Process for production of trialkoxyhalosilanes
View Patent ↗A process for the production of trialkoxyhalosilanes which comprises reacting a tetrahalosilane [37] with a tetra-alkoxysilane [38] in the presence of an alcohol whose alkoxy group is the same as those of the tetraalkoxysilane to thereby obtain a trialkoxyhalosilane [39], characterized in that the alcohol is used in an amount of 5 to 50% by mole based on the total amount of Si of the tetrahalosilane and the tetraalkoxysilane: SiX 4 [37] (wherein X is halogeno) Si(OR 1 ) 4 [38] (wherein R 1 is a hydrocarbon group having 1 to 6 carbon atoms) XSi(OR 1 ) 3 [39] (wherein X and R 1 are each as defined above).
1. A process for production of trialkoxy(dialkylamino) silanes, comprising:
a first step which comprises reacting a tetrahalosilane represented by Formula 1 with a tetraalkoxysilane represented by Formula 2 in the mixture of an alcohol composed of the same alkoxy group as that of the tetraalkoxysilane to yield a trialkoxyhalosilane represented by Formula 3, wherein the alcohol is used in an amount of 10-50% by mol based on a total amount of Si in the tetrahalosilane and the tetraalkoxysilane:
SiX 4 [Formula 1]
(where X denotes halogen)
Si(OR 1 ) 4 [Formula 2]
(where R 1 denotes a hydrocarbon group having 1-6 carbon atoms)
XSi(OR 1 ) 3 [Formula 3]
(where X denotes halogen; and R 1 a hydrocarbon group having 1-6 carbon atoms); and
and a second step of reacting the trialkoxy halosilane obtained in the first step with a dialkylamine represented by Formula 7 to yield a trialkoxy(dialkylamino) silane represented by Formula 8:
R 2 R 3 NH [Formula 7]
(where R 2 denotes a hydrocarbon group having 1-12 carbon atoms; and R 3 a hydrocarbon group having 1-12 carbon atoms)
R 2 R 3 NSi(OR 1 ) 3 [Formula 8]
(where R 1 denotes a hydrocarbon group having 1-6 carbon atoms; R 2 a hydrocarbon group having 1-12 carbon atoms; and R 3 a hydrocarbon group having 1-12 carbon atoms).
2. The process for production of trialkoxy(dialkylamino) silanes according to claim 1 , wherein the reacted mixture obtained in the first step is reacted with the dialkylamine represented by Formula 7, without subjecting to isolation/purification.
3. The process for production of trialkoxy(dialkylamino) silanes according to claim 1 , wherein X is chlorine and R 1 , R 2 and R 3 are ethyl in the compound represented by Formulae 1-3, 7, and 8.
4. The process for production of trialkoxy(dialkylamino) silanes according to claim 2 , wherein X is chlorine and R 1 , R 2 and R 3 are ethyl in the compound represented by Formulae 1-3, 7, and 8.