent liquor. The scale-inhibiting composition may include organic polycarboxylic acids; organic fatty acids; low molecular weight and polymeric aromatic acids; organic acid esters, anhydrides, and amides; low molecular weight and polymeric aliphatic and aromatic sulfonic acids; and low molecular weight and polymeric amines; and any combinations.
1. A method of inhibiting scale deposition from a black liquor in a pulp mill evaporator or concentrator, the method comprising:
(a) determining a level of scale deposition in the pulp mill evaporator or concentrator; and
(b) adding an effective amount of a scale-inhibiting composition to the black liquor, if the determined level of scale deposition is above a predetermined level;
(c) wherein the scale-inhibiting composition includes (i) one or more fatty acids of plant origin and (ii) one or more compounds selected from the group consisting of: polyacrylic acids; polymaleic acids; and any combination thereof.
2. The method of claim 1 , further comprising:
(a) inserting a probe having a temperature-regulated outer surface into the pulp mill evaporator or concentrator;
(b) contacting the temperature-regulated outer surface with the spent liquor;
(c) measuring a thermal conductivity of the temperature-regulated outer surface, wherein the thermal conductivity is dependent upon an amount of scale deposition on the temperature-regulated outer surface;
(d) transmitting the measured thermal conductivity to a controller;
(e) determining a level of scale deposition in the pulp mill evaporator or concentrator, based upon the measured thermal conductivity; and
(f) adding an effective amount of the scale-inhibiting composition to the spent liquor, if the determined level of scale deposition is above the predetermined level.
3. The method of claim 2 , including intermittently measuring the thermal conductivity on the temperature-regulated outer surface of the probe.
4. The method of claim 2 , including continuously measuring the thermal conductivity on the temperature-regulated outer surface of the probe.
5. The method of claim 1 , wherein the black liquor has a solids content below about 50%.
6. The method of claim 1 , wherein the black liquor is derived from a process selected from the group consisting of kraft, alkaline, sulfite, and neutral sulfite semichemical.
7. The method of claim 1 , wherein the scale includes one or more scales selected from the group consisting of: burkeite, sodium sulfate, sodium carbonate, entrapped organic material, calcium carbonate, and combinations thereof.
8. The method of claim 1 , including adding about 1 ppm to about 2,000 ppm of the scale-inhibiting composition, based on volume of the black liquor.
9. The method of claim 1 , wherein the one or more fatty acids of plant origin is a linseed oil heat polymerized in the presence of maleic anhydride and optionally cross-linked with pentaerythritol.
10. The method of claim 1 , wherein the one or more fatty acids of plant origin include one or a mixture of fatty acids and/or fatty acid esters with chain length from about C5 to about C50.
11. The method of claim 1 , wherein one or more of the one or more fatty acids of plant origin is derived from a biodiesel manufacturing process.
12. The method of claim 1 , wherein the one or more fatty acids of plant origin is derived from one or more phases of a biodiesel manufacturing process selected from the group consisting of addition of acid to the fatty acid salts solution of a crude fatty acid alkyl esters phase; addition of acid to the fatty acid salts solution of a crude glycerin phase; acidulation of at least one biodiesel manufacturing process stream containing at least one fatty acid salts component; transesterification reactions involving triglycerides; and any combinations thereof.
13. The method of claim 1 , wherein the one or more fatty acids of plant origin is selected from the group consisting of: palmitic acid, palmitoleic acid, stearic acid, oleic acid, linoleic acid, linolenic acid, arachidic acid, eicosenoic acid, behenic acid, lignoceric acid, tetracosenic acid, and any combinations thereof.
14. The method of claim 1 , wherein the pulp mill evaporator is a multiple-effect evaporator.
15. The method of claim 1 , including monitoring the concentration of the scale-inhibiting composition in the spent liquor by using an inert fluorescent tracer.