Ionic compound, electrolytic solution, electrochemical device and battery
View Patent ↗A battery capable of improving cycle characteristics is provided. An electrolytic solution impregnated with a separator includes an ionic compound with an asymmetric structure such as fluorotrifluoromethyl[oxalage-O,O′] lithium borate as an electrolyte salt. Thereby, compared to the case where an ionic compound with a symmetric structure such as bis[oxalate-O,O′] lithium borate or difluoro[oxalate-O,O′]lithium borate is included as an electrolyte salt, the conductivity of the electrolytic solution is improved.
1. An ionic compound comprising:
a structure shown in Chemical Formula 1:
where X n+ represents an ion of a Group 1A element or a Group 2A element in the short form of the periodic table of the elements, or an onium ion, M represents a transition metal, or a Group 3B element, a Group 4B element or a Group 5B element in the short form of the periodic table of the elements, Rf represents a fluorinated alkyl group or a fluorinated aryl group having a carbon number of 1 to 10, and Y represents ZC(CR 2 ) d CZ, O 2 S(CR 2 ) e SO 2 or OC(CR 2 ) e SO 2 (Z represents ═O, a halogenated alkyl group or a halogen group, R represents a hydrogen group, an alkyl group, a halogenated alkyl group or a halogen group), and a, g and n each are an integer of 1 or 2, b, c and e each are an integer of 1 to 4, d is 0 or an integer of 1 to 4, and f and m each are an integer of 1 to 3.
2. The ionic compound according to claim 1 , wherein the ionic compound includes fluorotrifluoromethyl[oxalate-O,O′] lithium borate.
3. An electrolytic solution comprising:
a solvent; and
an electrolyte salt shown in Chemical Formula 2:
where X n+ represents an ion of a Group 1A element or a Group 2A element in the short form of the periodic table of the elements, or an onium ion, M represents a transition metal, or a Group 3B element, a Group 4B element or a Group 5B element in the short form of the periodic table of the elements, Rf represents a fluorinated alkyl group or a fluorinated aryl group having a carbon number of 1 to 10, and Y represents ZC(CR 2 ) d CZ, O 2 S(CR 2 ) e SO 2 or OC(CR 2 ) e SO 2 (Z represents ═O, a halogenated alkyl group or a halogen group, R represents a hydrogen group, an alkyl group, a halogenated alkyl group or a halogen group), and a, g and n each are an integer of 1 or 2, b, c and e each are an integer of 1 to 4, d is 0 or an integer of 1 to 4, and f and m each are an integer of 1 to 3.
4. An electrochemical device comprising:
an electrolytic solution including an electrolyte salt shown in Chemical Formula 3:
where X n+ represents an ion of a Group 1A element or a Group 2A element in the short form of the periodic table of the elements, or an onium ion, M represents a transition metal, or a Group 3B element, a Group 4B element or a Group 5B element in the short form of the periodic table of the elements, Rf represents a fluorinated alkyl group or a fluorinated aryl group having a carbon number of 1 to 10, and Y represents ZC(CR 2 ) d CZ, O 2 S(CR 2 ) e SO 2 or OC(CR 2 ) e SO 2 (Z represents ═O, a halogenated alkyl group or a halogen group, R represents a hydrogen group, an alkyl group, a halogenated alkyl group or a halogen group), and a, g and n each are an integer of 1 or 2, b, c and e each are an integer of 1 to 4, d is 0 or an integer of 1 to 4, and f and m each are an integer of 1 to 3.
5. A battery comprising a cathode, an anode and an electrolytic solution, wherein
the electrolytic solution includes an electrolyte salt shown in Chemical Formula 4:
where X n+ represents an ion of a Group 1A element or a Group 2A element in the short form of the periodic table of the elements, or an onium ion, M represents a transition metal, or a Group 3B element, a Group 4B element or a Group 5B element in the short form of the periodic table of the elements, Rf represents a fluorinated alkyl group or a fluorinated aryl group having a carbon number of 1 to 10, and Y represents ZC(CR 2 ) d CZ, O 2 S(CR 2 ) e SO 2 or OC(CR 2 ) e SO 2 (Z represents ═O, a halogenated alkyl group or a halogen group, R represents a hydrogen group, an alkyl group, a halogenated alkyl group or a halogen group), and a, g and n each are an integer of 1 or 2, b, c and e each are an integer of 1 to 4, d is 0 or an integer of 1 to 4, and f and m each are an integer of 1 to 3.