SEPARATOR FOR LITHIUM SECONDARY BATTERY, METHOD FOR PRODUCING THE SAME, AND LITHIUM SECONDARY BATTERY INCLUDING THE SAME
A separator for a lithium secondary battery includes a high molecular porous film with a shut-down function and a heat-resistant porous layer integrally formed on each side of the high molecular porous film. The heat-resistant porous layers contain a heat-resistant high-molecular material and a ceramic filler. By using the separator, the occurrence of a short-circuit due to the melting and shrinkage of the high molecular porous film is prevented. Also, in the event of a short-circuit and the generation of heat higher than the melting point of the material of the high molecular porous film, the expansion of the short-circuit is prevented, so that the safety of the lithium secondary battery is improved.
1 . A separator for a lithium secondary battery, comprising:
a high molecular porous film with a shut-down function;
a first heat-resistant porous layer integrally formed on one face of said high molecular porous film, said first heat-resistant porous layer comprising a heat-resistant high-molecular material and a ceramic filler; and
a second heat-resistant porous layer integrally formed on the other face of said high molecular porous film, said second heat-resistant porous layer comprising a heat-resistant high-molecular material and a ceramic filler.
2 . The separator for a lithium secondary battery in accordance with claim 1 , wherein said heat-resistant high-molecular material of said first and second heat-resistant porous layers is a polyamideimide, and said ceramic filler of said first and second heat-resistant porous layers is an alumina filler.
3 . The separator for a lithium secondary battery in accordance with claim 1 , wherein the separator has a thickness of 12 to 24 μm.
4 . The separator for a lithium secondary battery in accordance with claim 1 , wherein 0.5≦Da/(Db 1 +Db 2 )≦8 where Da is the thickness of said high molecular porous film, Db 1 is the thickness of said first heat-resistant porous layer, and Db 2 is the thickness of said second heat-resistant porous layer.
5 . The separator for a lithium secondary battery in accordance with claim 1 , wherein 0.5≦Db 1 /Db 2 ≦2 where Db 1 is the thickness of said first heat-resistant porous layer, and Db 2 is the thickness of said second heat-resistant porous layer.
6 . The separator for a lithium secondary battery in accordance with claim 1 , wherein said high molecular porous film has a porosity of 40 to 70% at 25° C.
7 . A separator for a lithium secondary battery, comprising:
a high molecular porous film with a shut-down function, said high molecular porous film having a porosity of 40 to 70% at 25° C. and a thickness of Da;
a first heat-resistant porous layer integrally formed on one face of said high molecular porous film, said first heat-resistant porous layer comprising a polyamideimide and an alumina filler and having a thickness of Db 1 ; and
a second heat-resistant porous layer integrally formed on the other face of said high molecular porous film, said second heat-resistant porous layer comprising a polyamideimide and an alumina filler and having a thickness of Db 2 ,
wherein the sum of Da, Db 1 , and Db 2 is 12 to 24 μm, 0.5≦Da/(Db 1 +Db 2 )≦8, and 0.5≦Db 1 /Db 2 ≦2.
8 . A method for producing a separator for a lithium secondary battery, comprising the steps of:
immersing a high molecular porous film with a shut-down function in a coating liquid containing a heat-resistant high-molecular material or a precursor thereof and a ceramic filler; and
taking the high molecular porous film out of the coating liquid and heat-drying it to form a heat-resistant porous layer on each side of the high molecular porous film.
9 . A lithium secondary battery comprising: the separator of claim 1 ; a positive electrode comprising an active material which absorbs and desorbs lithium; a negative electrode comprising an active material which absorbs and desorbs lithium; and a non-aqueous electrolyte.